Journal of Power Sources, Journal Year: 2024, Volume and Issue: 625, P. 235710 - 235710
Published: Nov. 5, 2024
Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 15, 2025
Carbon-based printable mesoscopic solar cells (p-MPSCs) offer significant advantages for industrialization due to their simple fabrication process, low cost, and scalability. Recently, the certified power conversion efficiency of p-MPSCs has exceeded 22%, drawing considerable attention from community. However, key challenge in improving device performance is achieving uniform high-quality perovskite crystallization within mesoporous structure. This review highlights recent advancements p-MPSCs, with an emphasis on controlling kinetics regulating morphology confined mesopores. It first introduces offering a solid foundation understanding behavior. Additionally, summarizes mechanisms crystal nucleation growth, explaining how these processes influence quality perovskites. Furthermore, commonly applied strategies enhancing quality, such as additive engineering, solvent evaporation controlling, post-treatment techniques, are also explored. Finally, proposes several potential suggestions aimed at further refining crystallization, inspiring continued innovation address current limitations advance development p-MPSCs.
Language: Английский
Citations
4
ACS Energy Letters, Journal Year: 2025, Volume and Issue: unknown, P. 1275 - 1283
Published: Feb. 17, 2025
Language: Английский
Citations
1
Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 9, 2024
Abstract The oxidation of iodide ions during annealing in air and rich defects generated at crystal terminations perovskite are major limitations for achieving high photovoltaic performance printable mesoscopic solar cells (p‐MPSCs). Here, the dual role hydrazide derivatives inhibiting passivating termination is reported how affected by substituent studied. It's found that varying derivative from formylhydrazine (FH) to benzhydrazide (BH) then 4‐tert‐butylbenzhydrazide (TBBH) introducing phenyl 4‐tert‐butylphenyl substituents enhances electron donating ability hydrazides due electronic effect. tailored present enhanced suppression defect passivation capabilities, which lowers trap density p‐MPSCs significantly. As most effective additive, TBBH improves power conversion efficiency p‐MPSC 18.66% 20.30%, resulted device maintains 90% its initial after 500 h tacking maximum point 55 ± 5 °C under simulated 1 sun illumination.
Language: Английский
Citations
8
Small, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 12, 2025
Abstract The large open‐circuit voltage ( V OC ) losses limit the enhancement of power conversion efficiency (PCE) in printable mesoscopic perovskite solar cells (p‐MPSCs). These primarily result from high defect density at grain boundaries within mesoporous scaffold, which promotes non‐radiative recombination. In this study, crystallization improvement and modulation is promoted by adopting a multifunctional ionic liquid, 1‐butyl‐2,3‐dimethylimidazolium trifluoromethanesulfonate (BMMIm[OTF]). imidazolium ions BMMIm[OTF] form hydrogen bonds with PbI 6 4− framework coordinate under‐coordinated lead through S═O bonds. interactions synergistically improve crystallinity films optimize energy level alignment perovskite/carbon electrode interface. This improved interface facilitates more efficient charge transfer extraction while reducing As result, champion p‐MPSCs incorporating achieve PCE 20.02% 1.055 V, significantly outperforming control devices 0.965 V. Furthermore, hydrophobic nature enhances device stability. research provides practical strategy for developing durable p‐MPSCs.
Language: Английский
Citations
0
Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 532, P. 216499 - 216499
Published: Feb. 18, 2025
Language: Английский
Citations
0
Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: May 23, 2025
Abstract Mesoporous electron transport layer (ETL) in printable mesoscopic perovskite solar cells (p‐MPSCs) enables rapid and selective extraction of photogenerated electrons facilitates device fabrication without a hole (HTL). However, the inherent mesoporous architecture introduces abundant interfacial defects that promote undesired non‐radiative recombination, limiting power conversion efficiency (PCE). To address this challenge, an interface field‐effect passivation strategy is implemented, leveraging spatially cation extrusion. By incorporating tetraphenylphosphonium cations, sterically bulky organic ions migrate to perovskite/ETL during crystallization, robust electrostatic field introduced. This simultaneously suppresses recombination by inducing enhances charge through optimizing energy alignment. The synergistic effects yield PCE enhancement from 19.4% 21.0%. work underscores potential cation‐engineered fields improve performance HTL‐free carbon‐electrode photovoltaics.
Language: Английский
Citations
0
Small, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 28, 2025
Abstract In recent years, carbon‐based printable mesoscopic perovskite solar cells (p‐MPSCs) without hole transport layers have garnered considerable interest because of their outstanding benefits in terms stability and cost. However, the use carbon electrodes instead materials noble metal leads to energy level mismatch, which limits power conversion efficiency (PCE) p‐MPSCs. this work, a molecular doping strategy is proposed employing cyclopentylmethanamine passivate surface subsurface crystal defects while inducing an shift toward p‐type region within electrodes. This approach facilitates formation homojunction at micro‐interfaces between perovskites. Results demonstrate that optimizes internal alignment devices, thereby increasing driving force for transfer Ultimately, devices optimized through increase PCE from 17.50% 19.50% retaining over 92% initial after 150 days air ambiance. study provides straightforward effective designing high‐efficiency stable
Language: Английский
Citations
0
Small, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 9, 2024
The stability of perovskite solar cells is closely related to the defects in crystals, and a large number crystal are caused by solution method. In this study, resveratrol (RES), green natural antioxidant abundant knotweed grape leaves, introduced into films passivate defect. RES achieves defect passivation interacting with uncoordinated Pb
Language: Английский
Citations
1
Journal of Power Sources, Journal Year: 2024, Volume and Issue: 625, P. 235710 - 235710
Published: Nov. 5, 2024
Citations
1