Enhancing Stability Pvdf-Hfp-Based Ternary Gel Electrolyte for Dendrite-Free Lithium Metal Anodes DOI

Kaiwei Zhou,

Zunhao Fan,

Snežana Papović

et al.

Published: Jan. 1, 2024

Language: Английский

Multifunctional Additive for Electrolyte Stabilization and Electrode/Electrolyte Interphase Regulation in High-Voltage Lithium Metal Batteries DOI

Heyuan Sun,

Yue Dong, Kai Zhang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: April 17, 2025

Lithium-metal batteries (LMBs) incorporating nickel-rich cathodes have the potential to achieve superior energy densities. However, challenges associated with electrolyte-electrode interphases (EEIs) impeded successful transition of these advanced systems into practical applications. In this study, azidotrimethylsilane (ATMS) is introduced as a multifunctional additive for traditional carbonate-based electrolytes. The azido group in ATMS plays dual role electrochemical reactions, multiple nitrogen (N) atoms engaging both nucleophilic and electrophilic interactions. These N tend undergo preferential oxidation reactions at cathode, forming stable cathode electrolyte interphase, while also undergoing reduction anode inhibit lithium dendrite growth. Si-N bond structure has unique reactivity, effectively neutralizing HF produced from LiPF6 decomposition, thus preventing recurrent formation EEIs battery. As result, long-cycle performance Li||NCM811 significantly improved, capacity retention increasing 34.7% baseline 82.6% after 600 cycles. Similarly, enhances cycling Li||Li symmetric cells, extending their lifespan over 800 h, improves Coulombic efficiency Li||Cu cells 81.6 91.6%. synergistic effect on anodes further high-voltage LMBs.

Language: Английский

Citations

0
Dual-protection of cathode from HF corrossion enabling high-performance lithium metal batteries DOI
S.H. Dai,

Zuosu Qin,

Yuanhang Gao

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

Citations

0
Electronegativity-induced modulation of polysulfide adsorption in halogen-doped Ni2P to accelerate conversion kinetics for lithium-sulfur batteries DOI
Lin Peng, Yu Bai, Hang Li

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

Citations

0
Free-standing films of nickel nanowires anchored with Ni3S2 nanosheets for stable Li anodes DOI
Yang Xu, Gang Li,

Jiangtao Hai

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(44), P. 30534 - 30547

Published: Jan. 1, 2024

A free-standing 3D scaffold of nickel nanowires decorated with lithiophilic Ni 3 S 2 nanosheets was successfully constructed for stable Li anodes.

Language: Английский

Citations

2
Understanding and Regulating the Mechanical Stability of Solid Electrolyte Interphase in Batteries DOI Open Access
Jialin Li, Yanan Wang,

Shu‐Yu Sun

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 19, 2024

Abstract The unstable interface between reactive anodes and electrolytes in batteries has been identified as a critical factor limiting the long‐cycle stability of batteries. An effective solution is to build solid electrolyte interphase (SEI) that acts passivation layer mitigate side reactions electrolytes. mechanical SEI important because with poor cannot survive volume topography fluctuation anode upon cycling. stress built‐up would cause failure SEI, resulting exposure fresh surface electrolyte, consuming limited active materials electrolytes, inducing rapid battery decay. Therefore, understanding regulating imperative for improving cycle life. In this review, properties are discussed. Then, advanced characterization tools measure introduced. Additionally, recent progress on presented terms situ ex modifications SEI. Finally, an insightful outlook provided further understand regulate performance.

Language: Английский

Citations

2
Kinetic understanding of lithium metal electrodeposition for lithium anodes DOI

Rong Fang,

Yuxi Li, Wei‐Wei Wang

et al.

Physical Chemistry Chemical Physics, Journal Year: 2024, Volume and Issue: 26(36), P. 23544 - 23560

Published: Jan. 1, 2024

A comprehensive understanding of the kinetic impacts on lithium deposition and growth is outlined, along with a discussion diverse strategies for control regulation behaviors.

Language: Английский

Citations

1
Rational Modulating Ionic Transportation via Facile ZIF-L/rGO Lamellar Interlayer toward Dendrite-Free Anode for High-Performance Li-Metal Batteries DOI

Ruoshan Jin,

Zichun Xiao,

Zhanhui Jia

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 25, 2024

Language: Английский

Citations

1
Deciphering Lithium Deposition Behavior in Elemental Alloy Anodes for Lithium Metal Batteries DOI
Tao Li, Zhiyi Zhao,

Guohao Zhao

et al.

Nano Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 22, 2024

Lithium (Li) dendrite is one of the most fatal obstacles for developing practical high energy Li metal batteries, while alloy substrates, with strong lithiophilicity, have attracted increasing interest directing uniform deposition. However, previous research studies associated inhibition closely adsorption energy. Yet, deposition process not solely about an isolated atom, where a comprehensive understanding interfacial lattice mismatch and atom diffusion should also be taken into account. Here, we explore behavior from adhesion work, representing stability bonding strength, both diffusion. It found that overpotential inversely related to requires low barrier. These detailed relationships may offer guidance subsequent substrate development.

Language: Английский

Citations

1
Enhancing Stability Pvdf-Hfp-Based Ternary Gel Electrolyte for Dendrite-Free Lithium Metal Anodes DOI

Kaiwei Zhou,

Zunhao Fan,

Snežana Papović

et al.

Published: Jan. 1, 2024

Language: Английский

Citations

0