Constructing a Multifunctional SEI Layer Enhancing Kinetics and Stabilizing Zinc Metal Anode DOI

Dingzheng Li,

Chuanlin Li, Wenjie Liu

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 12, 2024

Abstract Zn dendrite growth and parasitic reactions at the interface of zinc anode/electrolyte in aqueous batteries severely hinder its lifespan application. Herein, anode is effectively stabilized by introducing trace amounts 4‐aminobutane‐1‐phosphate (ABPA) into ZnSO 4 electrolyte. The ABPA adsorbs onto surface then further decomposes to a high conductive organic/inorganic composite situ SEI layer including amino, partial carbon chain, phosphate. In layer, residual undecomposed chain promotes desolvation 2+ , amino induces uniform plating phosphate facilitates migration . Thus, this not only suppresses water‐related side but also enhances transport kinetics. As result, Zn||Zn symmetric cell delivers an ultralong cycle life over 13 000 cycles 50 mA cm −2 1 mAh A average Coulombic efficiency 99.72% achieved 1000 Zn||Cu half‐cell. Zn||I 2 full high‐capacity retention 91.42% after 40,000 cycles. Moreover, 49 pouch maintains 80.28% capacity 300 61.22%

Language: Английский

Multifunctional Zn–complex as interfacial coating for constructing stable and dendrite-free Zn anodes DOI
Jingtao Wang, Lin Liu, Jiahui Lu

et al.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2025, Volume and Issue: 718, P. 136931 - 136931

Published: April 14, 2025

Language: Английский

Citations

0
Constructing a Multifunctional SEI Layer Enhancing Kinetics and Stabilizing Zinc Metal Anode DOI

Dingzheng Li,

Chuanlin Li, Wenjie Liu

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 12, 2024

Abstract Zn dendrite growth and parasitic reactions at the interface of zinc anode/electrolyte in aqueous batteries severely hinder its lifespan application. Herein, anode is effectively stabilized by introducing trace amounts 4‐aminobutane‐1‐phosphate (ABPA) into ZnSO 4 electrolyte. The ABPA adsorbs onto surface then further decomposes to a high conductive organic/inorganic composite situ SEI layer including amino, partial carbon chain, phosphate. In layer, residual undecomposed chain promotes desolvation 2+ , amino induces uniform plating phosphate facilitates migration . Thus, this not only suppresses water‐related side but also enhances transport kinetics. As result, Zn||Zn symmetric cell delivers an ultralong cycle life over 13 000 cycles 50 mA cm −2 1 mAh A average Coulombic efficiency 99.72% achieved 1000 Zn||Cu half‐cell. Zn||I 2 full high‐capacity retention 91.42% after 40,000 cycles. Moreover, 49 pouch maintains 80.28% capacity 300 61.22%

Language: Английский

Citations

2