Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2024, Volume and Issue: unknown, P. 136018 - 136018
Published: Dec. 1, 2024
Language: Английский
Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2024, Volume and Issue: unknown, P. 136018 - 136018
Published: Dec. 1, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161099 - 161099
Published: Feb. 1, 2025
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 689, P. 137219 - 137219
Published: March 3, 2025
Language: Английский
Citations
0Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
Language: Английский
Citations
0Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
Language: Английский
Citations
0ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown
Published: May 7, 2025
Language: Английский
Citations
0Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown
Published: May 16, 2025
Tuning the surface strain is a powerful strategy to enhance catalytic activity of metal nanocatalysts, yet an atomically precise catalyst with intramolecular unlock atomic-level strain-structure-activity relationship still highly desired. Herein, we report synthesis, structural anatomy, and performance toward cyclohexanone oxime electrosynthesis Ag16Cu18(C≡C-C6H11)24 (Ag16Cu18) nanocluster, which has Cu6 ring in center. The Cu-Cu distance only 1.616 Å single crystal, shortest bond Cu nanomaterials date. Furthermore, once Ag16Cu18 was loaded onto carbon paper, ultrashort elongated ∼2.40 Å, showing strong compressive strain. exhibited excellent electrosynthesis, manifested by maximal Faradaic efficiency, yield, yield rate reaching 47.4%, 95.4%, 2.66 mmol·h-1·cm-2 at -0.35 V, respectively. In-situ attenuated total reflection surface-enhanced infrared spectroscopy revealed that sites adjacent Ag atoms primarily reduce NO stabilize it *NH2OH stage, while provide H* for reduction adsorb react *NH2OH, forming simultaneously. Density functional theory calculations confirmed presence ring, facilitates formation adsorption, hence significantly contributing generation. This study not reports case clusters but also provides understanding employing bimetallic nanocluster-based catalysts valuable organic molecules.
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 360, P. 130923 - 130923
Published: Dec. 3, 2024
Language: Английский
Citations
1Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2024, Volume and Issue: unknown, P. 136018 - 136018
Published: Dec. 1, 2024
Language: Английский
Citations
0