Journal of the Taiwan Institute of Chemical Engineers, Journal Year: 2025, Volume and Issue: unknown, P. 106182 - 106182
Published: May 1, 2025
Language: Английский
Journal of the Taiwan Institute of Chemical Engineers, Journal Year: 2025, Volume and Issue: unknown, P. 106182 - 106182
Published: May 1, 2025
Language: Английский
Published: Jan. 1, 2025
O3-type layered oxides are considered as one of the most promising cathode materials for sodium-ion batteries (SIBs) owing to their high initial sodium content, reversible capacity, mature synthesis process, and low production cost. However, adverse phase transition highly air-sensitive issues result in unsatisfactory cycle life poor processing properties, limiting further commercialization. Herein, we prepare a high-entropy metal oxide modified by TiB2 coating layer, which displays increasing structural stability due increase entropy. The layer prevents direct contact between electrolyte electrode, suppresses unfavorable side reaction with electrolyte. Moreover, induces part boron ions (B2−) doping into oxygen CNMT, expanding ion diffusion channels. Consequently, designed Na0.9Cu0.12Ni0.33Mn0.4Ti0.15O2@TiB2 (CNMT@TB) 1 wt% exhibits significantly improvement cycling (capacity retention 91.58% after 200 cycles at 100 mA g−1 93.90% 250 500 g−1) compared pristine CNMT (63.88% 80.07% g−1). This work provides insightful guidance simultaneously enhancing electrochemical performance batteries.
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 178735 - 178735
Published: Jan. 1, 2025
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 180715 - 180715
Published: May 1, 2025
Language: Английский
Citations
0Journal of the Taiwan Institute of Chemical Engineers, Journal Year: 2025, Volume and Issue: unknown, P. 106182 - 106182
Published: May 1, 2025
Language: Английский
Citations
0