Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137851 - 137851
Published: May 1, 2025
Language: Английский
Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137851 - 137851
Published: May 1, 2025
Language: Английский
Materials Today Energy, Journal Year: 2025, Volume and Issue: unknown, P. 101822 - 101822
Published: Jan. 1, 2025
Language: Английский
Citations
0Energy storage materials, Journal Year: 2025, Volume and Issue: 76, P. 104133 - 104133
Published: Feb. 19, 2025
Language: Английский
Citations
0Ionics, Journal Year: 2025, Volume and Issue: unknown
Published: March 26, 2025
Language: Английский
Citations
0ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: April 2, 2025
P2-type Mn-Fe-Cu-based cathode materials have garnered enormous attention as potential candidates for sodium-ion batteries (SIBs). Nevertheless, the detrimental phase transition and irreversible oxygen release cause significant capacity degradation poor cycling stability, thereby decelerating their application progress. Herein, we develop a novel P2-Na0.65Ca0.05Mn0.55Co0.05Fe0.2Cu0.2O2 material via codoping with Co Ca ions. The incorporation of Co3+ ions into Mn sites not only mitigates Jahn-Teller distortion Mn3+ to hinder but also activates anionic redox activity by establishing stable CoO6 octahedron. substitution Ca2+ Na enhances stability Na+ transport pathway suppresses sliding TMO2 layers constructing stronger Ca-O bond. Under synergistic effect Co/Ca codoping, shows enhanced diffusion kinetics, improved intrinsic conductivity, alleviated electrolyte corrosion, decreased cell volume variation during extraction/insertion. Consequently, electrode exhibits high initial discharge (125.9 mA h g-1 at 0.2 C), an excellent rate performance (79.6 10 outstanding long-cycle (73.2% retention after 1000 cycles C). This strategy highlights promising opportunity advance practical in high-performance SIBs.
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162735 - 162735
Published: April 1, 2025
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137851 - 137851
Published: May 1, 2025
Language: Английский
Citations
0