A superparaelectric design with structure optimization enables superior energy-storage performances and stabilities in (Na0.5Bi0.5)TiO3-based ceramics DOI

Xiangjun Meng,

Ying Yuan, Xing Zhang

et al.

Inorganic Chemistry Frontiers, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Boosting the energy-storage performances of (Na 0.5 Bi )TiO 3 -based ceramics by a superparaelectric design with structure optimization.

Language: Английский

Entropy regulation enhanced superior energy storage density and high temperature stability in lead-free relaxors DOI

Zhemin Chen,

Yongping Pu,

Yating Ning

et al.

Journal of the European Ceramic Society, Journal Year: 2024, Volume and Issue: 44(7), P. 4680 - 4688

Published: Feb. 6, 2024

Language: Английский

Citations

34
Remarkable energy storage capability and dielectric temperature stability in (Na0.5Bi0.5)TiO3-based medium entropy superparaelectrics DOI

Zhemin Chen,

Yongping Pu,

Yating Ning

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148796 - 148796

Published: Jan. 21, 2024

Language: Английский

Citations

33
Recent development of lead-free relaxor ferroelectric and antiferroelectric thin films as energy storage dielectric capacitors DOI Creative Commons
K.C. Sekhar,

B. Anina Anju,

Surya Kiran P. Nair

et al.

Journal of the European Ceramic Society, Journal Year: 2024, Volume and Issue: 44(7), P. 4332 - 4349

Published: Feb. 8, 2024

Dielectric electrostatic capacitors are breakthroughs in energy storage applications such as pulsed power (PPAs) and miniaturized energy-autonomous systems (MEASs). Low density, poor charge-discharge speed, deprived breakdown strength of batteries electrochemical limit their use various implantable, wearable, portable electronics. Recently, relaxor ferroelectric (RFE) anti-ferroelectric (AFE) thin film have emerged appropriate candidates for PPAs MEASs. High density (50-120 J/cm3), large (109-1010 W/kg), ultrafast speed (μs range), superior dielectric (DBS) (~MV/cm), excellent thermal stability (150-275 oC) RFE AFE high electronic device applications. In this review article, we portray a succinct discussion the properties AFE-based films.

Language: Английский

Citations

22
High resistivity under colossal permittivity SrTiO3 based ceramic via controlling ion diffusion DOI
Haochen Xie, Yongping Pu,

Yangchao Shang

et al.

Ceramics International, Journal Year: 2024, Volume and Issue: 50(8), P. 12672 - 12677

Published: Jan. 2, 2024

Language: Английский

Citations

21
Synergistic Optimization Unveils Remarkable Energy Storage Enhancement in Silver Niobate-Based Ceramics DOI
Wenjing Shi, Leiyang Zhang,

Yule Yang

et al.

ACS Applied Energy Materials, Journal Year: 2024, Volume and Issue: 7(15), P. 6515 - 6526

Published: July 25, 2024

AgNbO3 (AN)-based lead-free antiferroelectric (AFE) ceramic materials have garnered significant research attention due to their distinctive AFE structures and potential applications in pulse dielectric capacitor devices. However, inferior energy storage performance (ESP) has hindered further advancements practical use. To address this challenge, we introduce a synergistic optimization strategy aimed at enhancing the ESP of AN-based ceramics. Initially, incorporate Bi3+ ions into A-site Ta5+ B-site ABO3-structured AN crystal lattice. This deliberate modification leverages smaller radius compared Ag+ ions, effectively reducing tolerance factor oxygen octahedral torsion, thereby stabilizing phase. Additionally, hybridization ions' 6s orbitals with O2– 2p amplifies polarization. By finely adjusting Nb5+/Ta5+ ion concentration ratio control paraelectric phase content, regulate electric field-induced polarization its response trajectory, ultimately improving while minimizing hysteresis. Comprehensive characterization (Ag0.955Bi0.015)(Nb1–xTax)O3 ceramics was performed through X-ray diffraction refinement, temperature-dependent properties, transmission electron microscopy, revealing intricate interplay between atoms, structure, properties. Our investigation culminates demonstrating an ultrahigh recoverable density 7.06 J/cm3 efficiency 75% 470 kV/cm (Ag0.955Bi0.015)(Nb0.75Ta0.25)O3 ceramics, accompanied by exceptional temperature stability from room 140 °C. systematic lays groundwork for fabricating capacitors enhanced strategy.

Language: Английский

Citations

11
Superior energy storage properties in SrTiO3-based dielectric ceramics through all-scale hierarchical architecture DOI

Chengyang Zuo,

Xu Jialing,

Shilin Yang

et al.

Materials Horizons, Journal Year: 2024, Volume and Issue: 11(7), P. 1732 - 1740

Published: Jan. 1, 2024

The restricted energy density in dielectric ceramic capacitors is challenging for their integration with advanced electronic systems. Numerous strategies have been proposed to boost the at different scales or combine those multiscale effects. Herein, guided by all-scale synergistic design, we fabricated Sr

Language: Английский

Citations

10
B-site entropy tuning assisted Na0.5Bi0.5TiO3-based ceramics with superior energy storage performance DOI

Zhemin Chen,

Yongping Pu,

Yating Ning

et al.

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 89, P. 111635 - 111635

Published: April 17, 2024

Language: Английский

Citations

9
Structural origin of enhanced storage energy performance and robust mechanical property in A-site disordered high-entropy ceramics DOI
Suming Chen, Ting Wang,

Xiaoling Wang

et al.

Rare Metals, Journal Year: 2024, Volume and Issue: unknown

Published: July 31, 2024

Language: Английский

Citations

9
Investigation of structural, morphological, dielectric, optical, and ferroelectric-energy storage properties of [(1-x) BCT-(x) BZT] electroceramics DOI
Amiya Mandal, Deepak Yadav, Shivam Kumar Mittal

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 995, P. 174817 - 174817

Published: May 13, 2024

Language: Английский

Citations

7
Polymorphic Heterogeneous Polar Structure Enabled Superior Capacitive Energy Storage in Lead‐Free Relaxor Ferroelectrics at Low Electric Field DOI

Jiachen Xi,

Jikang Liu, Wangfeng Bai

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: June 12, 2024

Abstract High‐performance energy storage dielectrics capable of low/moderate field operation are vital in advanced electrical and electronic systems. However, contrast to achievements enhancing recoverable density ( W rec ), the active realization superior efficiency η ) with giant energy‐storage coefficient / E electric regions is much more challenging for dielectric materials. Herein, lead‐free relaxor ferroelectrics reported designed polymorphic heterogeneous polar structure. Following guidance Landau phenomenological theory rational composition construction, conceived (Bi 0.5 Na )TiO 3 ‐based ternary solid solution that delivers ≈0.0168 µC cm −2 , high ≈4.71 J −3 ≈93% under low 280 kV −1 accompanied by great stabilities against temperature/frequency/cycling number excellent charging–discharging properties, which ahead most currently bulk ceramics measured at same range. Atomistic observations reveal correlated coexisting local rhombohedral‐tetragonal nanoregions embedded cubic matrix constructed, enables polarization, minimized hysteresis, significantly delayed polarization saturation concurrently, endowing along . These findings advance superiority feasibility nanodomains designing highly efficient capacitors field‐region practical applications.

Language: Английский

Citations

7