Boosting energy storage properties of BNT-based relaxor ferroelectric ceramics via (Zn1/3Nb2/3)4+ complex ion doping DOI
Shun Li, Dongxu Li, Zong‐Yang Shen

et al.

Journal of Materials Science Materials in Electronics, Journal Year: 2024, Volume and Issue: 35(31)

Published: Nov. 1, 2024

Language: Английский

Ultrahigh capacitive energy storage of BiFeO3-based ceramics through multi-oriented nanodomain construction DOI Creative Commons
Zhixin Zhou, Wangfeng Bai,

Ning Liu

et al.

Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)

Published: Feb. 28, 2025

Lead-free BiFeO3-based (BF) materials with colossal spontaneous polarization and high Curie temperatures exhibit considerable potential for groundbreaking developments in dielectric capacitors. However, their inherent limitations, such as restricted breakdown strength (Eb) pronounced remanent polarization, critically restrict advancements energy storage capabilities. Herein, we achieve an exceptional recoverable density of 12.2 J cm−3 impressive efficiency 90.1% via the strategic design a dipolar region resilience to electric fields within ceramics. Guided by phase-field simulations validated through atomic-scale observations, superior performance is attributed incorporation aliovalent ions, which disrupt long-range ordered single-phase distribution, thus enhancing disorder vectors drastically reducing hysteresis. Simultaneously, refinement microstructural scale, coupled introduction high-bandgap synergistically improves durability. This study provides feasible blueprint leveraging high-performance ceramics, further facilitates progress lead-free capacitors next-generation systems. The authors make multi-oriented nanodomain ceramics fields, achieving 90.1%.

Language: Английский

Citations

2
Polymorphic relaxor phase and defect dipole polarization co-reinforced capacitor energy storage in temperature-monitorable high-entropy ferroelectrics DOI Creative Commons

Xiangfu Zeng,

Jinfeng Lin, G. S. Dong

et al.

Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)

Published: Feb. 22, 2025

Language: Английский

Citations

1
Dielectric, ferroelectric, and energy storage properties of BNBTA-xSLZT lead-free ceramics DOI
Han‐li Lian, Meng Shi, Sha Lv

et al.

Journal of the European Ceramic Society, Journal Year: 2025, Volume and Issue: unknown, P. 117219 - 117219

Published: Jan. 1, 2025

Language: Английский

Citations

0
Improved Energy Storage Performance of Bi0.41Na0.41Ca0.18TiO3 Lead‐Free Ceramics by Incorporating Bi(Mg2/3Nb1/3)O3 DOI Open Access
Y. C. Hu, Ying Zhao, Haiying Wang

et al.

physica status solidi (RRL) - Rapid Research Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 21, 2025

Bi 0.5 Na TiO 3 ‐based lead‐free ceramics have received much attention in the field of energy storage; however, their widespread use is hindered by high residual polarization. Herein, Bi(Mg 2/3 Nb 1/3 )O (BMN) incorporated into 0.41 Ca 0.18 (BNCT) using solid‐state reaction method. The with a perovskite structure (1− x )Bi ‐ (the abbreviation )BNCT‐ BMN, where = 0.00, 0.05, 0.10, 0.15, 0.20) are successfully synthesized. phase structure, microstructure, high‐temperature impedance, and storage properties BNCT investigated varying BMN content. Following that, 0.90BNCT–0.10BMN exhibits recoverable density 4.04 J cm −3 an efficiency 84.9% under electric strength 164 kV −1 . Furthermore, these demonstrate excellent frequency temperature stability 140 These results highlight promising potential 0.9BNCT‐0.10BMN for applications.

Language: Английский

Citations

0
Multiscale Structural Regulation of Energy Storage Properties and Their Mechanism of the (1 – x) (Bi0.5Na0.5)0.7Sr0.3TiO3–xCa(Mg1/3Ta2/3)O3 Ceramics DOI
Juntao Huang,

Saifei Wang,

Zhifei Zhang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: March 23, 2025

Ceramic dielectric capacitors have gained significant attention due to their ultrahigh power density, current and ultrafast charge-discharge speed. However, potential applications been limited by relatively low energy storage density. Researchers employed various approaches enhance In this study, (1 - x)(Bi0.5Na0.5)0.7Sr0.3TiO3-xCa(Mg1/3Ta2/3)O3 ceramics were prepared via a solid-phase reaction, the effect of structure on properties was investigated. The results indicate that introduction Ca(Mg1/3Ta2/3)O3 significantly alters multiscale structures (Bi0.5Na0.5)0.7Sr0.3TiO3 ceramic, including transformation from T-phase C-phase, refinement ceramic grains, formation polar nanoregions (PNRs), accompanied an increase in bandgap relaxation degree. These structural changes collectively contributed improved overall modified ceramics. Notably, 0.92(Bi0.5Na0.5)0.7Sr0.3TiO3-0.08Ca(Mg1/3Ta2/3)O3 demonstrated recoverable density (Wrec) 8.37 J/cm3 with efficiency (η) 87.7% at electric field 530 kV/cm. It also exhibited good temperature stability (25-120 °C), frequency (1-100 Hz), fatigue (1-105). Furthermore, it displayed exceptional charge discharge properties, (WD), time (t0.9), (CD), (PD) attaining 4.06 J/cm3, 35.2 ns, 2143.28 A/cm2, 460.71 MW/cm3, respectively. findings suggest are promising candidates for high-power pulsed electronic systems.

Language: Английский

Citations

0
High-Entropy Composition Design for Achieving Excellent Energy Storage Performance in (Bi0.5Na0.5)0.94Ba0.06TiO3-Based Ceramics DOI

Yiwen Niu,

Fan Zhang, Zhiqiang Zhang

et al.

ACS Applied Electronic Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 7, 2025

Language: Английский

Citations

0
Abundant nanodomains in Bi0.48Na0.48Ba0.04TiO3-based ceramics induced by phase transformation for excellent energy storage properties DOI

Jianan Hu,

Qin Feng,

Shengtao Hu

et al.

Journal of Materials Science, Journal Year: 2025, Volume and Issue: unknown

Published: March 17, 2025

Language: Английский

Citations

0
Energy storage properties in multiple ions co-doped Bi0.5Na0.5TiO3-SrTiO3 based ferroelectric ceramics via heterogeneous strategy coordination DOI
Juanjuan Wang,

Fusheng Lai,

Pengkang Ma

et al.

Ceramics International, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

Citations

0
Enhanced capacitive energy storage of NaNbO3-based relaxers via modulating phase structure strategy for high power energy storage DOI
Jianping Huang,

Mingzhao Xu,

Yue Pan

et al.

Journal of Materials Chemistry C, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A schematic diagram of the design strategy to achieve high energy storage performance via phase structure strategy: (a) and (b) dielectric temperature spectra, (c) PFM images, (d) slim unipolar P–E hysteresis loop.

Language: Английский

Citations

0
Boosting energy storage properties of BNT-based relaxor ferroelectric ceramics via (Zn1/3Nb2/3)4+ complex ion doping DOI
Shun Li, Dongxu Li, Zong‐Yang Shen

et al.

Journal of Materials Science Materials in Electronics, Journal Year: 2024, Volume and Issue: 35(31)

Published: Nov. 1, 2024

Language: Английский

Citations

0