Construction of Robust Da@Cnts/Cs Hydrogel Coatings on Hydrophobic Pvdf Membrane by Deposition of Self-Assembly for Efficient Separation of Oil-Water Emulsion and Dye Wastewater DOI

Jingxuan Zhao,

Hongxu Liu,

Yuhcao Qi

et al.

Published: Jan. 1, 2023

With the rapid development of industry, problem water pollution has become increasingly serious. Though there are many separation materials available to solve this problem, how separate multiple wastewater at same time remains a challenge. Hydrogel coating is suitable for use in field oil-water separation, and chitosan (CS) effective removing anionic dyes. Therefore, preparation membranes with hydrogel containing CS can effectively emulsion dye wastewater. In paper, DA@CNTs/CS was prepared by sequentially Cu2+, DA@CNTs, Cu2+ on surface polyvinylidene fluoride (PVDF) membrane deposition self-assembly, which enhanced hydrophilicity made it highly underwater oleophobic antifouling. The alkali treated PVDF contained large amount -OH, formed coordination bonds CS, DA could be stably loaded membrane. addition, introduction rigid CNTs improved performance modified under extreme conditions such as high PH salt concentration. PVDF-DA@CNTs/CS had an ideal pure flux (PWF) 1470 (L·m-2·h-1) efficiency 99.7% 99.4% emulsion. contaminant quickly removed washing DI water. overall also maintained very level long-term filtration summary, study provides new approach complex treatment technology.

Language: Английский

Green Fabrication of Zinc-Based Metal–Organic Frameworks@Bacterial Cellulose Aerogels via In Situ Mineralization for Wastewater Treatment DOI Creative Commons
Xinru Liu,

Jie Gu,

Yongqi Cao

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(5), P. 982 - 982

Published: Feb. 20, 2025

Compared to conventional adsorbents, zinc-based metal-organic frameworks (MOFs) such as zeolite imidazolium skeleton-8 (ZIF-8) exhibit enhanced thermal, chemical, and structural stability. Nonetheless, their powdered form results in limited dispersibility aqueous solutions a tendency aggregate, which significantly restricts utility adsorption applications. This study reports green composite aerogel through the situ mineralization of ZIF-8 onto bacterial cellulose (BC) for effective removal toxic metal ions (Cu2+) Congo red (CR) from wastewater. The ZIF@BC was characterized using scanning electron microscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis, X-ray diffraction, photoelectron specific surface area analysis. findings indicated that produced were evenly distributed across BC nanonetwork, facilitating CR Cu2+. maximum capacities aerogels determined be 397.55 mg/g 424.80 Cu2+, per Langmuir isotherm. Furthermore, ZIF-8@BC demonstrated excellent selectivity reusability, particularly adsorption. proposed mechanism interaction between Cu2+ involves electrostatic interactions, hydrogen bonding, π-π coordination ion exchange, microchemical precipitation, pore diffusion. research offers significant promise utilization MOF powders highlights substantial industrial potential.

Language: Английский

Citations

0

Mesoporous degradable chitosan-based monoliths: synthesis and applications toward water purification DOI
Jyoti Devi Katiyar, Subrata Chattopadhyay

Molecular Systems Design & Engineering, Journal Year: 2024, Volume and Issue: 9(4), P. 399 - 408

Published: Jan. 1, 2024

A synthetic strategy is presented for the preparation of degradable chitosan based functional porous polymer monoliths with tunable surface area, which are capable to efficiently remove multiple pollutants from water.

Language: Английский

Citations

2

Preparation of a novel magnetic composite based on rice straw derived biochar and chromium ferrite for enhanced absorption of organic dye DOI Open Access
Yuan Meng, Dan Chen, Yang Li

et al.

Environmental Engineering Research, Journal Year: 2024, Volume and Issue: 29(6), P. 240028 - 0

Published: April 3, 2024

The modification of biochar (BC) with metal/metal oxides is expected to improve its adsorption capacity pollutants, especially anions dyes. A green chromium ferrite-biochar composites (CF-BC) was synthesized enhance the efficiency Congo red (CR) via a simple co-precipitation method. samples were characterized by different characterization techniques: XRD, FT-IR, SEM, XPS, etc, which showed that ferrite successfully loaded on surface biochar. influencing factors and recycling properties discussed, mechanisms such as kinetics, isotherm, thermodynamics explored. results show CF-BC2 achieves removal rate 92.29% for CR maintains 90% even after three cycles. addition not only promoted effect, but also increased magnetic property, making adsorbents easy recycle. equilibrium kinetic studies suggested process followed Freundlich isotherm pseudo-second order model, respectively. Furthermore, study into mechanism revealed primarily through electrostatic attraction, hydrogen bonding, π-π interactions, pore filling.

Language: Английский

Citations

2

Construction of CS-SDAEM long-chain polysaccharide derivative on TA@CNTs coated PVDF membrane with effective oil-water emulsion purification and low contamination rate DOI

Jingxuan Zhao,

Hongxu Liu,

Yuanhang Zhao

et al.

International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: 275, P. 134230 - 134230

Published: July 31, 2024

Language: Английский

Citations

2

Superhydrophilic PVDF membrane fabricated on modified TiO2/CS-SDAEM nanoparticles deposited on GA/CNTs hydrophilic layer to achieve self-cleaning photodegradation and low contamination rate for dyestuff separation DOI

Jingxuan Zhao,

Hongxu Liu,

Yuchao Qi

et al.

International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: unknown, P. 139328 - 139328

Published: Dec. 1, 2024

Language: Английский

Citations

1

Advances and Prospects in the Study of Spherical Polyelectrolyte Brushes as a Dopant for Conducting Polymers DOI Creative Commons
Na Su

Molecules, Journal Year: 2024, Volume and Issue: 29(6), P. 1315 - 1315

Published: March 15, 2024

Owing to their special structure and excellent physical chemical properties, conducting polymers have attracted increasing attention in materials science. In recent years, tremendous efforts been devoted improving the comprehensive performance of by using technique “doping.” Spherical polyelectrolyte brushes (SPBs) bearing chains grafted densely surface core particles potential be novel dopant not only because spherical structure, high grafting density charge density, but also due possibility being applied printed electronics. This review first presents a summary general dopants polymers. Meanwhile, doped with is highlighted, including preparation, characterization, doping mechanism. It demonstrated that has improved addition SPBs, which act as template synthesis composites. Furthermore, applications future developments conductive composites are briefly reviewed proposed, would draw more this field.

Language: Английский

Citations

0

Environmental Cationic Dye/Porous Silica Nanospheres for Printed Cotton Fabrics with Enhanced Coloration Performance DOI
Jinping Zhang,

Peibo Du,

Zaisheng Cai

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(47), P. 65620 - 65627

Published: Nov. 14, 2024

The wastewater of printing and dyeing is difficult to treat due the degradation resistance dye use massive chemicals, causing a threat ecosystem. Pigment fabrics possesses great advantages like high efficiency flexible production, but there are some challenges risk color depth hand feeling large size pigment poor adsorption light. In order improve coloration ability pigment, herein, novel kind cationic dye/porous silica nanospheres were prepared through methylene blue rhodamine B onto electronegative porous applied in on woven cotton fabric. It was found that exhibited an average diameter, good depth, feeling, image quality for preparation. comparison with dye-printed fabrics, dye/WHMS show higher resulting from lower visible light reflectance. Notably, strong interaction between dyes hydrophilic (WHMS) facilitates improvement absorption stability. Meanwhile, printed demonstrate splendid fastness. dry/wet rubbing fastnesses 4 3–4, respectively. Furthermore, dye/WHMS-printed possess satisfactory breathability. consumptions reduced, process simplified. We think this work may provide insight into textiles enhanced effects alleviate environmental impact conventional textile coloration.

Language: Английский

Citations

0

Construction of Robust Da@Cnts/Cs Hydrogel Coatings on Hydrophobic Pvdf Membrane by Deposition of Self-Assembly for Efficient Separation of Oil-Water Emulsion and Dye Wastewater DOI

Jingxuan Zhao,

Hongxu Liu,

Yuhcao Qi

et al.

Published: Jan. 1, 2023

With the rapid development of industry, problem water pollution has become increasingly serious. Though there are many separation materials available to solve this problem, how separate multiple wastewater at same time remains a challenge. Hydrogel coating is suitable for use in field oil-water separation, and chitosan (CS) effective removing anionic dyes. Therefore, preparation membranes with hydrogel containing CS can effectively emulsion dye wastewater. In paper, DA@CNTs/CS was prepared by sequentially Cu2+, DA@CNTs, Cu2+ on surface polyvinylidene fluoride (PVDF) membrane deposition self-assembly, which enhanced hydrophilicity made it highly underwater oleophobic antifouling. The alkali treated PVDF contained large amount -OH, formed coordination bonds CS, DA could be stably loaded membrane. addition, introduction rigid CNTs improved performance modified under extreme conditions such as high PH salt concentration. PVDF-DA@CNTs/CS had an ideal pure flux (PWF) 1470 (L·m-2·h-1) efficiency 99.7% 99.4% emulsion. contaminant quickly removed washing DI water. overall also maintained very level long-term filtration summary, study provides new approach complex treatment technology.

Language: Английский

Citations

0