A Comprehensive Review of Novel Emerging Electrolytes for Supercapacitors: Aqueous and Organic Electrolytes Versus Ionic Liquid-Based Electrolytes

Energy & Fuels, Journal Year: 2024, Volume and Issue: 38(10), P. 8528 - 8552

Published: April 29, 2024

Storage of energy is essential to meet the daily demand for powering portable devices. This necessitates development storage systems such as supercapacitors (SCs), batteries, and solar cells. SCs have garnered a lot attention their ability provide massive amount power. Nevertheless, traditional mechanisms fall short our expectations. Ionic liquids (ILs), evolutionary green designer solvents, are efficient enough substitute conventional electrolytes aqueous or organic in SCs. A limited potential window restricts performance high electrodes. In contrast, with volatility, flammability, lack tunability not suitable long-term robust applications. Beneficial properties ILs negligible thermal, chemical, electrochemical stability overcome many restrictions improved overall performances. can be used standalone electrolyte mixed electrolytes, redox elements, polymers obtain The structure anions cations has been found significantly influence benefit wider working voltage, temperature range, better density. utilized only but also synthesis electrode materials. Consequently, it discuss recent findings function achieving higher-performing review mainly highlights most on use ILs-based electrodes supercapacitors.

Language: Английский

---

Deep eutectic solvents in food contaminants detection: Characteristics, interaction mechanism and application advances from extracting to other roles

Food Chemistry, Journal Year: 2025, Volume and Issue: 476, P. 143521 - 143521

Published: Feb. 21, 2025

Language: Английский

---

Nanoplastics Extraction from Water by Hydrophobic Deep Eutectic Solvents

ACS Applied Engineering Materials, Journal Year: 2024, Volume and Issue: 2(6), P. 1460 - 1466

Published: June 4, 2024

Nanoplastics pollution, a growing environmental threat, adversely affects ecosystems and human health. The challenge in extracting detecting nanoplastics from matrices lies their minuscule sizes, varied shapes, low concentration. We demonstrate an efficient approach employing hydrophobic deep eutectic solvents (HDESs) for the liquid/liquid extraction of polystyrene (PS) beads (nominally sized 0.1, 0.2, 0.3, 0.5, 1.0 μm), stand-in nanoplastics, both fresh saline water. Of ten different HDES systems evaluated, those described by 1:2 molar ratios tetrabutylammonium bromide ([N4444]Br):decanoic acid or tetraoctylammonium ([N8888]Br):decanoic as well 1:1 thymol:menthol showed exceptional efficiency, achieving nearly complete removal (a mean efficiency 98.4%) single pass across range nanoplastic sizes 100 to 1000 nm. comprising [N4444]Br:decanoic exhibits high capacity, effectively capturing at least 17.2 wt % PS. Crucially, extractive fluids comprise benign components, hydrophobicity these HDESs helps prevent water phase contamination, showcasing potential sustainable solution problem.

Language: Английский

---

Preparation of dicationic ionic liquid modified silica stationary phase for mixed-mode liquid chromatography and its application for food additive detection

Analytica Chimica Acta, Journal Year: 2024, Volume and Issue: 1321, P. 343018 - 343018

Published: July 24, 2024

Language: Английский

---

Elucidating the dynamics behavior of PFASs at the water and hydrophobic low-melting mixture solvents interphase

Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: 407, P. 125170 - 125170

Published: June 1, 2024

Language: Английский

---

Design of deep eutectic solvents for multiple perfluoroalkyl substances removal: Energy-based screening and mechanism elucidation

The Science of The Total Environment, Journal Year: 2024, Volume and Issue: 949, P. 175039 - 175039

Published: July 29, 2024

Language: Английский

---

Comprehensive review of combustion ion chromatography for the analysis of total, adsorbable, and extractable organic fluorine

Journal of Separation Science, Journal Year: 2024, Volume and Issue: 47(15)

Published: Aug. 1, 2024

Poly- and perfluoroalkyl substances (PFAS) are a class of persistent organic pollutants whose high stability appreciable water solubility have led to near-global contamination. PFAS bioaccumulative toxins that been linked myriad disorders detected nearly universally in human blood. Liquid chromatography-tandem mass spectrometry is the most frequent method used for quantitation, though this typically only measures few dozen >14 000 known has shown account small portion total fluorine present. Sum parameter methods such as total, extractable, adsorbable emerged alternative measurements determination. Combustion ion chromatography become preferred organofluorine measurement where sorbent or extract containing combusted emitted hydrofluoric acid (HF) measure cumulative Herein we critically review types measurement, their separation from sample matrix, key parameters analytical instrument affect sensitivity, reproducibility, recovery with regards analysis.

Language: Английский

---

Pushing the boundaries of solid state: Exploring strategies for the synthesis of porous liquids and prospects for their application

Fuel, Journal Year: 2025, Volume and Issue: 387, P. 134353 - 134353

Published: Jan. 11, 2025

Language: Английский

---

Sulfur dioxide removal using deep eutectic solvent–functionalized palm kernel shell–activated carbon

Biomass Conversion and Biorefinery, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 8, 2025

Language: Английский

---

Pretreatment and detection of per- and polyfluoroalkyl substances (PFAS): A review of current advancements, development challenges, and perspectives

Microchemical Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113789 - 113789

Published: April 1, 2025

Language: Английский

---