Cited by Construction of electron-deficient Co on the nanoarrays enhances absorption and direct electron transfer to accelerate electrochemical nitrate reduction

Recent Breakthroughs in Electrocatalytic Reduction of Nitrogen-Oxyanions for Environmentally Benign Ammonia Synthesis DOI

Minghang Jiang, Xiaochuan Huang, Dan Luo

et al.

Nano Energy, Journal Year: 2025, Volume and Issue: unknown, P. 110683 - 110683

Published: Jan. 1, 2025

Language: Английский

Citations

Effective N2 activation strategies for electrochemical ammonia synthesis DOI

Minghang Jiang, Xi Chen,

Fasheng Chen

et al.

Chem, Journal Year: 2025, Volume and Issue: unknown, P. 102441 - 102441

Published: March 1, 2025

Language: Английский

Citations

Defect‐Enriched Cobalt‐Based Coordination Polymers for Selective and Efficient Nitrate Electroreduction to Ammonia DOI

Yidan Ding,

S. Zhang, Yunxia Liu

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

Abstract Electrocatalytic nitrate reduction to ammonia (NRA) offers an arousing route for converting widespread pollutant under mild conditions. Among other NRA catalysts, single‐atom catalyst (SAC) has emerged as a promising candidate due its numerous advantages such maximum metal‐atom‐utilization efficiency, homogeneous and tailorable active sites, which still encounters formidable challenge accelerate the kinetics simultaneously suppress competitive hydrogen evolution reaction, especially when operated in electrolytes with low concentration nitrate. Herein, general strategy is reported prepare defect‐enriched coordination polymer catalysts featuring well‐defined unsaturated metal can exhibit exceptional performance even at surpass SACs toward catalysis. Taking cobalt (Co) example, Co‐based polymers (d‐CoCP) counterpart CoCP without defects are investigated proof‐of‐concept study. Both experimental theoretical results elucidate that elaborately‐engineered d‐CoCP markedly decrease thermodynamic barrier reducing *NO *HNO rate‐limiting step along pathway, thus accelerating adsorption of promoting kinetics.

Language: Английский

Citations

Multiscopic Microenvironment Engineering in Nitrate Electrocatalytic Reduction DOI

Lin Gu,

Yuting Cong,

Ziyang Wu

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 15, 2025

Abstract The electrocatalytic reduction of nitrate (NO 3 RR) is essential for environmental remediation and the nitrogen cycle, yet effects local microenvironment at multiple‐level on catalysis remain largely unclear. This review focuses analyzing impact microenvironmental engineering NO RR from multiscopic. Four aspects are detailed understanding regulation in RR, that are, electronic/molecular interactions (theory simulations), catalysts/reactants (intrinsic activity modulation), solution (anion/cation effect) diffusion (electrocatalytic reactor design). Additionally, relevant situ characterization techniques various material systems (metals, compounds, carbon composites, organic composites) discussed detail can modulate reaction microenvironment. Given potential large‐scale applications, necessary designs also summarized industrial level optimized performance. concludes by outlining future research directions enhancing microenvironment, which will be crucial developing efficient catalysts expanding application microenvironments.

Language: Английский

Citations

Construction of electron-deficient Co on the nanoarrays enhances absorption and direct electron transfer to accelerate electrochemical nitrate reduction DOI

Zhifeng Gao,

Xueying Duan,

Xu Yin

et al.

Journal of Hazardous Materials, Journal Year: 2024, Volume and Issue: 480, P. 136443 - 136443

Published: Nov. 7, 2024

Language: Английский

Citations