Cited by Serial triphenylpropionic acid and N,N'-chelator mixed ligands Cu(II) complexes: structure and biological properties

Structural, spectral and theoretical features of mono and di-substituted novel hydrazones: In vitro antibacterial and anticancer implications DOI

M. Sooraj,

E. Manoj

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 141664 - 141664

Published: Feb. 1, 2025

Language: Английский

Citations

Synthesis, characterization and theoretical studies of three similar nickel (II) complexes: Biological and photocatalytic applications DOI

A. Manasa Mohan,

Lakshmi V. Menon,

K.K. Mohammed Hashim

et al.

Polyhedron, Journal Year: 2025, Volume and Issue: unknown, P. 117499 - 117499

Published: March 1, 2025

Language: Английский

Citations

Synthesis, Characterization, Band gap calculation, DFT study and Biological implication of Two Nitrogen-rich Proligands: Polymorphic Crystal Structures and Hirshfeld surface analyses of a Thiocarbohydrazone DOI

M. Sooraj,

M.J. Krishnapriya,

E. Manoj

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1321, P. 139857 - 139857

Published: Aug. 30, 2024

Language: Английский

Citations

Coumarin based Schiff base proligands as promising antioxidant, antibacterial and anticancer agents: DFT and molecular docking correlations DOI

Ansa Santu,

E. Manoj

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 141650 - 141650

Published: Feb. 1, 2025

Language: Английский

Citations

Nickel(II) Complexes of Benzoylpyridine Diaminoguanidinedihydrazone via In Situ One‐Pot Method: Structural, Spectral, and Catalytic Studies DOI

K.K. Mohammed Hashim,

Lahinakillathu Nishana,

M.R. Prathapachandra Kurup

et al.

Applied Organometallic Chemistry, Journal Year: 2025, Volume and Issue: 39(3)

Published: Feb. 14, 2025

ABSTRACT Seven Ni(II) complexes ( 1 – 7 ) designed from a new nitrogen‐rich ligand 1,3‐bis(phenyl(pyridin‐2‐yl)methylideneamino)guanidine hydrochloride (H 3 L‧ HCl) are reported. The were synthesized using in situ one‐pot method and characterized by elemental analyses, FT‐IR, Far‐IR, electronic solution‐phase spectra, solid‐state diffuse reflectance spectra (UV‐DRS), conductivity measurements, room temperature magnetic moment calculations. structures of H HCl complex confirmed via SCXRD analysis. Additionally, 4 on crystallization yielded mononuclear complex, [Ni(H 2 L)]Cl‧ 2H O 4a ), which was molecular packing the compounds is affected counter anions stabilized various noncovalent interactions within crystal lattice, analyzed quantitatively Hirshfeld surface band gaps indicate semiconductor characteristics, evaluated experimentally subsequently DFT catalytic investigation reveals that facilitates cinnamyl alcohol conversion 90% with selectivity 92% for cinnamaldehyde under optimal reaction conditions 80°C 24 h, employing TBHP decane as oxidizing agent. Similarly, all other also found to exhibit comparable conversions range 81%–91% conditions. Furthermore, silico docking studies demonstrated binding affinity SARS‐CoV‐2 main protease active site (M pro makes them suitable candidates further biological exploration.

Language: Английский

Citations

Self-assembled nickel(ii)-centered metal–organic square grid complexes for CO₂ sensing DOI

M. Sooraj,

R. Jayakrishnan,

E. Manoj

et al.

Dalton Transactions, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Detection and monitoring of hazardous CO2 gas are essential for ensuring human health environmental safety, which form part Goal 13 the United Nations Sustainable Development Goals (SDGs). Metal-organic square complexes in thin-film forms explored this work first time as sensors. Two new Ni(II) metal-organic grid [Ni(HL)]4Cl4·26H2O (1) [Ni(HL)]4 (BF4)4·20H2O (2) were achieved by self-assembly, utilizing 1,5-bis(2-benzoylpyridine) thiocarbohydrazone (H2L) building blocks. The formation a molecular [NiHL]44+ unit containing four octahedrally coordinated centers complex 1 was confirmed single crystal X-ray diffraction (SCXRD). Complex 2, conversely, yielded crystals complex, [NiL]4 (2a), from its DMF ethanol mixture. MALDI mass spectral study indicates that metallosupramolecular units stable solution, while thermogravimetric reveals rigidity cationic structures their solid states. solvent accessible pore volume 1952 Å3 (≈18.2%) accordance with TG result 18.1% weight loss up to 272 °C. Hirshfeld surface used void analysis. BET areas 2 observed be 2.390 4.803 m2 g-1, respectively. experimentally solid-state band gap energy ∼1.45 eV, revealing semiconductor characteristics. Thin films both these then developed using drop casting process employed sensing, hosts consist many secondary amine groups. Both demonstrated sensing capability towards gas, found improve further under white light illumination. responses 31% 59% sensors engineered limit detection reliable 500 ppm. thin film sensor working chemiresistive mode outperformed counterpart when operated sensor.

Language: Английский

Citations

Synthesis, characterization and comparative biological activity of a novel set of cu(II) complexes containing azole-based ligand frames DOI

Courtney E. Elwell,

Emily Stein,

Adam Lewis

et al.

Journal of Inorganic Biochemistry, Journal Year: 2024, Volume and Issue: 262, P. 112736 - 112736

Published: Sept. 19, 2024

Language: Английский

Citations

Serial triphenylpropionic acid and N,N'-chelator mixed ligands Cu(II) complexes: structure and biological properties DOI

Jing Feng, Jing Liu, Yizhu Lei

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1321, P. 139773 - 139773

Published: Aug. 24, 2024

Language: Английский

Citations