Humidity-Triggered Reversible 0–1D Phase Transition in Hybrid Antimony Halides
Yi Liu,
No information about this author
Jiahua Luo,
No information about this author
Abdusalam Ablez
No information about this author
et al.
Nanomaterials,
Journal Year:
2025,
Volume and Issue:
15(6), P. 442 - 442
Published: March 14, 2025
Stimulus-responsive
inorganic–organic
hybrid
metal
halides
(IOMHs)
have
shown
great
potential
in
applications
such
as
sensing
and
anti-counterfeiting.
IOMHs
can
undergo
a
variety
of
structural
changes
when
triggered
by
humidity;
however,
relevant
reports
dimensionality
change
from
zero
dimension
(0D)
to
one
(1D)
are
rare.
This
study
investigates
the
synthesis,
structure,
properties
two
antimony-based
IOMHs,
namely
0D-(Mp)3SbCl6·MeCN
1D-(Mp)2SbCl5
(Mp
=
protonated
morpholine;
MeCN
acetonitrile).
Photophysical
characterizations
show
that
(Mp)3SbCl6·MeCN,
being
excited
at
375
nm,
exhibits
typical
self-trapped
exciton
triplet
state
broad-band
emission,
with
peak
620
nm
quantum
yield
high
75.06%.
Under
humid
conditions,
0D
structure
(Mp)3SbCl6·MeCN
undergoes
phase
transition,
leading
1D
(Mp)2SbCl5.
transition
is
accompanied
fluorescence
quenching.
X-ray
powder
diffraction,
Raman
spectroscopy,
thermogravimetric
analysis
confirm
process
its
reversibility.
Based
on
contrast
before
after
demonstrated
an
ideal
material
for
water
sensing,
capable
detecting
trace
amounts
tetrahydrofuran
detection
limit
0.2%
v/v.
Language: Английский
Nitrogen-doped carbon dots derived from mangosteen peel for the detection of Cr2O72− and vanillin
Yaxuan Chen,
No information about this author
Yushi Guo,
No information about this author
Zhiqiang Xing
No information about this author
et al.
Journal of Photochemistry and Photobiology A Chemistry,
Journal Year:
2024,
Volume and Issue:
458, P. 115945 - 115945
Published: Aug. 6, 2024
Language: Английский
A zero-dimensional 1-butylpiperazine-cadmium(II) hybrid material: Synthesis, structural analysis, and DFT studies
Sabrine Hermi,
No information about this author
Shakeel Ahmad,
No information about this author
Amal Belaid
No information about this author
et al.
Journal of Molecular Structure,
Journal Year:
2024,
Volume and Issue:
unknown, P. 140079 - 140079
Published: Sept. 1, 2024
Language: Английский
Nitrogen-Doped Carbon Dots Derived from Mangosteen Peel for the Detection of Cr2o72- and Vanillin
Yaxuan Chen,
No information about this author
Yushi Guo,
No information about this author
Zhiqiang Xing
No information about this author
et al.
Published: Jan. 1, 2024
Nitrogen-doped
biomass
carbon
dots
(MP-NCDs)
based
on
mangosteen
peel
were
prepared
by
one-step
hydrothermal
method.
Transmission
electron
microscopy
demonstrated
that
MP-NCDs
spherical
and
their
particle
size
ranged
from
2.6
to
5.0
nm.
X-ray
photoelectron
spectroscopy
indicated
they
composed
of
C,
N,
O
elements.
Fourier
transform
infrared
revealed
surface
was
equipped
with
oxygen-containing
amino-containing
groups.
Bright
blue
light
emission
characteristics
demonstrated.
They
had
high
stability
in
aqueous
solution
salt
solution.
Furthermore,
could
be
utilized
as
a
bifunctional
fluorescent
probe
for
detecting
Cr2O72-
vanillin
through
the
fluorescence
quenching
method,
which
exhibited
selectivity,
sensitivity,
anti-interference
performance.
The
detection
limits
determined
2.33
μM
4.6
μM,
respectively.
A
detailed
analysis
conducted
mechanism.
performance
sensing
system
tested
real
samples
using
river
water
infant
formula
models.
Language: Английский
Designing Zero-Dimensional Cadmium-Based Organic–Inorganic Hybrids: The Role of Halogen Doping in Modulating Multifunctional Properties
Meng‐Na Wang,
No information about this author
Jing Wei,
No information about this author
Rong-Jie Hao
No information about this author
et al.
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(38), P. 17864 - 17871
Published: Sept. 10, 2024
Advances
in
materials
science
are
increasingly
dependent
on
the
development
of
multifunctional
capable
improving
system
efficiency
and
reducing
environmental
impact.
In
this
study,
two
zero-dimensional
(0D)
cadmium-based
organic-inorganic
hybrid
(BEMPD)
Language: Английский
Zero-Dimensional Organic-inorganic Hybrid Indium Halide Perovskite with Broadband Yellow Light Emission
Qi Wang,
No information about this author
Wei Jiang,
No information about this author
Peng-Yao Xuan
No information about this author
et al.
CrystEngComm,
Journal Year:
2024,
Volume and Issue:
26(45), P. 6486 - 6492
Published: Jan. 1, 2024
0D
indium
halide
[1-Me-Pipz]
2
[InCl
6
]Cl·H
O
exhibits
strong
broadband
yellow
emission
with
a
high
PLQY
of
52%.
This
crystal
also
demonstrated
excellent
structural
and
spectral
stability,
allowing
its
use
in
efficient
white
light-emitting
diodes.
Language: Английский