Review on Interface Issues between a Garnet Li7La3Zr2O12 Solid Electrolyte and Li Anode: Advances and Perspectives DOI

Jian-Cang Wang,

Ying Li, Zhengxiao Li

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: 38(14), P. 12528 - 12545

Published: July 4, 2024

In the pursuit of advancements within realm solid-state lithium metal batteries, considerable attention has been directed toward garnet-type Li7La3Zr2O12 (LLZO) material owing to its exceptional stability, elevated ionic conductivity at room temperature, compatibility with high operating voltages, and environmentally friendly low-cost production methodologies. Despite these merits, widespread utilization LLZO in conjunction a anode is significantly impeded by emergence interfacial resistance interface dendrite growth issues. When challenges are addressed, this paper comprehensively examines mechanistic underpinnings issues arising from interaction between anode. Furthermore, it surveys latest improvement methodologies employed mitigate concerns, aiming propel advancement battery technology.

Language: Английский

Multi-objective optimization of efficient liquid cooling-based battery thermal management system using hybrid manifold channels DOI
Zengguang Sui, Haosheng Lin, Qin Sun

et al.

Applied Energy, Journal Year: 2024, Volume and Issue: 371, P. 123766 - 123766

Published: June 21, 2024

Language: Английский

Citations

25
Characterizing Electrode Materials and Interfaces in Solid-State Batteries DOI Creative Commons
Elif Pınar Alsaç, Douglas Lars Nelson, Sun Geun Yoon

et al.

Chemical Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 4, 2025

Solid-state batteries (SSBs) could offer improved energy density and safety, but the evolution degradation of electrode materials interfaces within SSBs are distinct from conventional with liquid electrolytes represent a barrier to performance improvement. Over past decade, variety imaging, scattering, spectroscopic characterization methods has been developed or used for characterizing unique aspects in SSBs. These efforts have yielded new understanding behavior lithium metal anodes, alloy composite cathodes, these various solid-state (SSEs). This review provides comprehensive overview strategies applied SSBs, it presents mechanistic SSB that derived methods. knowledge critical advancing technology will continue guide engineering toward practical performance.

Language: Английский

Citations

2
Cool batteries: What’s next? DOI Creative Commons

Yanbing Mo,

Xiaoli Dong

Next Energy, Journal Year: 2024, Volume and Issue: 3, P. 100115 - 100115

Published: March 23, 2024

Lithium-ion batteries (LIBs) often encounter performance decline issues in cold conditions when temperature significantly drops, despite being widely regarded as a leading battery technology. Functioning typical rocking-chair battery, lithium ions shuttle through the "blood" (the electrolyte) of LIBs between graphite anode commonly-used negative electrode) and intercalation compound cathode (positive electrode), where ion movement tends to slow down with decreasing temperature. Considering relative maturity electrode materials, researchers generally pay attention electrolyte corresponding electrode/electrolyte interphase order accelerate transport. In light significant advancements, we herein try delineate categorize engineering depict what next can be done build better suitable for cooler temperatures near future. Specifically, advances are summarized goal improving ionic conductivity bulk electrolyte, facilitating desolvation dynamics at interface, accelerating across interfacial film. Furthermore, viable strategies outlined understand design principles low-temperature inspire more endeavors overcome critical challenges faced by extreme conditions.

Language: Английский

Citations

9
Bacterial Cellulose Applications in Electrochemical Energy Storage Devices DOI
Zijian Zheng, Huan Ye, Zhanhu Guo

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 3, 2024

Abstract Bacterial cellulose (BC) is produced via the fermentation of various microorganisms. It has an interconnected 3D porous network structure, strong water‐locking ability, high mechanical strength, chemical stability, anti‐shrinkage properties, renewability, biodegradability, and a low cost. BC‐based materials their derivatives have been utilized to fabricate advanced functional for electrochemical energy storage devices flexible electronics. This review summarizes recent progress in development BC‐related devices. The origin, components, microstructure BC are discussed, followed by advantages using applications. Then, material design strategies terms solid electrolytes, binders, separators, as well BC‐derived carbon nanofibers electroactive discussed. Finally, short conclusion outlook regarding current challenges future research opportunities related next‐generation suggestions proposed.

Language: Английский

Citations

9
All-solid-state batteries designed for operation under extreme cold conditions DOI Creative Commons

Bolong Hong,

Lei Gao, Changping Li

et al.

Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)

Published: Jan. 2, 2025

A pressing need for enhancing lithium-ion battery (LIB) performance exists, particularly in ensuring reliable operation under extreme cold conditions. All-solid-state batteries (ASSBs) offer a promising solution to the challenges posed by conventional LIBs with liquid electrolytes low-temperature environments. In this study, leveraging benefits of amorphous solid-state (SSEs) xLi3N-TaCl5 (1 ≤ 3x 2), we develop ASSBs capable functioning effectively The designed ASSBs, employing LiCoO2 positive electrode mass loading 4.46 mg cm‒2 and Li-In negative electrode, demonstrate initial discharge capacities 183.19, 164.8 143.78 mAh g‒1 18 mA at ‒10, ‒30, ‒40 °C, respectively, exhibit final capacity 137.6 ‒30 °C 100th cycle. Moreover, an 51.94 ‒60 cycling over 200 h. Lithium-ion often struggle maintain Here, authors solid (xLi₃N-TaCl₅) high ionic conductivities design all-solid-state operating hours.

Language: Английский

Citations

1
Li-Ion Nanorobots with Enhanced Mobility for Fast-Ion Conducting Polymer Electrolytes DOI
Matisse Wei-Yuan Tu, Ziheng Wang, Qionghai Chen

et al.

Energy & Environmental Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The activated hopping of ultrasmall nanoparticles, in conjunction with the accelerated segmental motion polymer, establishes a dual-channel Li + transport pathway that significantly enhances conductivity polymer electrolyte.

Language: Английский

Citations

1
Scalable carbon-patterned layer enhances low-temperature performance of large-format lithium-ion batteries DOI
Jaejin Lim, Siyoung Park, Hyobin Lee

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: 105, P. 87 - 95

Published: Feb. 11, 2025

Language: Английский

Citations

1
Single-crystal Ni-rich Layered Oxide Cathodes with LiNbO3-Li3BO3 Coating for Sulfide All-Solid-State Batteries DOI
Guoshun Liu, Zhonghao Li,

Leiying Zeng

et al.

Nano Energy, Journal Year: 2025, Volume and Issue: unknown, P. 110798 - 110798

Published: Feb. 1, 2025

Language: Английский

Citations

1
Research Progress and Prospect of Perovskite and Anti‐Perovskite Solid Electrolytes for Sodium Solid‐State Batteries DOI

Huize Yang,

Wei Wang, Yaxue Wang

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 8, 2025

Abstract Sodium solid‐state batteries (SSSBs) are poised to revolutionize energy storage by capitalizing on sodium's exceptional crustal abundance (2.36% vs 0.0017% for lithium) and cost‐effectiveness, addressing critical sustainability challenges of lithium‐dependent technologies. Solid electrolytes (SEs) with high ionic conductivity stability have gained significant attention. The compositional structural flexibility perovskites anti‐perovskites make them competitive, the combination advanced computer simulations synthesis techniques can achieve stable materials. Importantly, perovskite anti‐perovskite SEs at room temperature endow enormous potential construction SSSBs. In this review, research progress SSSBs is summarized, different optimization strategies improving compared, an in‐depth discussion chemical electrochemical provided. Specifically, key technical indicators reflecting their tolerance future application been summarized discussed first time. Among these, anti‐perovskites, due diversity presence more ion transport channels, become commercial SEs. Finally, development directions prospected.

Language: Английский

Citations

1
PEO‐Based Solid‐State Polymer Electrolytes for Wide‐Temperature Solid‐State Lithium Metal Batteries DOI

Yunxuan Song,

Meng Su,

Hengying Xiang

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 26, 2024

Abstract Developing solid‐state lithium metal batteries with wide operating temperature range is important in future. Polyethylene oxide (PEO)‐based electrolytes are extensively studied for merits including superior flexibility and low glass transition temperature. However, ideal usage temperatures conventional PEO‐based between 60 65 °C, unequable degrades their electrochemical performances at high (≤25 °C ≥80 °C). Herein, modification methods of PEO low, especially wide‐temperature applications reviewed based on detailed analyses mechanisms involved its different temperatures. First, shortcomings solid due to influence pointed out. Second, existing strategies summarized detail from three aspects high, temperatures, application derivatives or chain segment treatment PEO, addition fillers, other such as reasonable regulation salts, introduction functional layers metal‐organic frameworks (MOFs) covalent organic (COFs). Finally, a summary description electrolyte research development trends provided. The review aims offer some guidance the creation wider working ranges.

Language: Английский

Citations

7