Electrodeposition of Sacrificial Layer, Al2O3/ZnTPP film, onto NiTi Orthodontic Wire: Surface Characterizations and Electrochemical Investigations DOI

Venkatraman Venkateshwaran,

Gokul Sridharan,

Dhanraj Ganapathy

et al.

Micro and Nanosystems, Journal Year: 2024, Volume and Issue: 16(4), P. 247 - 254

Published: Aug. 22, 2024

Background: NiTi (nickel-titanium) alloy wires are widely used in orthodontics due to their unique properties, such as shape memory and superelasticity. However, these can be susceptible corrosion the oral environment, which compromise mechanical performance longevity. Zinc tetraphenyl porphyrin (ZnTPP) is a inhibitor that forms protective layer on aluminum oxide (Al2O3) surface, acting barrier against corrosive agents. Objective: The electrodeposition of sacrificial Al2O3 with ZnTPP was carried out onto Ni- Ti orthodontic wire enhance resistance. Methods: 10 mM nitrate dissolved mL 0.1 M phosphate buffer solution (PBS), an electrolyte. Firstly, by using cyclic voltammetry potential scanning between 0 -2.0 V at scan rate 50 mV/s for cycles. Secondly, 1 PBS ethanol (1:1) prepared Electrodeposition Al2O3/NiTi achieved through window Results: ZnTPP/Al2O3/NiTi displayed potentiodynamic polarization resistance 412931 Ω, high stability compared bare (396421 Ω). Additionally, measured 0.254 mm/year, notably lower than (0.540 mm/year). This decrease attributed presence ZnTPP/Al2O3 film, renders electrically insulative significantly increases its impedance wire. Conclusion: bilayer coating has proven improve wires. Thus, materials considered archwires improved stability.

Language: Английский

High-performance electrochemical sensors with SnBi2O3/Graphene oxide nanocomposite for selective antibiotic detection DOI
Krishnapandi Alagumalai,

Nandhini Munusamy,

Shen‐Ming Chen

et al.

Journal of the Taiwan Institute of Chemical Engineers, Journal Year: 2025, Volume and Issue: 171, P. 106033 - 106033

Published: March 9, 2025

Language: Английский

Citations

0

Self-Assembled porphyrin on Fe/Graphene: A Versatile electrode for Nitrofurantoin antibiotic sensing DOI

Quynh Xuan Thi Nguyen,

Trung‐Dung Dang, Hong Cao

et al.

Microchemical Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113418 - 113418

Published: March 1, 2025

Language: Английский

Citations

0

Polycrystalline boron nitride microflowers for non-invasive vitamin B3 (nicotinamide) sensing DOI
Muhammad Farhan, Muhammad Subhan, Shahzad Naseem

et al.

Diamond and Related Materials, Journal Year: 2025, Volume and Issue: unknown, P. 112296 - 112296

Published: April 1, 2025

Language: Английский

Citations

0

Smart electrochemical determination of food additive (Propyl gallate) in edible oil and chicken samples based on CoSe2@FeS2 nanocomposite modified laser induced graphene electrode DOI

Jeffrey Joseph John Jeya Kamaraj,

Umamaheswari Rajaji, P. Sakthivel

et al.

Journal of the Taiwan Institute of Chemical Engineers, Journal Year: 2024, Volume and Issue: 162, P. 105601 - 105601

Published: June 8, 2024

Language: Английский

Citations

3

Facile fabrication of bismuth oxide anchored graphene oxide for the effective electrochemical sensing of diuron DOI

Nandhini Munusamy,

Francis Packiaraj Don Disouza,

Shen‐Ming Chen

et al.

Journal of the Taiwan Institute of Chemical Engineers, Journal Year: 2024, Volume and Issue: 165, P. 105708 - 105708

Published: Aug. 24, 2024

Language: Английский

Citations

3

Sensitive Determination of Hydroquinone and Catechol Using an Electrochemical Sensor Based on Nitrogen-Doped Malic Acid Carbon Quantum Dots DOI

Cheng Rong,

Yanmei Huang,

Xinyu Zheng

et al.

Materials Chemistry and Physics, Journal Year: 2024, Volume and Issue: unknown, P. 130077 - 130077

Published: Oct. 1, 2024

Language: Английский

Citations

3

Nafion/ZrO2 Modified NiTi Orthodontic Wire: Preparation, Material Characterization, and Corrosion Studies DOI

Raja Rajamanikkam San Chitta Raj,

Keerthana Madhivanan,

Dhanraj Ganapathy

et al.

Micro and Nanosystems, Journal Year: 2024, Volume and Issue: 16(3), P. 183 - 189

Published: June 20, 2024

Background: Nickel-titanium (NiTi) orthodontic wires are widely used in dental corrective procedures due to their high mechanical properties and cost-effectiveness. However, they prone oral corrosion, leading deterioration, aesthetic issues, potential health concerns. Objective: This study aims improve the corrosion resistance durability of NiTi by employing zirconium dioxide (ZrO2) Nafion coating with goal enhancing wire performance. Methods: Two types were evaluated: a standard, unmodified as control another treated electrodeposited ZrO2 film (Naf) coating. Surface analysis was conducted using various techniques, including Field Emission Scanning Electron Microscopy (FESEM) Energy Dispersive X-ray Spectroscopy (EDX) analysis. Results: The uncoated exhibited rate 4.436× 10-1 mm/year, whereas Naf/ZrO2-coated showed 4.068× indicating that Naf/ZrO2 acted protective layer. Additionally, layer provided poor electrical conductivity, resulting slightly higher impedance compared bare NiTi. served barrier, which significantly enhanced improved lifespan. Conclusion: Electro-modification through deposition overall wires, offering promising advancement for use orthodontics. underscores enhance longevity wires.

Language: Английский

Citations

2

A review on green synthesis, biological applications of carbon dots in the field of drug delivery, biosensors, and bioimaging DOI
Arshdeep Chopra,

Yogindra Kumari,

Ajay Pal Singh

et al.

Luminescence, Journal Year: 2024, Volume and Issue: 39(8)

Published: Aug. 1, 2024

Abstract Since the beginning of nanoscience and nanotechnology, carbon dots (CDs) have been foundational idea dominated growth nano‐field. CDs are an intriguing platform for utilization in biology, technology, catalysis, other fields thanks to their numerous distinctive structural, physicochemical, photochemical characteristics. several already created, they assessed based on synthesis process, luminescence Due biocompatibility, less toxic effects, most significantly fluorescent features contrast nanostructures, benefits. This review focuses recent advancements characterization, applications, techniques used made from natural sources. It will also direct scientists creation a technique adjustable that is more practical, effective, environmentally benign. With low toxicity cost, meeting new era's requirements selectivity sensitivity detection sensing various things, such as biomaterial sensing, enzymes, chemical contamination, temperature sensing. Its variety properties, optical chemiluminescence, morphological analysis, make it good option use bioimaging, drug delivery, biosensors, cancer diagnosis.

Language: Английский

Citations

1

Green Synthesis of Carbon Quantum Dots Using Barks of Ficus religiosa and their Application as a Selective Fluorescence Chemosensor DOI

Balabadra Krishna Meghal,

Gokul Sridharan,

Dhanraj Ganapathy

et al.

Micro and Nanosystems, Journal Year: 2024, Volume and Issue: 16(4), P. 255 - 263

Published: Aug. 22, 2024

Background: Green synthesis refers to the environmentally friendly methods of producing materials, typically using sustainable and non-toxic reagents. Carbon Quantum Dots (CQDs) are a new class carbon nanomaterials composed discrete, quasi-spherical nanoparticles with sizes below 10 nm. Objective: The CQDs were made from bark Ficus religiosa (FR) tree. Barks collected FR served as source for process due its unique bioactive composition. Methods: tree barks collected, completely washed ethanol DI H2O, dried at 50°C in hot air oven. After that, was cut into small pieces ground well. powder (200 mg) mixed 100 mL H2O heated 60°C 60 min. transferred an autoclave 175°C 12 h. Results: UV-Vis, FT-IR, FE-SEM, EDS, elemental mapping, fluorescence spectroscopy used characterization CQDs. Moreover, showed wide emission spectrum ranging 280 400 nm by adjusting excitation wavelengths. Fe3+ ions had higher quenching impact on compared other heavy metal ions. Fluorescence measurements that this CQD-based method could detect lowest limit detection (LOD) 2.07 μM linear 0-70 Fe3+. Conclusion: This novel fluorescent CQDs-based be selective real-world water samples.

Language: Английский

Citations

1

Ultra-sensitive zinc cobaltate assembled on N-rich carbon nitride electrochemical sensor for the detection of paraquat in food samples DOI
Subburaj Srinithi, Naveen Karuppusamy, Shen‐Ming Chen

et al.

Journal of the Taiwan Institute of Chemical Engineers, Journal Year: 2024, Volume and Issue: 165, P. 105779 - 105779

Published: Oct. 3, 2024

Language: Английский

Citations

1