Ionics, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 23, 2024
Language: Английский
Ionics, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 23, 2024
Language: Английский
Advanced Science, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 21, 2025
Abstract The unavoidable self‐reduction of Bismuth (Bi)‐based catalysts to zero‐valence Bi often results in detrimental adsorption OCHO * , leading unsatisfactory selectivity HCOOH the electroreduction carbon dioxide (CO 2 ). A novel Bi‐tannin (Bi‐TA) complex is developed, which undergoes situ reconstruction into a Bi/Bi₂O₂CO₃ phase during CO reduction. This reconstructed catalyst exhibits high activity and selectivity, achieving Faradaic Efficiency (FE) for formate production exceeding 90%, peaking at 96%. Operando spectroscopic theoretical analyses reveal that δ+ active site significantly enhances formation intermediate, crucial production. study offers promising approach overcoming limitations Bi‐based reduction formate.
Language: Английский
Citations
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Published: May 15, 2024
Language: Английский
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Published: Feb. 10, 2025
Language: Английский
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Published: March 12, 2025
Language: Английский
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Published: May 5, 2025
Language: Английский
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Published: Oct. 1, 2024
Language: Английский
Citations
3Ionics, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 23, 2024
Language: Английский
Citations
0