Stable Radical Polymers as New Electroactive Materials: Synthesis, Properties, and Emerging Applications DOI Creative Commons

Yufeng Xiong,

Yingjiang Li, X. Z. Cui

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 15, 2024

Abstract Extensive research over recent decades has demonstrated the feasibility of producing stable radical polymers (SRPs) by exploring structure–stability relationships. Owing to their excellent redox activities and inherent paramagnetic characteristics, SRPs are emerging as key functional materials with considerable potentials for various applications such in organic electrodes, semiconductors, magnetic materials, quantum information technologies. Accordingly, this review provides a comprehensive summary most widely investigated representative families SRPs. Innovative strategies design synthesis relationship among physicochemical properties, electronic structures, resulting functionalities these discussed. Moreover, advancements highlighted. Finally, challenges chemistry material functionalization, offering insights into transformative potential future applications, emphasized.

Language: Английский

Bioinspired Stimuli-Responsive Materials for Soft Actuators DOI Creative Commons
Zhongbao Wang, Yixin Chen, Yuan Ma

et al.

Biomimetics, Journal Year: 2024, Volume and Issue: 9(3), P. 128 - 128

Published: Feb. 21, 2024

Biological species can walk, swim, fly, jump, and climb with fast response speeds motion complexity. These remarkable functions are accomplished by means of soft actuation organisms, which commonly composed muscle tissue systems. To achieve the creation their biomimetic artificial counterparts, various stimuli-responsive materials have been synthesized developed in recent decades. They respond to external stimuli form structural or morphological transformations actively passively converting input energy into mechanical energy. core element actuators for typical smart devices like robots, muscles, intelligent sensors nanogenerators. Significant progress has made development bioinspired materials. However, these not comprehensively summarized specific mechanisms literature. In this review, we will discuss advances that instrumental actuators. Firstly, different principles discussed, including fluidic, electrical, thermal, magnetic, light, chemical stimuli. We further summarize state-of-the-art explore advantages disadvantages using electroactive polymers, magnetic composites, photo-thermal responsive shape memory alloys other Finally, provide a critical outlook on field emphasize challenges process implementation industries.

Language: Английский

Citations

8
Nature-inspired miniaturized magnetic soft robotic swimmers DOI
R. Pramanik, Roel Verstappen, Patrick R. Onck

et al.

Applied Physics Reviews, Journal Year: 2024, Volume and Issue: 11(2)

Published: April 24, 2024

State-of-the-art biomedical applications such as targeted drug delivery and laparoscopic surgery are extremely challenging because of the small length scales, requirements wireless manipulation, operational accuracy, precise localization. In this regard, miniaturized magnetic soft robotic swimmers (MSRS) attractive candidates since they offer a contactless mode operation for path maneuvering. Inspired by nature, researchers have designed these small-scale intelligent machines to demonstrate enhanced swimming performance through viscous fluidic media using different modes propulsion. review paper, we identify classify nature-inspired basic that been optimized over large evolutionary timescales. For example, ciliary like Paramecium Coleps covered with tiny hairlike filaments (cilia) beat rhythmically coordinated wave movements propulsion gather food. Undulatory spermatozoa midge larvae use traveling body waves push surrounding fluid effective highly environments. Helical bacteria rotate their slender whiskers (flagella) locomotion stagnant viscid fluids. Essentially, all three employ nonreciprocal motion achieve spatial asymmetry. We provide mechanistic understanding magnetic-field-induced spatiotemporal symmetry-breaking principles adopted MSRS at scales. Furthermore, theoretical computational tools can precisely predict magnetically driven deformation fluid–structure interaction discussed. Here, present holistic descriptive recent developments in smart material systems covering wide spectrum fabrication techniques, design, applications, strategies, actuation, modeling approaches. Finally, future prospects promising systems. Specifically, synchronous tracking noninvasive imaging external agents during vivo clinical still remains daunting task. experimental demonstrations mostly limited vitro ex phantom models where dynamics testing conditions quite compared conditions. Additionally, multi-shape morphing multi-stimuli-responsive modalities active structures demand further advancements 4D printing avenues. Their multi-state configuration an solid-fluid continuum would require development multi-scale models. Eventually, adding multiple levels intelligence enhance adaptivity, functionalities, reliability critical applications.

Language: Английский

Citations

6
Triggerable Patches for Medical Applications DOI Creative Commons

Sofia Sirolli,

Daniele Guarnera, Leonardo Ricotti

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(35)

Published: June 11, 2024

Medical patches have garnered increasing attention in recent decades for several diagnostic and therapeutic applications. Advancements material science, manufacturing technologies, bioengineering significantly widened their functionalities, rendering them highly versatile platforms wearable implantable Of particular interest are triggerable designed drug delivery tissue regeneration purposes, whose action can be controlled by an external signal. Stimuli-responsive particularly appealing as they may enable a high level of temporal spatial control over the therapy, allowing precision possibility to adjust treatment according specific clinical personal needs. This review aims provide comprehensive overview existing extensive literature on patches, emphasizing potential diverse applications highlighting strengths weaknesses different triggering stimuli. Additionally, current open challenges related design use efficient such tuning mechanical adhesive properties, ensuring acceptable trade-off between smartness biocompatibility, endowing with portability autonomy, accurately controlling responsiveness stimulus maximizing efficacy, reviewed.

Language: Английский

Citations

4
Bioinspired Stimuli-Responsive Materials for Soft Actuators DOI Open Access
Zhongbao Wang, Yixin Chen, Yuan Ma

et al.

Published: Jan. 29, 2024

Biomimetic stimuli-responsive materials can respond to various external stimuli in the form of structural or morphological transformations by actively passively converting input energy into mechanical energy. They are core element soft actuators for typical smart devices like robots, artificial muscles, intelligent sensors and nanogenerators. While significant progresses have been made bioinspired materials, they not yet achieved remarkable properties biological systems. In this review, we will discuss recent advances biomimetic that instrumental actuators. Different principles firstly discussed, including fluidic, electrical, thermal, magnetic, light chemical stimuli. We further summarize state-of-the-art explore advantages disadvantages using electroactive polymers, magnetic composites, hydrogels, liquid crystal elastomers, shape memory alloys chemical-responsive materials. Finally, provide a critical outlook on field actuators, emphasize challenges process their implementation industries.

Language: Английский

Citations

3
Bioinspired Metal–Ligand Networks with Enhanced Stability and Performance: Facile Preparation of Hydroxypyridinone (HOPO)-Functionalized Materials DOI Creative Commons

Declan P. Shannon,

Kenneth Cérdan, Minseong Kim

et al.

Macromolecules, Journal Year: 2024, Volume and Issue: 57(24), P. 11339 - 11349

Published: Dec. 6, 2024

Bioinspired hydroxypyridinone (HOPO)functionalized materials are shown to display a remarkable capacity for stability and chelating wide array of metal ions. This allows the synthesis multifunctional networks with diverse physical properties when compared traditional catechol systems. In present study, we report facile, one-pot an amino HOPO ligand simple, scalable incorporation into PEG-acrylate based via active ester chemistry. modular network approach fabrication patterned containing which can chelate range ions, such as transition metals (Fe

Language: Английский

Citations

0
Stable Radical Polymers as New Electroactive Materials: Synthesis, Properties, and Emerging Applications DOI Creative Commons

Yufeng Xiong,

Yingjiang Li, X. Z. Cui

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 15, 2024

Abstract Extensive research over recent decades has demonstrated the feasibility of producing stable radical polymers (SRPs) by exploring structure–stability relationships. Owing to their excellent redox activities and inherent paramagnetic characteristics, SRPs are emerging as key functional materials with considerable potentials for various applications such in organic electrodes, semiconductors, magnetic materials, quantum information technologies. Accordingly, this review provides a comprehensive summary most widely investigated representative families SRPs. Innovative strategies design synthesis relationship among physicochemical properties, electronic structures, resulting functionalities these discussed. Moreover, advancements highlighted. Finally, challenges chemistry material functionalization, offering insights into transformative potential future applications, emphasized.

Language: Английский

Citations

0