Journal of Photochemistry and Photobiology A Chemistry, Journal Year: 2024, Volume and Issue: unknown, P. 116221 - 116221
Published: Dec. 1, 2024
Language: Английский
Journal of Photochemistry and Photobiology A Chemistry, Journal Year: 2024, Volume and Issue: unknown, P. 116221 - 116221
Published: Dec. 1, 2024
Language: Английский
Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162844 - 162844
Published: March 1, 2025
Language: Английский
Citations
2Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162933 - 162933
Published: March 1, 2025
Language: Английский
Citations
1Published: Jan. 1, 2025
Direct Z-scheme-heterostructures with enhanced redox potential are increasingly regarded as promising materials for solar-driven water-splitting. This arises from the synergistic interaction between intrinsic dipoles in Janus and interfacial electric fields across layers. In this study, we explore photocatalytic of 20 two-dimensional Janus-transition-metal-dichalcogenide (TMD) heterobilayers efficient Utilizing density-functional theory calculations, first screen these based on key properties such band gaps magnitude to identify candidates. We then evaluate additional critical factors, including carrier mobility surface chemical reactions, fully assess their performance. By examining alignment synthetic internal fields, distinguish Type-I, Type-II, Z-scheme configurations, enabling targeted design optimal materials. Furthermore, employ Fröhlich model quantify contributions longitudinal-optical phonon mode, providing detailed insights into how mobility, influenced by scattering, affects Our results reveal that several Janus-TMDC heterobilayers, WSe2-SWSe, WSe2-TeWSe, WS2-SMoSe, exhibit strong absorption visible spectrum achieve solar-to-hydrogen conversion efficiencies up 33.24%. research highlights a viable pathway advancing clean energy generation through processes.
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160576 - 160576
Published: Feb. 1, 2025
Language: Английский
Citations
0International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 115, P. 113 - 130
Published: March 10, 2025
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137374 - 137374
Published: March 1, 2025
Language: Английский
Citations
0Chemistry of Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 20, 2025
Language: Английский
Citations
0Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125288 - 125288
Published: March 1, 2025
Language: Английский
Citations
0Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
S-scheme heterojunctions have become a hot topic in photocatalysis. Copper (Cu) compounds are versatile family of photocatalytic materials, including oxides (CuO, Cu2O), binary (CuBi2O4, CuFe2O4), sulfides (CuxS, (1 ≤ x 2)), selenides (CuSe), phosphides (Cu3P), metal organic frameworks (MOFs), etc. These materials characterized by narrow bandgaps, large absorption coefficients, and suitable band positions. To further increase the efficiency photoinduced charge separation, Cu-based widely integrated into exploited for hydrogen evolution reaction (HER), CO2 reduction, H2O2 generation, N2 fixation, pollutant degradation. This review comprehensively discusses recent progress heterojunctions, highlights their considerable potential targeted applications sustainable energy conversion, environmental remediation, beyond. The fundamentals transfer, design principles verification tools summarized. Then, describes categorized according to chemical composition, integration applications. In particular, implications transfer mechanism on promoting catalytic activity selected systems analyzed. Finally, current limitations outlooks provided motivate future studies developing novel advanced photocatalysts with high performance studying underlying mechanisms.
Language: Английский
Citations
0Journal of Rare Earths, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
Language: Английский
Citations
0