Molecular Catalysis, Journal Year: 2024, Volume and Issue: 571, P. 114700 - 114700
Published: Nov. 23, 2024
Language: Английский
Molecular Catalysis, Journal Year: 2024, Volume and Issue: 571, P. 114700 - 114700
Published: Nov. 23, 2024
Language: Английский
Advanced Composites and Hybrid Materials, Journal Year: 2025, Volume and Issue: 8(2)
Published: Feb. 20, 2025
Abstract Pulsed DC plasma-liquid interaction was used to prepare Ag-doped Fe 3 O 4 @SiO 2 @TiO (PP-FST) core–shell in a very short time compared conventional methods. Tetraethyl orthosilicate (TEOS) and Ti(IV) isopropoxide precursors were employed as sources of SiO TiO , respectively, under the influence using silver metal electrodes. TEM images EDS mapping proved successful formation structure without detection Ag NPs on PP-FST surface. This proposed dispersion within lattice during synthesis process technique. The XRD patterns show an increase crystallinity sample after exposure plasma. Furthermore, structural optical properties studied XPS UV–Vis, respectively. synthesized FST exhibited outstanding light absorption capabilities which may be attributed strong surface plasmon resonance (SPR) effect at interface nanoparticles semiconductor. lowers energy band gap 2.05 eV, 2.73 eV for FST. specific area determined by BET analysis 53.9 m /g PP-FST, whereas it 34.1 Moreover, activity both plasma-prepared conventionally nano-catalysts evaluated removing toxic dyes such Acid Orange 142 (AO). degradation efficiency significantly increased 99.6% 80% FST, highlighting plasma treatment.
Language: Английский
Citations
0Molecular Catalysis, Journal Year: 2025, Volume and Issue: 576, P. 114940 - 114940
Published: Feb. 22, 2025
Language: Английский
Citations
0Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
The photocatalytic reduction of carbon dioxide (CO2) into value-added chemical fuels is an effective strategy to address the fossil fuel crisis and global warming. Herein, a novel p–n junction composed ZnTe nanoparticles Cu-TCPP nanosheets was successfully constructed for efficient CO2-to-CO conversion. Structural spectroscopic characterization confirmed establishment junction, which enhances charge separation transfer. ZnTe/Cu-TCPP composite exhibits enhanced CO2 with CO as primary product (120.53 μmol g–1), achieving 4.8- 5.9-fold yield improvements over pristine Cu-TCPP, respectively. DFT calculations revealed significantly adsorption energy (−0.549 eV) on heterojunction, promoting reaction. In situ DRIFTS analysis presence key intermediates (*COOH, *CH3, *CO), validating their roles in selective conversion pathways. A mechanistic study further elucidated contribution each component reaction process. Additionally, photocatalyst exhibited excellent stability, demonstrating its potential sustainable reduction.
Language: Английский
Citations
0ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 133187 - 133187
Published: April 1, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 354, P. 128976 - 128976
Published: July 26, 2024
Language: Английский
Citations
3Catalysis Letters, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 13, 2024
Language: Английский
Citations
2Langmuir, Journal Year: 2024, Volume and Issue: 40(47), P. 25327 - 25333
Published: Nov. 15, 2024
Defect engineering is a highly effective strategy for accelerating charge transfer and enhancing the performance of photocatalysts. In this study, ZnIn
Language: Английский
Citations
2Surfaces and Interfaces, Journal Year: 2024, Volume and Issue: 55, P. 105457 - 105457
Published: Nov. 18, 2024
Language: Английский
Citations
2Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 177677 - 177677
Published: Nov. 1, 2024
Language: Английский
Citations
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