Highly Stable Bifunctional Heterostructured Electrocatalyst Integrated with LDPE‐Derived Spherical Carbon for Longevous Alkaline Seawater Splitting DOI Open Access

Samikannu Prabu,

Goli Nagaraju, Sivaprakash Sengodan

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: March 24, 2025

Abstract The development of innovative electrocatalysts for seawater splitting shows great potential large‐scale green energy. Specifically, interface engineering plays a vital role in improving surface properties and charge transfer. However, electrolysis encounters considerable challenges like chloride‐induced corrosion, impurities, microorganisms that hinder efficiency. Herein, we design highly durable electrocatalyst based on selenium‐enriched NiMn‐S x supported low‐density polyethylene‐derived spherical carbon‐Ni foam (Se‐NiMnS @SC/NF) using combination pyrolysis hydrothermal processes. resulting Se‐NiMnS @SC/NF bifunctional catalyst with hollow cycas cone structure exhibited exceptional electrochemical performance corrosion resistance alkaline an ultralow overpotential 146 262 mV the hydrogen evolution reaction (HER) oxygen (OER) to achieve large current density 500 mA cm⁻ 2 . In simulated setup, maintained cell voltage 2.07 V at , demonstrating outstanding durability over 100 h ≈100% Faradaic Se S doping heterostructured refines electronic boosts kinetics, while increases exposure active sites. Additionally, carbon layer provided strong making excellent electrolysis.

Language: Английский

Multiphasic interfaces boost hydrogen evolution reaction of bifunctional NiFe LDH electrocatalyst via sulfur-phosphorus co-thermal treatment for efficient overall water-splitting DOI
Guangyao Yang,

Weiliang Peng,

Jianwei Ye

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 179074 - 179074

Published: Feb. 1, 2025

Language: Английский

Citations

0
Preparation of Fe(OH)3/Ni3S2/NiS heterostructure on an iron nickel foam as long-life trifunctional electrocatalysts for seawater and urea splitting DOI
Hongying Li, Xiang Gao, S. Zheng

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 179554 - 179554

Published: March 1, 2025

Language: Английский

Citations

0
Highly Stable Bifunctional Heterostructured Electrocatalyst Integrated with LDPE‐Derived Spherical Carbon for Longevous Alkaline Seawater Splitting DOI Open Access

Samikannu Prabu,

Goli Nagaraju, Sivaprakash Sengodan

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: March 24, 2025

Abstract The development of innovative electrocatalysts for seawater splitting shows great potential large‐scale green energy. Specifically, interface engineering plays a vital role in improving surface properties and charge transfer. However, electrolysis encounters considerable challenges like chloride‐induced corrosion, impurities, microorganisms that hinder efficiency. Herein, we design highly durable electrocatalyst based on selenium‐enriched NiMn‐S x supported low‐density polyethylene‐derived spherical carbon‐Ni foam (Se‐NiMnS @SC/NF) using combination pyrolysis hydrothermal processes. resulting Se‐NiMnS @SC/NF bifunctional catalyst with hollow cycas cone structure exhibited exceptional electrochemical performance corrosion resistance alkaline an ultralow overpotential 146 262 mV the hydrogen evolution reaction (HER) oxygen (OER) to achieve large current density 500 mA cm⁻ 2 . In simulated setup, maintained cell voltage 2.07 V at , demonstrating outstanding durability over 100 h ≈100% Faradaic Se S doping heterostructured refines electronic boosts kinetics, while increases exposure active sites. Additionally, carbon layer provided strong making excellent electrolysis.

Language: Английский

Citations

0