Small, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 9, 2024
Abstract The success of achieving scale‐up deployment zinc ion batteries is to selectively regulate the rapid and dendrite‐free growth anodes. Herein, this proposed that a creative design strategy constructing multi‐functional separators (MFS) stabilize By in situ decorating metal‐organic‐framework coating on commercial glass fiber, upgraded separator remarkable benefit for strong anion (SO 4 2− ) anchoring, uniform flux across interface, boosted Zn 2+ desolvation. Such feature promotes transportation efficiency, which enables high transference number 0.81, enhanced ionic conductivity, superb exchange current density 12.80 mA cm −2 . Consequently, anode can be operated stably with an ultra‐long service lifetime over 4800 h symmetric cells improved cycling endurance full batteries. This work paves attractive pathway regulated selectivity toward high‐energy metal beyond chemistry.
Language: Английский