Pushing Boundaries: Introducing Silver-Based Metal–Organic Framework Oxidase-Like Nanozyme over a Wide-Range Temperature

ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: 7(17), P. 20793 - 20803

Published: Aug. 15, 2024

The conventional notion is that enzymes, natural and nanozymes, exhibit peak activity solely within defined psychrophilic or thermophilic conditions. This work challenges the by preparing a highly efficient oxidase-mimic of Ag-based metal–organic frameworks (MOFs) (referred to as UoZ-3; UoZ stands for University Zakho), which effectively in wide-range temperatures. breakthrough not only widens working temperature range but also overcomes instability problem hydrogen peroxide limited use peroxidase-based applications. UoZ-3 showed lower Michaelis–Menten constants compared silver nanoparticles ions. Surprisingly, cold/hot adapted nanozyme exhibited sensitivity both hydrogen-atom transfer single-electron reactions with reducing agents, encompassing all antioxidant species are relevant physiological contexts. Furthermore, visual-based platform integrated smartphone was established successfully applied total capacity detection various temperatures breast cancer patients. will open an avenue research

Language: Английский

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Dual-State Red-Emitting Zinc-Based MOF Accompanied by Dual-Mode and Dual-State Detection: Color Tonality Visual Mode for the Detection of Tetracycline

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 13, 2024

Red-emitting metal-organic frameworks (MOFs) are still mostly based on the use of lanthanides or functionalization with red fluorophores. However, production transition-metal-based MOFs red-emitting is scarce. This work reports synthesis a novel dual-state Zn-based MOF (denoted as UoZ-7) capability to detect target molecules in dual state, solution, and solid paper. UoZ-7 gives strong emission when excited solution state 365 nm ultraviolet (UV) lamp irradiation. Coordination-induced mechanism for enhancement restriction intramolecular rotation occurred ligand within framework structure. was successfully used tetracycline (TC) using dual-mode detection, fluorescence-based ratiometry, color tonality, TC adsorb surface, yellow-greenish emerges due aggregation-induced between UoZ-7. Concurrently, inner filter effect diminishes The detection platform provides simple reliable fast method on-site various environmental biomedical applications. Moreover, will have further luminescence-based

Language: Английский

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Carbon Quantum Dots from Natural Sources as Sustainable Probes for Metal Ion Sensing: Preparation, Characterizations and Applications

Talanta Open, Journal Year: 2024, Volume and Issue: 10, P. 100348 - 100348

Published: Aug. 23, 2024

Language: Английский

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Visual-Based Platform Using Sustainable Intrinsic Fluorescent Zn-Based Metal–Organic Framework for Detection of Folic Acid in Pharmaceutical Formulations

Journal of Inorganic and Organometallic Polymers and Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 19, 2024

Language: Английский

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Pine needle-derived oxidase-like Mn nanozymes: sustainable nanozyme, scalable synthesis, and visual and colorimetric nitrite detection

Microchimica Acta, Journal Year: 2025, Volume and Issue: 192(3)

Published: Feb. 11, 2025

Language: Английский

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Nanomineralzyme as a novel sustainable class of nanozyme: Chalcopyrite-based nanozyme for the visual detection of total antioxidant capacity in citrus fruit

Food Chemistry, Journal Year: 2025, Volume and Issue: 471, P. 142769 - 142769

Published: Jan. 5, 2025

Language: Английский

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Flower-like ag-ZIF nanoparticles with petal-like structures as effective hot/cold-adapted oxidase mimic: Visual color tonality nitrite detection

Food Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 143615 - 143615

Published: Feb. 1, 2025

Language: Английский

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Nanoscale mineral as a novel class enzyme mimic (mineralzyme) with total antioxidant capacity detection: Colorimetric and smartphone-based approaches

Materials Today Chemistry, Journal Year: 2024, Volume and Issue: 40, P. 102262 - 102262

Published: Aug. 23, 2024

Language: Английский

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Lanthanide and functionalization-free dual-state emitting zinc-based MOFs followed by dual-state detection: ratiometric and color-tonality visual detection of tetracycline in solution and on paper in food and environmental samples

Microchimica Acta, Journal Year: 2024, Volume and Issue: 192(1)

Published: Dec. 21, 2024

Language: Английский

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The Multifaceted Role of Tannic Acid: From Its Extraction and Structure to Antibacterial Properties and Applications

Progress in Polymer Science, Journal Year: 2024, Volume and Issue: unknown, P. 101908 - 101908

Published: Dec. 1, 2024

Language: Английский

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