Hydrophobically Modified Polyacrylamide Incorporating Both Hydrophilic and Hydrophobic Units: Enhanced Printability and Stability in Aqueous Ink DOI Creative Commons
Zhi-Rui Liu,

Li‐Lin Tan,

Juan Gao

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(21), P. 5105 - 5105

Published: Oct. 29, 2024

For this research, three hydrophobically modified polyacrylamides, HPAAB, HPAAF, and HPAAS, with multiple hydrophobic monomers were designed, synthesized, used as thickeners in aqueous ink for digital ink-jet printing. The structures characterized by Fourier transform infrared (FTIR) analysis nuclear magnetic resonance (NMR) spectroscopy. viscosity–average molecular weight was determined intrinsic viscosity determination adjusted according to content. critical association concentration (CAC) of polymers measured simultaneously using the apparent method fluorescence spectrum. formation a network structure mechanism are visualized dynamically scanning electron microscope (SEM) at different concentrations. Under same conditions, HPAAB exhibited excellent thickening ability across pH levels, temperatures, shear rates, which is caused longer side chain stronger effect behenyl polyoxyethylene ether methacrylate (BEM) group. Furthermore, an thickener displays significant printability stability, functioning much better than corresponding that uses commercial thickener. This first example associating polyacrylamide, incorporating both hydrophilic units within single chain, thereby serving efficient ink.

Language: Английский

Influence of Alkyl Chain Length on the Performance of Inverse Emulsion Polyacrylamide Fracturing Fluid Thickeners DOI
Ye Zhang, Eryun Yan, Qiaomei Chen

et al.

Industrial & Engineering Chemistry Research, Journal Year: 2024, Volume and Issue: 63(13), P. 5513 - 5526

Published: March 21, 2024

The alkyl chain length of hydrophobic monomers significantly influences the properties associative polymers. In this study, four with varying lengths were copolymerized acrylamide, using inverse emulsion polymerization method. Four polyacrylamides successfully synthesized and characterized infrared spectroscopy, nuclear magnetic resonance (NMR), radius gyration detection, they compared (PAMs) (without monomers). Polymer morphology was analyzed scanning electron microscopy, while rheological assessed a rheometer. Emulsion stability determined by measuring conductivity. Investigation indicate direct correlation between polymer monomer. longer monomer, higher rheology increasing association droplet encapsulation.

Language: Английский

Citations

5

Secondary Utilization of Self-Suspending Proppant's Coating Polymer: Enhance Oil Recovery DOI

Yunxiang Luo,

na li,

Jun Zheng

et al.

Published: Jan. 1, 2024

Language: Английский

Citations

0

Secondary Utilization of Self-Suspending Proppant's Coating Polymer: Enhance Oil Recovery DOI

Yunxiang Luo,

Na Li, Jun Zheng

et al.

Geoenergy Science and Engineering, Journal Year: 2024, Volume and Issue: 243, P. 213301 - 213301

Published: Sept. 10, 2024

Language: Английский

Citations

0

Hydrophobically Modified Polyacrylamide Incorporating Both Hydrophilic and Hydrophobic Units: Enhanced Printability and Stability in Aqueous Ink DOI Creative Commons
Zhi-Rui Liu,

Li‐Lin Tan,

Juan Gao

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(21), P. 5105 - 5105

Published: Oct. 29, 2024

For this research, three hydrophobically modified polyacrylamides, HPAAB, HPAAF, and HPAAS, with multiple hydrophobic monomers were designed, synthesized, used as thickeners in aqueous ink for digital ink-jet printing. The structures characterized by Fourier transform infrared (FTIR) analysis nuclear magnetic resonance (NMR) spectroscopy. viscosity–average molecular weight was determined intrinsic viscosity determination adjusted according to content. critical association concentration (CAC) of polymers measured simultaneously using the apparent method fluorescence spectrum. formation a network structure mechanism are visualized dynamically scanning electron microscope (SEM) at different concentrations. Under same conditions, HPAAB exhibited excellent thickening ability across pH levels, temperatures, shear rates, which is caused longer side chain stronger effect behenyl polyoxyethylene ether methacrylate (BEM) group. Furthermore, an thickener displays significant printability stability, functioning much better than corresponding that uses commercial thickener. This first example associating polyacrylamide, incorporating both hydrophilic units within single chain, thereby serving efficient ink.

Language: Английский

Citations

0