Inorganic Chemistry Communications, Journal Year: 2024, Volume and Issue: unknown, P. 113283 - 113283
Published: Oct. 1, 2024
Language: Английский
Inorganic Chemistry Communications, Journal Year: 2024, Volume and Issue: unknown, P. 113283 - 113283
Published: Oct. 1, 2024
Language: Английский
Applied Organometallic Chemistry, Journal Year: 2025, Volume and Issue: 39(3)
Published: Feb. 25, 2025
ABSTRACT Formation of a tridentate mono‐basic hydrazone‐quinoxalyl ligand was done through condensation quinoxalyl‐2‐carbohydrazide with 2‐hydroxy‐1‐naphthaldehyde (H 2 dip). The coordination capability H dip Ni (II) and V (IV) ions examined at molar ratios 1:1 leading to the synthesis two distinct complexes, Ni(dip) VO(dip), respectively. chemical structure validated by many spectroscopic techniques. characterization included carbon, hydrogen, nitrogen elemental analyses assessments magnetic properties conductivity behavior. inhibited effects (organic molecules) its chelating agents on constrained proliferation three specific bacterial/fungal types, beside established human cancer cell lines, have been evaluated in relation structural impact VO(dip) compared their free research aimed determine nature influence metal chelates binding affinity dip, Ni(dip), for ct‐DNA, that is, calf thymus DNA, depending viscometric/spectrophotometric alterations characters. Furthermore, assessment constants (13.12, 15.19, 14.88 × 10 7 mol −1 dm 3 ), Gibbs energy (−40.21, −44.51, −45.01 kJ chromism modes respectively, used examine interaction mechanisms attributing increased ct‐DNA comparison dip. antioxidant potential within SOD (superoxide dismutase) DPPH (2,2‐diphenyl‐1‐picrylhydrazyl) assays, reporting respectable reactivity. catalysts represented superior catalytic oxidative activity 1,2‐cyclooctene (unsaturated hydrocarbons, CyO) using hydrogen peroxide homogenous manner. At 80°C, yield percentage selective epoxy‐cyclooctane (CyOO) 90% after h 93% acetonitrile (the best solvent) disparity optimum actions these pertained differences electronegativity Lewis's acidity, suggested mechanistic pathway.
Language: Английский
Citations
1Computational Biology and Chemistry, Journal Year: 2024, Volume and Issue: 113, P. 108190 - 108190
Published: Aug. 31, 2024
Language: Английский
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Published: Jan. 1, 2025
Language: Английский
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Published: Jan. 1, 2025
Language: Английский
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0Inorganica Chimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 122692 - 122692
Published: April 1, 2025
Language: Английский
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Published: Sept. 10, 2024
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2Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: unknown, P. 126777 - 126777
Published: Dec. 1, 2024
Language: Английский
Citations
2Inorganic Chemistry Communications, Journal Year: 2024, Volume and Issue: unknown, P. 113283 - 113283
Published: Oct. 1, 2024
Language: Английский
Citations
1