Synthesis and resolution of a 1,1′-biazulene analogue of BINOL DOI Creative Commons

Anthony P. Gee,

Tiberiu-M. Gianga, Gabriele Kociok‐Köhn

et al.

RSC Advances, Journal Year: 2025, Volume and Issue: 15(19), P. 14881 - 14892

Published: Jan. 1, 2025

Biaryls exhibiting axial chirality have been extensively exploited in fields such as asymmetric catalysis, but the biaryl linkage typically consists of benzenoid aromatic rings, with non-benzenoid biaryls being scarce. Here we report first preparation a (non-benzenoid) 1,1'-biazulene-2,2'-diol ("1,1'-BAzOL") enantiopure form and determine its barrier to racemisation. Furthermore transformed into corresponding 2,2'-bis(phosphonate), thereby demonstrating functional group interconversion through cross coupling highlighting potential for diversification.

Language: Английский

Selective and sensitive colourimetric and electrochemical detection of cyanide and its estimation in food materials: A spectroscopic and theoretical study DOI

V. Dharaniprabha,

Kuppanagounder P. Elango

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 141981 - 141981

Published: March 1, 2025

Language: Английский

Citations

0
Synthesis and resolution of a 1,1′-biazulene analogue of BINOL DOI Creative Commons

Anthony P. Gee,

Tiberiu-M. Gianga, Gabriele Kociok‐Köhn

et al.

RSC Advances, Journal Year: 2025, Volume and Issue: 15(19), P. 14881 - 14892

Published: Jan. 1, 2025

Biaryls exhibiting axial chirality have been extensively exploited in fields such as asymmetric catalysis, but the biaryl linkage typically consists of benzenoid aromatic rings, with non-benzenoid biaryls being scarce. Here we report first preparation a (non-benzenoid) 1,1'-biazulene-2,2'-diol ("1,1'-BAzOL") enantiopure form and determine its barrier to racemisation. Furthermore transformed into corresponding 2,2'-bis(phosphonate), thereby demonstrating functional group interconversion through cross coupling highlighting potential for diversification.

Language: Английский

Citations

0