Journal of Coordination Chemistry,
Journal Year:
2023,
Volume and Issue:
76(9-10), P. 1157 - 1172
Published: May 19, 2023
Centrosymmetric
homopolynuclear
Cu(II)
and
Co(II)
chelated
complexes,
[Cu2(L)(H2O)2]
(1)
[Co4(L)(μ-OAc)2(CH3OH)4(OAC)2]⋅2CH2Cl2
(2),
were
synthesized
using
a
new
symmetrical
methoxy-disubstituted
bis(salamo)-type
ligand,
H4L,
with
salts
in
organic
solvents.
Complexes
1
2
structurally
characterized
by
single-crystal
X-ray
crystallography.
The
results
indicated
that
is
five-coordinate
dinuclear
structure
containing
tetranuclear
complex
two
distinct
six-coordinate
environments.
Furthermore,
pack
into
three-dimensional
two-dimensional
extended
networks,
respectively.
UV–Vis
spectra,
IR
Hirshfeld
surface
analyses
of
the
complexes
carried
out
to
further
characterize
coordination
between
H4L
metal(II)
ions.
Fluorescence
methods
used
interrogate
coordination,
where
changes
emission
varied
amounts
ligand
supported
solution-phase
ratios
ion
1:2
1:4,
Journal of Coordination Chemistry,
Journal Year:
2023,
Volume and Issue:
76(9-10), P. 1157 - 1172
Published: May 19, 2023
Centrosymmetric
homopolynuclear
Cu(II)
and
Co(II)
chelated
complexes,
[Cu2(L)(H2O)2]
(1)
[Co4(L)(μ-OAc)2(CH3OH)4(OAC)2]⋅2CH2Cl2
(2),
were
synthesized
using
a
new
symmetrical
methoxy-disubstituted
bis(salamo)-type
ligand,
H4L,
with
salts
in
organic
solvents.
Complexes
1
2
structurally
characterized
by
single-crystal
X-ray
crystallography.
The
results
indicated
that
is
five-coordinate
dinuclear
structure
containing
tetranuclear
complex
two
distinct
six-coordinate
environments.
Furthermore,
pack
into
three-dimensional
two-dimensional
extended
networks,
respectively.
UV–Vis
spectra,
IR
Hirshfeld
surface
analyses
of
the
complexes
carried
out
to
further
characterize
coordination
between
H4L
metal(II)
ions.
Fluorescence
methods
used
interrogate
coordination,
where
changes
emission
varied
amounts
ligand
supported
solution-phase
ratios
ion
1:2
1:4,