(μ-Pentafluorophenylthiorato)(o-bis(diphenylphosphino)benzene) Silver(I) Dimer

Molbank, Journal Year: 2025, Volume and Issue: 2025(1), P. M1970 - M1970

Published: Feb. 20, 2025

This study reports the synthesis and characterization of a novel thiolate-bridged heteroleptic dinuclear silver(I) complex, [Ag(μ-C6F5S)(dppbz)]2, incorporating o-bis(diphenylphosphino)benzene (dppbz). The complex was synthesized in high yield via reaction oxide with pentafluorothiophenol dppbz. Single crystal X-ray diffraction analysis revealed distorted tetrahedral structure an Ag2S2 core, where each Ag atom is coordinated by Ag…Ag distance (3.2652(3) Å) suggests weak argentophilic interaction. Notably, uncommon intermolecular fluorine-fluorine contact observed, likely stabilized hydrogen bonding stabilizing structure. shows luminescence under UV radiation emission maximum at 514 nm.

Language: Английский

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O-H⋯N, C-H⋯O, and O-H⋯π hydrogen bonds between water and 2-methylpyridine

Journal of Molecular Liquids, Journal Year: 2025, Volume and Issue: unknown, P. 127593 - 127593

Published: April 1, 2025

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Testing the reality of F··F halogen bonds

Chemical Physics Letters, Journal Year: 2024, Volume and Issue: 860, P. 141822 - 141822

Published: Dec. 12, 2024

Language: Английский

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