Integration of 1,2,3-Triazine N-Oxide and 2,4,6-Trinitroaniline Moieties for the Design of Heat-Resistant Energetic Compounds DOI

Wenhao Cui,

Haoran Xu, Zhiwen Ye

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 7, 2025

Heat-resistant energetic compounds are of great importance in the field material chemistry. Here, we report a practical synthesis series fused-ring via combination 1,2,3-triazine N-oxide and 2,4,6-trinitroaniline moieties. Starting from known compound 4,6-diamino-2-chloropyrimidine-5-carbonitrile (1), nucleophilic substitution followed by one-step nitration introduced three nitro groups onto benzene ring moiety, simultaneously. The resulting 4-7 exhibited high decomposition temperature (Td > 250 °C) as well relatively good detonation properties low sensitivities.

Language: Английский

π-π2max: Bridging Molecular Characteristics to Crystal Packing in Nitro-Containing Two-Dimensional Energetic Materials DOI Creative Commons
Xiaokai He, Chao Chen, Zhixiang Zhang

et al.

Defence Technology, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 1, 2025

Language: Английский

Citations

0
Integration of 1,2,3-Triazine N-Oxide and 2,4,6-Trinitroaniline Moieties for the Design of Heat-Resistant Energetic Compounds DOI

Wenhao Cui,

Haoran Xu, Zhiwen Ye

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 7, 2025

Heat-resistant energetic compounds are of great importance in the field material chemistry. Here, we report a practical synthesis series fused-ring via combination 1,2,3-triazine N-oxide and 2,4,6-trinitroaniline moieties. Starting from known compound 4,6-diamino-2-chloropyrimidine-5-carbonitrile (1), nucleophilic substitution followed by one-step nitration introduced three nitro groups onto benzene ring moiety, simultaneously. The resulting 4-7 exhibited high decomposition temperature (Td > 250 °C) as well relatively good detonation properties low sensitivities.

Language: Английский

Citations

0