Metal-organic frameworks for biomedical applications: A review

Advances in Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 331, P. 103210 - 103210

Published: June 5, 2024

Language: Английский

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Electrochemical Conversion of CO2 Using Metal-Organic Frameworks-Based Materials: A Review on Recent Progresses and Outlooks

Chemosphere, Journal Year: 2024, Volume and Issue: 365, P. 143312 - 143312

Published: Sept. 10, 2024

Language: Английский

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Green Ammonia Unleashed: Cutting-Edge Electrochemical Synthesis, Catalyst Innovations, and SOFC Integration for a Sustainable Energy Future─A Review and Perspectives

Energy & Fuels, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 14, 2025

Green ammonia emerges as an important candidate for the transition toward sustainable energy solutions to address global imperative carbon neutrality. The current review explores electrochemical synthesis of and its integration into Solid Oxide Fuel Cells (SOFCs) while also challenging traditional method, known substantial consumption considerable footprint. specific advances covered in this article include lithium cycling, electromagnetic fields, plasma technology used ammonia. Innovations have resulted from development efficient single-atom, transition-metal- alloy-based bismuth-based catalysts. In background, paper analyzes advancements made application within SOFCs, emphasizing advancement nickel-based catalysts decomposition technologies that improve both efficiency durability these systems operational settings. This presents a compelling perspective on their potential critical challenges storage, emissions reduction, low-carbon future.

Language: Английский

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Evaluation of the Potential of a Ratiometric Fluorescence Sensor for Sensitively Recognizing 1-Hydroxypyrene in Real Urine Samples Based on a Stable Zn-MOF

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 20, 2025

In the work, a 3D Zn-based MOF, [CH3(NH2)2][Zn2(obdb)(OH)]·DMF (compound 1) has been formed successfully through self-assembly of Zn(II) ion and organic linker H4obdb (4',4‴-oxybis[1,1'-biphenyl]-3,5-dicarboxylic acid, high-symmetrical tetra-carboxylate ligand) under solvothermal conditions. structure compound 1, Zn symmetry-generated ones constitute tetra-nuclear cluster [Zn4(μ2-COO)8(μ3-OH)2], then by coordination clusters linkers, stair-like framework containing 1D rectangular channel with porosity 47.3% is generated. Interestingly, 1 confirmed to possess striking air pH stability. Noteworthily, results detecting studies certify that can serve as prospective ratiometric fluorescence sensor for selectively recognizing 1-hydroxypyrene (1-HP) among diverse urine components promising probe Asp from other 11 kinds amino acids depended on "turn-off" effects decorated high quenching efficiencies (97.5% 1-HP 94.3% Asp) outstanding sensitivity Ksv values 1.84 × 105 M-1 1.41 104 in DMF-H2O binary system. Amazingly, sensing capacities maintain similar levels fresh human compared those system, giving 5.79 1.72 Asp.

Language: Английский

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Dual-Mode Sensor Based on a Single-Atom Cobalt Catalyst for Simultaneous Electrochemical and Colorimetric Detection of Bioactive Small Molecules

Analytical Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 9, 2025

The design of single-atom catalysts with dual functions has emerged as a promising strategy for developing high-performance sensing platforms. Herein, we reported facile host-guest synthesizing an atomically dispersed Co catalyst (Co-N-C), where atoms were uniformly anchored on the N-doped carbon matrix derived from zeolitic imidazolate framework-8. as-prepared Co-N-C exhibits both excellent electrochemical and peroxidase-like colorimetric activities toward detection three important bioactive small molecules, ascorbic acid (AA), dopamine (DA), uric (UA). sensor demonstrated ultrahigh sensitivity limits 4.83, 1.36, 0.371 μM AA, DA, UA, respectively, along outstanding selectivity against common interferents stable performance. Meanwhile, method also showed analytical performance 2.24 3.09 2.97 results indicate that electronic modulation through precise nitrogen coordination enhances affinity Co-Nx target reactants, thereby promoting adsorption electron transfer throughout reaction. This improves catalytic efficiency selectivity, establishing dual-catalytic functionality material biosensing applications.

Language: Английский

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Mechanism of pesticide thiram reversibly inhibiting of Pt single-atom peroxidase-mimicking nanozyme and its application in colorimetric sensing thiram

Talanta, Journal Year: 2025, Volume and Issue: unknown, P. 128201 - 128201

Published: April 1, 2025

Language: Английский

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A comprehensive review on the rational design of MOF-based heterogeneous catalysts for the classic Biginelli reaction

Polyhedron, Journal Year: 2025, Volume and Issue: unknown, P. 117570 - 117570

Published: April 1, 2025

Language: Английский

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Potent Noble Metal–Nickel Oxide Interaction: A Strategy for Improved Oxygen Reduction Reaction via Engineering the Electronic Structure

The Journal of Physical Chemistry C, Journal Year: 2024, Volume and Issue: 128(28), P. 11562 - 11571

Published: July 2, 2024

Language: Английский

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Enhanced oxygen evolution performance by single metal (tungsten, nickel and manganese) atom oxides anchored nanorods of CeO2-MnO2-rGO as electrocatalysts

Journal of the Taiwan Institute of Chemical Engineers, Journal Year: 2024, Volume and Issue: 165, P. 105800 - 105800

Published: Oct. 22, 2024

Language: Английский

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Multifunctional metal-organic materials of 9-anthracenyl-4′-benzoate with Zn(II), Co(II), and Mn(II) as highly efficient catalysts for electrochemical water-splitting and photochemical dye-degradation

Materials Today Chemistry, Journal Year: 2024, Volume and Issue: 43, P. 102464 - 102464

Published: Dec. 11, 2024

Language: Английский

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