Prussian blue analogues for potassium-ion batteries: insights into the electrochemical mechanisms DOI Creative Commons
Phuong Nam Le Pham, Romain Wernert,

Maëlle Cahu

et al.

Journal of Materials Chemistry A, Journal Year: 2023, Volume and Issue: 11(6), P. 3091 - 3104

Published: Jan. 1, 2023

A comprehensive evaluation of a Mn–Fe-based Prussian Blue Analogue suited as positive electrode material for K-ion batteries is made by complementary ex situ and operando characterization techniques – showing fundamental promises limitations.

Language: Английский

Highly Crystalline Prussian Blue for Kinetics Enhanced Potassium Storage DOI

Wenli Shu,

Meng Huang,

Lishan Geng

et al.

Small, Journal Year: 2023, Volume and Issue: 19(28)

Published: April 4, 2023

Abstract Prussian blue analogs (PBAs) are promising cathode materials for potassium‐ion batteries (KIBs) owing to their large open framework structure. As the K + migration rate and storage sites rely highly on periodic lattice arrangement, it is rather important guarantee high crystallinity of PBAs. Herein, crystalline 2 Fe[Fe(CN) 6 ] (KFeHCF‐E) synthesized by coprecipitation, adopting ethylenediaminetetraacetic acid dipotassium salt as a chelating agent. result, an excellent capability ultra‐long lifespan (5000 cycles at 100 mA g −1 with 61.3% capacity maintenance) achieved when tested in KIBs. The highest 10 −9 cm s bulk phase determined galvanostatic intermittent titration technique. Remarkably, robust structure reversible solid‐phase mechanism KFeHCF‐E proved situ XRD. This work offers simple optimization method developing high‐performance PBAs advanced

Language: Английский

Citations

37
Cathode materials for calcium‐ion batteries: Current status and prospects DOI Creative Commons
Yuhan Wu,

Ziqi Zhao,

Xiaorui Hao

et al.

Carbon Neutralization, Journal Year: 2023, Volume and Issue: 2(5), P. 551 - 573

Published: Aug. 27, 2023

Abstract In the post‐lithium‐ion battery era, calcium‐ion batteries (CIBs) have aroused extensive attention because of their strong cost competitiveness, low standard redox potentials, and high safety. However, related research is progressing slowly due to constraints development electrode materials. The large ionic radius Ca 2+ especially increases challenge design cathode materials for reversible uptake/removal. Despite inspiring achievements, various challenges still need be further resolved. Here, this review systematically summarizes recent advances in CIB materials, including Prussian blue its analogues, metal oxides, chalcogenides, polyanionic compounds, organic We first provide a brief introduction CIBs compare advantages with other technologies. Then, preparation methods are introduced, breakthrough investigations highlighted. Finally, some possible directions discussed promote emerging technology.

Language: Английский

Citations

37
Constructing MOF-derived V2O5 as advanced cathodes for aqueous zinc ion batteries DOI
Chengjie Yin, Hui Wang,

Cheng‐Ling Pan

et al.

Journal of Energy Storage, Journal Year: 2023, Volume and Issue: 73, P. 109045 - 109045

Published: Sept. 22, 2023

Language: Английский

Citations

32
Noncovalent interactions engineering construct the fast-kinetics organic cathode for room/low-temperature aqueous zinc-ion battery DOI

Ruanye Zhang,

Hai Xu,

Derong Luo

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 458, P. 141336 - 141336

Published: Jan. 6, 2023

Language: Английский

Citations

28
Prussian blue analogues for potassium-ion batteries: insights into the electrochemical mechanisms DOI Creative Commons
Phuong Nam Le Pham, Romain Wernert,

Maëlle Cahu

et al.

Journal of Materials Chemistry A, Journal Year: 2023, Volume and Issue: 11(6), P. 3091 - 3104

Published: Jan. 1, 2023

A comprehensive evaluation of a Mn–Fe-based Prussian Blue Analogue suited as positive electrode material for K-ion batteries is made by complementary ex situ and operando characterization techniques – showing fundamental promises limitations.

Language: Английский

Citations

26