HAT-CN-Modified Spiro-OMeTAD Realizes Efficient Perovskite Solar Cells DOI

Junbo Yang,

Zheng Xiao,

Zhu Ma

et al.

ACS Applied Energy Materials, Journal Year: 2024, Volume and Issue: 8(1), P. 141 - 150

Published: Dec. 31, 2024

Hole transport materials are essential for facilitating the movement of holes between perovskite layer and electrode. Spiro-OMeTAD (2,2′,7,7′-tetrakis (N,N-di-p-methoxyphenylamine) 9,9′-spirobifluorene) is extensively utilized as a hole material among various alternatives. However, spiro-OMeTAD itself has short plate with low mobility conductivity. We report solar cell n-i-p type HAT-CN-modified layer, while HAT-CN exhibits metalloid properties. The Fermi level shifted downward, which promotes migration from to layer. buffer reduces roughness film, thereby improving surface contact metal power conversion efficiency device, was modified on increased 20.45 21.65%. Additionally, hysteresis index decreased 15.99 11.37% device stability improved. This strategy effectively enhances both charge carrier hydrophobicity achievement efficient stable cells.

Language: Английский

Optimizing the Buried Interface in Flexible Perovskite Solar Cells to Achieve Over 24% Efficiency and Long‐Term Stability DOI

Ruoyao Xu,

Fang Pan,

Jinyu Chen

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 36(7)

Published: Oct. 7, 2023

The buried interface of the perovskite layer has a profound influence on its film morphology, defect formation, and aging resistance from outset, therefore, significantly affects quality device performance derived solar cells. Especially for FAPbI

Language: Английский

Citations

76

Mechanical Durability and Flexibility in Perovskite Photovoltaics: Advancements and Applications DOI
Fei Song,

Dexu Zheng,

Jiangshan Feng

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(18)

Published: Jan. 14, 2024

Abstract The remarkable progress in perovskite solar cell (PSC) technology has witnessed a leap efficiency within the past decade. As this continues to mature, flexible PSCs (F‐PSCs) are emerging as pivotal components for wide array of applications, spanning from powering portable electronics and wearable devices integrating seamlessly into electronic textiles large‐scale industrial roofing. F‐PSCs characterized by their lightweight, mechanical flexibility, adaptability cost‐effective roll‐to‐roll manufacturing, hold immense commercial potential. However, persistent concerns regarding overall stability robustness these loom large. This comprehensive review delves recent strides made enhancing F‐PSCs. It covers spectrum crucial aspects, encompassing material optimization, precise crystal grain regulation, film quality enhancement, strategic interface engineering, innovational developed transparent electrodes, judicious substrate selection, integration various functional layers. By collating analyzing dedicated research endeavors, illuminates current landscape addressing challenges surrounding stability. Furthermore, it provides valuable insights obstacles bottlenecks that demand attention innovative solutions field

Language: Английский

Citations

27

Utilizing electrostatic dynamic bonds in zwitterion elastomer for self-curing of flexible perovskite solar cells DOI
Yaohua Wang, Yuanyuan Meng, Chang Liu

et al.

Joule, Journal Year: 2024, Volume and Issue: 8(4), P. 1120 - 1141

Published: Feb. 8, 2024

Language: Английский

Citations

26

Annual research review of perovskite solar cells in 2023 DOI Creative Commons

Qisen Zhou,

Xiaoxuan Liu, Zonghao Liu

et al.

Materials Futures, Journal Year: 2024, Volume and Issue: 3(2), P. 022102 - 022102

Published: April 24, 2024

Abstract Perovskite (PVK) solar cells (PSCs) have garnered considerable research interest owing to their cost-effectiveness and high efficiency. A systematic annual review of the on PSCs is essential for gaining a comprehensive understanding current trends. Herein, analysis papers reporting key findings in 2023 was conducted. Based results, were categorized into six classifications, including regular n–i–p PSCs, inverted p–i–n PVK-based tandem cells, PVK modules, device stability, lead toxicity green solvents. Subsequently, detailed overview summary advancements within each classification presented. Overall, this serves as valuable resource guiding future endeavors field PSCs.

Language: Английский

Citations

20

SnO2 Surface Modification and Perovskite Buried Interface Passivation by 2,5‐Furandicarboxylic Acid for Flexible Perovskite Solar Cells DOI
Qing Sun,

Xiangxin Meng,

Gang Liu

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(45)

Published: May 30, 2024

Abstract Flexible perovskite solar cells (PSCs) have received great attention due to their low weight, high power ratio, and potential applications in wearable electronic products. The efficiency stability of flexible PSCs are directly affected by the carrier extraction transport capabilities electron layer. Herein, efficient prepared through incorporating 2,5‐Furandicarboxylic acid (FDCA) multifunctional intermediate layer between tin oxide (SnO 2 ) perovskite, which can effectively eliminate defects at interfacial increase mobility SnO layer, modify surface shift conduction band upward improve interface charge extraction, passivate buried induce larger crystal growth, establish a bridge collection efficiency. As result, rigid with FDCA display champion conversion (PCE) 24.53% open circuit voltage ( V OC 1.204 V. Furthermore, device achieves PCE 22.10%, preserve 90% its initial after aging for 500 h ambient condition without encapsulation, maintain 81% original 10,000 bending cycles.

Language: Английский

Citations

17

π-Interactions suppression of buried interface defects for efficient and stable inverted perovskite solar cells DOI
Hui Chen, Jiabao Yang, Qi Cao

et al.

Nano Energy, Journal Year: 2023, Volume and Issue: 117, P. 108883 - 108883

Published: Sept. 9, 2023

Language: Английский

Citations

25

Substrate Modifications for Stability Improvements of Flexible Perovskite Solar Cells DOI Creative Commons
Jingyang Lin, Yanling He, Hongbo Mo

et al.

Energy Technology, Journal Year: 2024, Volume and Issue: 12(5)

Published: Jan. 11, 2024

Flexible perovskite solar cells (fPSCs) prepared on flexible plastic substrates exhibit poor stability under illumination in ambient, due to inferior gas barrier properties of substrates. Herein, we investigated effect different modifications the back surface substrate improve ambient. T 80 simulated at maximum power point ambient (ISOS‐L‐1) can be increased from h over 350 with deposition a single layer (by spin‐coating or by atomic (ALD)). While ALD layers resulted best value and significant reduction oxygen transmission rate compared other even for very low film thickness (≈10 nm), simple solution‐processed spin‐on‐glass also enables (more than 4 times) improvement device stability. This work illustrates importance decreasing ingress moisture into fPSCs through substrate.

Language: Английский

Citations

9

Progress in Flexible Perovskite Solar Cells: Paving the Way for Scalable Manufacturing DOI Creative Commons
Dimitar I. Kutsarov, Ehsan Rezaee, J. D.B. Lambert

et al.

Advanced Materials Technologies, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 20, 2025

Abstract The urgency for a sustainable mitigation of the environmental impacts caused by climate change highlights importance renewable energy technologies to fight this challenge. Perovskite solar cells (PSCs) emerge as promising alternative traditional photovoltaic (PV) due their unprecedented increase in efficiency (currently peaking at 26.95%) and long‐term stability proven successful completion industry relevant International Electrotechnical Commission (IEC) testing standards. Flexible PSCs (f‐PSCs) offer significant advantages such lightweight high power‐per‐weight ratio, mechanical flexibility, throughput roll‐to‐roll (R2R) manufacturing. These make f‐PSCs ideal implementation various applications areas, wearable electronics, portable devices, space PV, building‐ or automotive‐integrated PVs, more. Notably, efficiencies over 23% now mark milestone f‐PSCs, demonstrating competitiveness with rigid panels. This review explores breakthroughs focusing on flexible substrates, electrode materials, perovskite inks, encapsulation strategies. It also covers recent advancements studies fabricated scalable deposition methods emphasizes interfacial engineering enhancing durability. concludes summary key findings, remaining challenges, perspectives market uptake f‐PSCs.

Language: Английский

Citations

1

Influence of F‐containing Materials on Perovskite Solar Cells DOI

Kaiwen Dong,

Lina Zhu,

Guangyue Yang

et al.

ChemSusChem, Journal Year: 2024, Volume and Issue: 17(21)

Published: May 21, 2024

Abstract Perovskite solar cells (PSCs) are usually modified and passivated to improve their performance stability. The interface modification bulk doping the two basic strategies. Fluorine (F)‐containing materials highly favored because of unique hydrophobicity coordination ability. This review discusses characteristics F, principles improving photovoltaic stability PSC devices using F‐containing materials. We systematically summarized latest progress in application achieve efficient stable PSCs on several key layers. It is believed that this work will afford significant understanding inspirations toward future directions PSCs, provide profound insights for development PSCs.

Language: Английский

Citations

5

Enhancing efficiency and stability of inverted perovskite solar cells through synergistic suppression of multiple defects via poly(ionic liquid)-buried interface modification DOI

Yijun Bai,

Tong Wang, Jiabao Yang

et al.

Journal of Material Science and Technology, Journal Year: 2024, Volume and Issue: 212, P. 281 - 288

Published: June 28, 2024

Language: Английский

Citations

5