Recent strategies for constructing hierarchical multicomponent nanoparticles/metal–organic framework hybrids and their applications DOI Creative Commons
Tran Minh Ngoc, Anh Ngoc Nguyen, Jung‐Eun Bae

et al.

Nanoscale Advances, Journal Year: 2023, Volume and Issue: 5(14), P. 3589 - 3605

Published: Jan. 1, 2023

Recent strategies for the controllable encapsulation of nanoparticles within nanospaces metal–organic frameworks (NPNS@MOF) with hierarchical architectures, intrinsic properties, superior activities, and practical applicabilities are summarized.

Language: Английский

Research Progress on the Application of MOF and MOF‐Based Materials in Nitrogen Reduction DOI
Ying Zhu,

Houqiang Ji,

Tianyu Huang

et al.

Advanced Sustainable Systems, Journal Year: 2024, Volume and Issue: unknown

Published: June 3, 2024

Abstract Electrocatalytic and photocatalytic nitrogen fixation have become new ways to achieve green reduction because of their environmentally friendly cost‐effective characteristics. At present, there has been an increasing curiosity about using metal‐organic frameworks (MOFs) for photocatalysis electrocatalysis. However, electrocatalytic ammonia production is still not practical applications. Having a thorough understanding necessary the advancement applications development highly efficient catalysts in future. The catalytic activity MOF itself limited. By adjusting exposure active sites through low‐temperature calcination solvent addition, photogenerated carrier recombination inhibited, adsorption activation N 2 are enhanced, improving its performance This review examines reported photocatalysts, electrocatalysts, photoelectrocatalysts based on MOFs associated materials. underlying mechanism electrocatalysis elucidated. Additionally, inclusive survey related materials as reaction (NRR) presented, with representative examples discussed. Finally, research progress MOF‐based summarized prospected.

Language: Английский

Citations

6
In Situ-Generated Hollow CoFe-LDH/Co-MOF Heterostructure Nanorod Arrays for Oxygen Evolution Reaction DOI

Guoying Yang,

Yijin Song,

Song‐De Han

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(12), P. 5634 - 5641

Published: March 11, 2024

Assembling a heterostructure is an effective strategy for enhancing the electrocatalytic activity of hybrid materials. Herein, CoFe-layered double hydroxide and Co-metal-organic framework (CoFe-LDH/Co-MOF) hollow nanorod arrays are synthesized. First, [Co(DIPL)(H

Language: Английский

Citations

5
Structural and Phase Engineering of a Hierarchical 2D–2D Nickel MOF/Hydroxide‐Derived Ni0.85Se/NiTe2 Heterointerface for Robust HER, OER, and Overall Water Splitting DOI
Ishwor Pathak, Sampath Prabhakaran, Debendra Acharya

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 10, 2024

The development of a nonnoble metal-based cost-effective, efficient, and durable bifunctional electrocatalyst is crucial to achieving the goal carbon neutrality. In this study, structural interfacial engineering approach employed design 2D-2D hierarchical nickel MOF/nickel hydroxide-derived selenide/nickel telluride dual-phase material through single-step selenotellurization process. rational highly ordered nanoarchitectures provides well-defined voids ample pathways for ion diffusion. Furthermore, works synergistically at heterojunctions, providing local enrichment mechanism catalytic As result, Ni

Language: Английский

Citations

5
Water-regulated 2D Ni-MOF-derived heat-sheared Nano-Ni@TC for efficient hydrogen evolution DOI
Qianwei Chen,

Fan Liu,

Wenqian Liu

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 64, P. 389 - 397

Published: March 28, 2024

Language: Английский

Citations

4
Integrated Heterogeneous Engineering with the Vacancy Defect of Porous CoPv-MoxPv Nanosheets for an Accelerated Hydrogen Evolution Reaction DOI
Qian Long, Yao Zhu, Huiting Hu

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(20), P. 9346 - 9354

Published: May 8, 2024

Electrochemical water splitting is a possible way of realizing sustainable and clean hydrogen production but challenging, because highly active durable electrocatalyst essential. In this work, we integrated heterogeneous engineering vacancy defect strategies to design fabricate heterostructure (CoPv-MoxPv/CNT) with abundant phosphorus vacancies attached carbon nanotubes (CNTs). The defects enabled the optimization electronic structure; thereby, electron-rich low-valent metal sites enhanced ability nonmetallic P capture proton H. Meanwhile, interface between bimetallic phosphides CNTs realized rapid electron transfer. addition, Co, Mo, species in electrocatalytic process exposed increased amounts featuring porous nanosheet structures, which facilitated adsorption reaction intermediates thus evolution performance. particular, optimized CoPv-MoxPv/CNT catalyst possesses an overpotential 138 mV at current density 10 mA cm–2 long-term stability for 24 h. This work offers insights possibilities exploration transition metal-based electrocatalysts through combining multiple synergistic strategies.

Language: Английский

Citations

4
Rational Design of Bimetal Nanoparticles Anchored Hierarchical Carbon Nanospheres with Abundant Active Sites for High-Performance Liquid/Flexible Zinc-Air Batteries DOI

Dingsheng Yuan,

Li-Juan Peng,

Dan Zhu

et al.

Published: Jan. 1, 2025

The development of highly active bifunctional electrocatalysts is crucial to the sluggish oxygen reduction reaction/oxygen evolution reaction (ORR/OER) for efficient wearable Zn–air batteries (ZAB). Fe-Nx-C moieties anchored on carbon supports emerge as a desirable alternative ORR catalysts but its OER activity suffers from low catalytic performance and stability. Herein, N-doped carbon-encapsulated Fe3C MnO nanoparticles composite (FeMn-NC) was developed using simple one-step pyrolysis self-sacrificial template. obtained FeMn-NC possess hierarchical porous structure with large specific surface area rich pyridinic N, which are favorable exposure sites. introduction Fe3C/MnO interface can regulate charge redistribution promote ORR/OER kinetics, confirmed by theoretical calculations. exhibits an excellent in alkaline electrolytes.The assembled liquid ZAB cathode achieve ultrahigh capacity 831.7 mAh g-1 charge-discharged stability up 800 h at 10 mA cm⁻² (2400 cycles). Furthermore, corresponding flexible solid-state provides stable open-circuit voltage 1.50 V 676.1 g−1 1.0 cm-2 good cycling This work offers strategy synthesize materials properties, be applied other electrochemical energy devices.

Language: Английский

Citations

0
Recent advances in platinum group metallenes: From synthesis to energy-related electrocatalytic application DOI

Zi‐Han Yuan,

Tianjiao Wang,

Bin Sun

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125041 - 125041

Published: Jan. 1, 2025

Language: Английский

Citations

0
Fe, Co, and Ni co-doped nitrogen-doped carbon nanotubes for the electrocatalytic oxygen reduction reaction DOI
Haitao Huang, Zhijie Chen, Haijin Li

et al.

Catalysis Science & Technology, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The creation of efficient non-precious metals is crucial for advancing electrochemical systems used in energy conversion and storage technologies.

Language: Английский

Citations

0
In-Situ Synthesis of Co-Tin Heterostructure Composite for Efficient Oxygen Reduction Reaction DOI
Jiannan Cai,

Fanglin Hu,

Qingshan Zhu

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0
Strategies for the preparation of MOFs-based composites and their research progress in electrocatalysis DOI
Tian Zhao, Fuli Luo, Pengcheng Xiao

et al.

Microporous and Mesoporous Materials, Journal Year: 2025, Volume and Issue: unknown, P. 113560 - 113560

Published: Feb. 1, 2025

Language: Английский

Citations

0