Nano Energy, Journal Year: 2024, Volume and Issue: unknown, P. 110263 - 110263
Published: Sept. 1, 2024
Language: Английский
Nano Energy, Journal Year: 2024, Volume and Issue: unknown, P. 110263 - 110263
Published: Sept. 1, 2024
Language: Английский
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: April 8, 2024
Abstract Electrocatalytic nitrate reduction reaction (NO 3 RR) driven by renewable energy is a promising technology for the removal of nitrate‐containing wastewater. However, sluggish kinetics resulted from complex proton‐coupled electron transfer and various intermediates remain key barriers large‐scale application NO RR. Herein, tactic reported to raise rate RR increase selectivity N 2 using bimetal catalyst: Co inclined act on steps needed in process, rate‐determining step (RDS: *NO , asterisk means intermediates) subsequent *N hydrogenation as well Fe exhibits efficient activity selectivity‐ determining (SDS: then ) via relay catalysis mechanism. A efficiency 78.5% an ultra‐long cycle stability 60 cycles (12 h per cycle) are achieved FeCo alloy confined with nitrogen‐doped porous carbon nanofibers (FeCo‐NPCNFs). DFT calculations unveil that introduction active site not only regulates d‐band center alloy, optimizes adsorption intermediates, but also has strong capacity supply hydrogen species. Clearly, this study elucidates effects bimetallic performance electrocatalytic offers avenues designing Fe‐based catalysts realize nitrogen‐neutral cycle.
Language: Английский
Citations
49Nano Research, Journal Year: 2023, Volume and Issue: 17(4), P. 2276 - 2282
Published: Oct. 18, 2023
Language: Английский
Citations
37Nano Energy, Journal Year: 2023, Volume and Issue: 117, P. 108840 - 108840
Published: Aug. 29, 2023
Language: Английский
Citations
32Nano Energy, Journal Year: 2023, Volume and Issue: 116, P. 108818 - 108818
Published: Aug. 22, 2023
Language: Английский
Citations
27Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148640 - 148640
Published: Jan. 8, 2024
Language: Английский
Citations
17ACS Materials Letters, Journal Year: 2024, Volume and Issue: 6(7), P. 2591 - 2598
Published: May 28, 2024
Electrocatalytic reduction of nitrate (NO3–) in waste streams to valuable ammonia under ambient conditions is a green route for remediation. However, efficient catalysts are required this multistep proton coupled electron transfer reaction. This work presented tandem catalyst composed N-doped carbon layer coated Co3O4 with CuOx as highly and selective electrocatalyst NO3– NH3 at low onset potential. The catalysis → NO2– over the two synergistical sites situ generated metallic Cu was verified by experiments theoretical calculations. Benefiting from active sites, exhibited an yield rate 3.23 mg h–1 cm–2 Faradaic efficiency 93.77% ultralow potential −0.1 V versus RHE. opens new avenue design electrocatalytic reduction.
Language: Английский
Citations
14Nano Energy, Journal Year: 2024, Volume and Issue: 133, P. 110463 - 110463
Published: Nov. 10, 2024
Language: Английский
Citations
12Nano Energy, Journal Year: 2023, Volume and Issue: 115, P. 108688 - 108688
Published: July 12, 2023
Language: Английский
Citations
19Nano Energy, Journal Year: 2023, Volume and Issue: 116, P. 108791 - 108791
Published: Aug. 16, 2023
Language: Английский
Citations
16Nano Energy, Journal Year: 2024, Volume and Issue: 130, P. 110084 - 110084
Published: Aug. 3, 2024
Language: Английский
Citations
6