ACS Nano,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 19, 2024
Triboelectric
nanogenerators
(TENGs)
have
garnered
significant
attention
for
mechanical
energy
harvesting,
self-powered
sensing,
and
human-machine
interaction.
However,
their
performance
is
often
constrained
by
materials
that
lack
sufficient
robustness,
self-healing
capability,
adaptability
to
environmental
extremes.
Eutectogels,
with
inherent
ionic
conductivity,
thermal
stability,
sustainability,
offer
an
appealing
alternative
as
flexible
TENG
electrodes,
yet
they
typically
suffer
from
weak
damage
endurance
insufficient
capability.
To
overcome
these
challenges,
here,
we
introduce
internal-external
dual
reinforcement
strategy
(IEDRS)
enhances
internal
bonding
dynamics
within
the
eutectogel
matrix,
composed
of
glycidyl
methacrylate
deep
eutectic
solvent,
integrates
plant-derived
lignin
external
reinforcer.
Notably,
resultant
eutectogel,
named
GLCL,
exhibits
collection
merits
including
superior
robustness
(1.53
MPa
tensile
stress
1.85
MJ/m
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(31)
Published: May 17, 2024
Abstract
Electronic
skin
(e‐skin),
a
skin‐like
wearable
electronic
device,
holds
great
promise
in
the
fields
of
telemedicine
and
personalized
healthcare
because
its
good
flexibility,
biocompatibility,
conformability,
sensing
performance.
E‐skin
can
monitor
various
health
indicators
human
body
real
time
over
long
term,
including
physical
(exercise,
respiration,
blood
pressure,
etc.)
chemical
(saliva,
sweat,
urine,
etc.).
In
recent
years,
development
materials,
analysis,
manufacturing
technologies
has
promoted
significant
e‐skin,
laying
foundation
for
application
next‐generation
medical
devices.
Herein,
properties
required
e‐skin
monitoring
devices
to
achieve
long‐term
precise
summarize
several
detectable
field
are
discussed.
Subsequently,
applications
integrated
systems
reviewed.
Finally,
current
challenges
future
directions
this
This
review
is
expected
generate
interest
inspiration
improvement
systems.
Nano-Micro Letters,
Journal Year:
2024,
Volume and Issue:
16(1)
Published: May 31, 2024
Abstract
The
rapid
development
of
the
Internet
Things
and
artificial
intelligence
technologies
has
increased
need
for
wearable,
portable,
self-powered
flexible
sensing
devices.
Triboelectric
nanogenerators
(TENGs)
based
on
gel
materials
(with
excellent
conductivity,
mechanical
tunability,
environmental
adaptability,
biocompatibility)
are
considered
an
advanced
approach
developing
a
new
generation
sensors.
This
review
comprehensively
summarizes
recent
advances
in
gel-based
TENGs
sensors,
covering
their
principles,
properties,
applications.
Based
requirements
working
mechanism
characteristic
advantages
gels
introduced.
Design
strategies
performance
optimization
hydrogel-,
organogel-,
aerogel-based
systematically
summarized.
In
addition,
applications
human
motion
sensing,
tactile
health
monitoring,
human–machine
interaction,
other
related
fields
Finally,
challenges
discussed,
feasible
proposed
to
guide
future
research.
Advanced Healthcare Materials,
Journal Year:
2024,
Volume and Issue:
13(17)
Published: April 3, 2024
Abstract
Burns
can
cause
severe
damage
to
the
skin
due
bacterial
infection
and
inflammation.
Although
conductive
hydrogels
as
electroactive
burn‐wound
dressings
achieve
remarkable
effects
on
accelerating
wound
healing,
issues
such
imbalance
between
their
high
conductivity
mechanical
properties,
easy
dehydration,
low
transparency
must
be
addressed.
Herein,
a
double‐network
eutectogel
is
fabricated
by
integrating
polymerizable
deep
eutectic
solvents
(PDESs)including
acrylamide/choline
chloride/glycerol
(acrylamide‐polymerization
crosslink)
thiolated
hyaluronic
acid
(disulfide‐bonding
crosslink).
The
introduction
of
PDESs
provides
with
(up
0.25
S·m
−1
)
strength
(tensile
strain
59–77%)
simulating
those
natural
human
skin,
well
satisfactory
tissue
adhesiveness,
self‐healing
ability,
antibacterial
properties.
When
combined
exogenous
electrical
stimulation,
exhibits
ability
reduce
inflammation,
stimulate
cell
proliferation
migration,
promote
collagen
deposition
angiogenesis,
facilitate
remodeling.
This
shows
great
potential
dressing
for
healing
major
burn
wounds.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(25)
Published: April 4, 2024
Hydrogel-based
electronics
have
inherent
similarities
to
biological
tissues
and
hold
potential
for
wearable
applications.
However,
low
conductivity,
poor
stretchability,
nonpersonalizability,
uncontrollable
dehydration
during
use
limit
their
further
development.
In
this
study,
projection
stereolithography
3D
printing
high-conductive
hydrogel
flexible
passive
wireless
sensing
is
reported.
The
prepared
photocurable
silver-based
rapidly
planarized
into
antenna
shapes
on
substrates
using
surface
stereolithography.
After
partial
dehydration,
silver
flakes
within
the
circuits
form
sufficient
conductive
pathways
achieve
high
conductivity
(387
S
cm
ACS Applied Materials & Interfaces,
Journal Year:
2024,
Volume and Issue:
16(35), P. 46771 - 46788
Published: Aug. 21, 2024
Electronic
skin
(e-skin)
is
considered
as
a
highly
promising
interface
for
human-computer
interaction
systems
and
wearable
electronic
devices.
Through
elaborate
design
assembly
of
various
materials,
it
possesses
multiple
characteristics
similar
to
human
skin,
including
remarkable
flexibility,
stretchability,
sensitivity
temperature
humidity,
biocompatibility,
efficient
interfacial
ion/electron
transport
capabilities.
Here,
we
innovatively
integrate
multifunctional
carbon
quantum
dots
(CQDs),
which
exhibit
conductivity,
antibacterial
properties,
ultraviolet
absorption,
fluorescence
emission,
with
poly(acrylic
acid)
glycerin
(Gly)
into
three-dimensional
network
structure
natural
goatskin
collagen
fibers.
top-down
strategy
enhanced
by
hydrogen
bond
reconstruction,
successfully
fabricated
novel
transparent
e-skin
(PAC-eSkin).
This
exhibited
significant
tensile
properties
(4.94
MPa
strength
263.42%
maximum
breaking
elongation),
while
also
possessing
Young's
modulus
(2.32
MPa).
It
noteworthy
that
the
functionalized
CQDs
used
was
derived
from
discarded
goat
hair,
addition
Gly
gave
PAC-eSkin
excellent
antifreezing
moisturizing
properties.
Due
presence
ultrasmall
CQDs,
creates
channels
within
PAC-eSkin,
could
rapidly
sense
motion
physiological
signals
(with
gauge
factor
(GF)
1.88).
Furthermore,
had
potential
replace
traditional
electrode
patches
real-time
monitoring
electrocardiogram,
electromyogram,
electrooculogram
signals,
higher
SNR
(signal-to-noise
ratio)
25.1
dB.
Additionally,
customizable
size
shape
offer
vast
possibilities
construction
single-electrode
triboelectric
nanogenerator
systems.
We
have
reason
believe
development
this
based
on
CQDs-functionalized
dermal
matrices
can
pave
new
way
innovations
in
human–computer
interfaces
their
sensing
application
diverse
scenarios.
Advanced Energy Materials,
Journal Year:
2024,
Volume and Issue:
14(24)
Published: April 5, 2024
Abstract
Triboelectric
nanogenerators
(TENGs)
are
recognized
for
energy
conversion
efficiency
and
applications
including
electronics
storage
devices.
This
study
introduces
a
groundbreaking
development
in
TENG
by
incorporating
negative
Poisson's
ratio
metamaterials
to
fabricate
auxetic‐assisted
triboelectric
(Auxetic‐TENG),
subversively
overcoming
the
low
power
density
of
traditional
materials.
Subtly,
an
integrated
layer‐by‐layer‐assembly
core–shell
accumulation
strategy
is
employed
create
synclastic
polytetrafluoroethylene
friction
shell‐skeleton,
into
which
positive
nature
collagen
aggregate
(CA)
foam
inwardly
embedded
as
core‐material.
Surprisingly,
on‐demand
introduction
synergy
with
CA
significantly
increases
contact
area
mechanical
absorption
Auxetic‐TENG
under
pressure.
enhancement
electricity
capitalizes
on
contraction
origins
metamaterials,
expansion
characteristics
materials
within
structure,
facilitating
synergistic
compression
stratum.
Consequently,
achieves
open‐circuit
voltage
85
V,
overturning
four
times
compared
conventional
contact–separation
TENG,
4.2
W
m
−2
.
Application
experiments
demonstrate
superior
performance
auxetic‐TENG
various
ratios
stress
conditions,
highlighting
its
potential
real‐time
monitoring
healthcare
applications.
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
34(29)
Published: March 18, 2024
Abstract
Biologically
inspired
peptide‐based
materials,
as
novel
charge
transport
have
gained
increasing
interest
in
bioelectronics
due
to
their
remarkable
electrical
properties
and
inherent
biocompatibility.
Extensive
studies
shown
that
peptides
can
self‐assemble
into
a
variety
of
hierarchical
nanostructures
with
unique
physical
through
supramolecular
interactions.
Therefore,
materials
hold
great
promise
for
applications
emerging
electronic
fields
such
sensing,
energy
harvesting,
storage,
transmission.
Herein,
this
work
proposes
review
article
summarize
the
rational
design
research
progress
devices
bioelectronics.
This
first
introduces
strategies
assembly
mechanism
constructing
high‐performance
devices.
In
following
part,
are
systematically
classified
discussed,
including
sensors,
piezoelectric
nanogenerators,
electrodes,
semiconductors.
Finally,
remaining
challenges
future
perspectives
bioelectronic
presented.
believes
will
provide
inspiration
guidance
development
innovative
smart
field
Nano Energy,
Journal Year:
2024,
Volume and Issue:
128, P. 109960 - 109960
Published: July 3, 2024
The
current
wearable
devices
are
largely
rigid
and
bulky,
which
calls
for
the
development
of
next-generation
soft
biocompatible
technologies.
Another
limitation
is
that
conventional
generally
powered
by
thick
non-compliant
batteries,
hindering
miniaturization
improvement
electronics.
Hydrogels
have
attracted
tremendous
attention
in
field
bioelectronics
due
to
their
tissue-like
properties,
can
minimize
mechanical
mismatch
between
flexible
biological
tissues.
Moreover,
take
advantage
physical
chemical
energy
from
human
body
or
ambient
environment,
such
as
motions,
heat
energy,
biofuel,
water
wind
power
nature,
more
novel
technology
portable
supply
has
been
carried
out,
facilitating
bioelectronics.
In
this
review,
recent
advances
self-powered
based
on
hydrogels
summarized.
Firstly,
excellent
properties
introduced,
including
prominent
self-healing
high
conductivity
incorporation
conductive
polymers
additives,
interfacial
adhesion
functionality,
biocompatibility,
antibacterial
properties.
Then,
several
strategies
harvesting
discussed,
triboelectric
nanogenerators
(TENGs),
piezoelectric
(PENGs),
thermoelectric
(TEGs),
biofuel
cells
(BFCs),
hydrovoltaics,
antennas,
hydrogel-based
batteries.
Next,
some
representative
applications
illustrated
(i.e.,
motion
monitoring,
healthcare
monitoring
therapies,
neural
stimulation
human-machine
interaction).
Finally,
a
brief
summary
outlook
hydrogel
presented.
SusMat,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 24, 2024
Abstract
Ionic
conductive
hydrogels
(ICHs)
prepared
from
natural
bioresources
are
promising
candidates
for
constructing
flexible
electronics
both
commercialization
and
environmental
sustainability
due
to
their
intrinsic
characteristics.
However,
simultaneous
realization
of
high
stiffness,
toughness,
conductivity,
multifunctionality
while
ensuring
processing
simplicity
is
extremely
challenging.
Here,
a
poly(ionic
liquid)
(PIL)‐macromolecule
functionalization
strategy
within
NaOH/urea
system
proposed
construct
high‐performance
versatile
polysaccharide‐based
ICHs
(e.g.,
cellulosic
ICHs).
In
this
strategy,
the
elaborately
designed
“soft”
(PIL
chains)
“hard”
(cellulose
backbone)
structures
as
well
dynamic
covalent
noncovalent
bonds
cross‐linked
networks
endow
hydrogel
with
mechanical
strength
(9.46
±
0.23
MPa
compressive
modulus),
exceptional
stretchability
(214.3%),
toughness
(3.64
0.12
MJ
m
−3
).
Ingeniously,
inherent
design
flexibility,
functional
compatibility
PILs,
exhibit
conductivity
(6.54
0.17
mS
cm
−1
),
self‐healing
ability
(94.5%
2.0%
efficiency),
antibacterial
properties,
freezing
resistance,
water
retention,
recyclability.
Interestingly,
extended
fabricate
diverse
various
polysaccharides,
including
agar,
alginate,
hyaluronic
acid,
guar
gum.
addition,
multimodal
sensing
(strain,
temperature,
humidity)
realized
based
on
stimulus‐responsive
characteristics
hydrogels.
This
opens
new
perspectives
biomass‐based
beyond.