Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114604 - 114604
Published: April 1, 2025
Language: Английский
Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114604 - 114604
Published: April 1, 2025
Language: Английский
MRS Energy & Sustainability, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
Language: Английский
Citations
0Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: April 9, 2025
Abstract Magnesium ion batteries (MIBs) receive concentrated attention owing to their high intrinsic advantages such as theoretical volumetric energy densities. However, poor cycling performances and low‐temperature electrochemical properties remain major technical issues in MIBs. Electrode materials impose a great influence on the characteristics of 2D transition metal dichalcogenides (TMDs) are potentially excellent electrode for MIBs account open framework outstanding characteristics. In this work, pre‐intercalation modification strategy is adopted design K + pre‐intercalated WS 2 material Structural characterizations density functional theory (DFT) calculations demonstrate that Mg 2+ diffusion barrier effectively lowered accompanied by interlayer expansion layered structure, aiding quick reliable storage. Consequently, K‐WS demonstrates performances, reversible capacity 217 mA h g −1 at 0.2 A with stability. addition, capable running smoothly low temperatures, showing superior preservation 97% upon completion 1000 cycles −30 °C. This work supplies an uplifting means optimization cutting‐edge
Language: Английский
Citations
0Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: April 16, 2025
Abstract Rechargeable magnesium batteries (RMBs) have drawn tremendous attention for large‐scale energy storage systems due to their low cost and high safety. However, the charge density slow diffusion of Mg 2+ in cathode material limit development practical materials. Molybdenum disulfide (MoS 2 ) is considered as an attractive electrode RMBs owing its layered structure theoretical capacity. Unfortunately, limited intercalation sites phase transitions between 2H 1T during cycling will lead capacity poor rate capability. Herein, a Cu single atom doped MoS (SACu‐MoS designed first time address above challenges. The strengthens interaction promotes electron transfer, thereby achieving excellent enhancing effect facilitates reversible conversion 1T. As result, obtained SACu‐MoS exhibits specific (up 375 mAh g −1 at 20 mA ), capability (122 1000 outstanding performance 109 after 500 cycles ). This work provides decisive guidance feasible technical solution analyses deep mechanisms on tuning metal sulfide electrodes advanced RMBs.
Language: Английский
Citations
0Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 538, P. 216702 - 216702
Published: April 21, 2025
Language: Английский
Citations
0Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114604 - 114604
Published: April 1, 2025
Language: Английский
Citations
0