Role of Electronic Conductivities Toward Practical All‐Solid‐State Lithium‐Metal/Sulfur Batteries DOI Open Access
Niaz Ahmad,

Cailing Fan,

Muhammad Faheem

et al.

Advanced Sustainable Systems, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 23, 2024

Abstract Inorganic solid‐state electrolytes (ISSEs) are recognized as promising candidates for safer and higher energy‐density all‐solid‐state lithium‐metal/sulfur batteries (ASSLM/SBs). Significant efforts have been directed at designing ISSEs with better chemical/electrochemical stability, superior lithium‐ion conductivity, extensive working voltage windows. However, it has investigated that Li‐dendrites produced within bulk during the charge‐discharge process short‐circuit ASSLM/SBs. Notably, non‐negligble electronic conductivity (σ e ) ≈10 −8 S cm −1 can trigger nucleation of intrinsic defects, e.g., grain boundaries, pores, cracks ISSEs, leading to a significant self‐discharge phenomenon in Furthermore, reasons behind insufficient utilization cathode active materials (CAMs) ASSLM/SBs practical current densities or C‐rate remained overlooked. Herein, first, strategies reduce σ sulfide‐based SSEs prevent Li‐dendrite formation defects discussed. Second, enhance sulfur‐based cathodes' ionic (CAMs: Li 2 8 addressed. How balanced positive layer realizes fast kinetics maximizes CAMs reversibility high‐performance is also Finally, an conclusion innovative perspectives presented give readers clearer insight into

Language: Английский

Advances in Sulfide Solid–State Electrolytes for Lithium Batteries DOI

Mingxuan Yao,

Jiangtao Shi, Aiyun Luo

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104018 - 104018

Published: Jan. 1, 2025

Language: Английский

Citations

2
Enhancing the electrochemical stability of the Li1.3Al0.3Ti1.7(PO4)3 by altering with Li6PS5Cl composite solid electrolytes for all-solid-state lithium batteries DOI

Cheng-En Yu,

Shivnath Babu,

Ming-Kuen Huang

et al.

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 110, P. 115332 - 115332

Published: Jan. 6, 2025

Language: Английский

Citations

1
In situ co-growth LiF-Li3N rich dual-protective layers enable high interface stability for solid-state lithium-metal batteries DOI
Kun Zeng, Qing Liu, Hang Ma

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 70, P. 103564 - 103564

Published: June 1, 2024

Language: Английский

Citations

8
In Situ Co-Growth Lif-Li3n Rich Dual-Protective Layers Enable High Interface Stability for Solid-State Lithium-Metal Batteries DOI
Kun Zeng, Qing Liu, Hang Ma

et al.

Published: Jan. 1, 2024

Lithium metal anodes hold promise for next-generation high-energy-density batteries. However, serious dendrite formation and unstable solid electrolyte interphase (SEI) impede their practical implementation. Herein, a novel gel polymer (GPE) integrated design is exploited to in situ co-growth Li3N LiF rich SEI by improving electron transfer kinetics enhancing mechanical properties. Specifically, polyethylene glycol diacrylate used as GPE matrix form robust crosslinked network. Meanwhile, the high transport capacity of acrylonitrile promotes generation Li3N. The polyfluorinated introduction boosts kinetics, facilitating C-F bond cleavage LiF. Finally, dual-protective constructed, which regulates ion flux achieves dendrite-free lithium deposition. Impressively, treated symmetrical cell demonstrates excellent plating/stripping cycling 1000 h at 0.5 mA cm−2 with notably reduced overpotentials (50 mV). Moreover, obtained GEL@F matched LiFePO4 displays good stability over 400 cycles 91.8% retention 1 C. Concurrently, paired LiCoO2 drives 82.8% after 200 cycles. This study introduces rational from structural composition optimize chemical activity/physical properties interfaces.

Language: Английский

Citations

7
Solid‐State Electrolytes for Lithium Metal Batteries: State‐of‐the‐Art and Perspectives DOI Creative Commons
Jun Huang, Chen Li,

Dongkai Jiang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 35(1)

Published: Oct. 31, 2024

Abstract The use of all‐solid‐state lithium metal batteries (ASSLMBs) has garnered significant attention as a promising solution for advanced energy storage systems. By employing non‐flammable solid electrolytes in ASSLMBs, their safety profile is enhanced, and the anode allows higher density compared to traditional lithium‐ion batteries. To fully realize potential solid‐state (SSEs) must meet several requirements. These include high ionic conductivity Li + transference number, smooth interfacial contact between SSEs electrodes, low manufacturing cost, excellent electrochemical stability, effective suppression dendrite formation. This paper delves into essential requirements enable successful implementation ASSLMBs. Additionally, representative state‐of‐the‐art examples developed past 5 years, showcasing latest advancements SSE materials highlighting unique properties are discussed. Finally, provides an outlook on achieving balanced improved addressing failure mechanisms solutions, critical challenges such reversibility plating/stripping thermal runaway, characterization techniques, composite SSEs, computational studies, ASS lithium–sulfur lithium–oxygen With this consideration, ASSLMBs can be realized.

Language: Английский

Citations

5
Strategies to Boost the Safety and Ionic Conductivity of Lithium‐Ion Batteries Using Solid State Electrolytes: A Review DOI Open Access

Savitha Hosamane,

Nagaraju Kottam,

A. Suresh

et al.

Wiley Interdisciplinary Reviews Energy and Environment, Journal Year: 2025, Volume and Issue: 14(1)

Published: Jan. 2, 2025

ABSTRACT The enormous potential of lithium‐ion batteries (LIBs) to provide environmentally sustainable practices and efficient energy storage has led a rising interest in LIBs. Thermal runaway behaviors LIBs, including high temperature, ejection, combustion, explosion, the release toxic gases, as well thermal failure propagation battery pack, are both possible. Here, briefly mentioned about solid‐state electrolytes (SSE), which may use make LIBs safer by reducing these risks. However, SSE's ionic conductivity is subpar when compared that other liquid electrolytes, demanding modification. authors have also focused on several SSE types this review, inorganic SSE, solid polymer (SPEs), composite electrolytes. Additionally, it was described how enhance SSEs at ambient temperature.

Language: Английский

Citations

0
A Ring-Shaped Lithium Metal Anode Enables High-Performance All-Solid-State Batteries Revealed by In Situ L-Band EPR Imaging DOI
Jiaxing Lv, Ying Jiang, Guozhong Lu

et al.

The Journal of Physical Chemistry Letters, Journal Year: 2025, Volume and Issue: unknown, P. 917 - 923

Published: Jan. 20, 2025

In traditional operations of all-solid-state lithium metal batteries (ASSLMBs), a small thin circular disk is employed as anode (LMA). However, ASSLMBs with circular-disk LMA often fail in <150 cycles low capacity retention. this work, we developed new ring-shaped to improve cyclability. Full cells consisting LMA, LiCoO2 cathode, and Li6PS5Cl electrolyte maintain good retention 83.65% at 0.3C after 300 cycles. Moreover, situ L-band electron paramagnetic resonance imaging (EPRI) showed that fewer Li dendrites are formed on LMA. This work highlights the importance design shape mitigate growth shows EPRI useful technique for ASSLMBs.

Language: Английский

Citations

0
An All-in-One Approach for sulfide solid electrolyte with bidirectional stabilization shells enabling 4.6 V All-solid-state Lithium Batteries DOI

Shenghao Jing,

Kun Wang, Sijia Li

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104131 - 104131

Published: Feb. 1, 2025

Language: Английский

Citations

0
Sulfide-Based Anode-Free Solid-State Batteries: Key Challenges and Emerging Solutions DOI Creative Commons

Jiwei Wang,

Hongli Zhu

ACS Energy Letters, Journal Year: 2025, Volume and Issue: unknown, P. 2377 - 2391

Published: April 17, 2025

Language: Английский

Citations

0
Realizing high-stability anodes for rechargeable magnesium batteries via in situ-formed nanoporous Bi and nanosized Sn DOI
Dachong Gu, Yuan Yuan, Xianhao Peng

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(39), P. 26890 - 26901

Published: Jan. 1, 2024

Nanoporous Bi and nanosized Sn are formed in situ by the synergistic effect of Bi–Sn phase separation, defects Mg 2+ insertion/extraction reaction for high performance battery anodes.

Language: Английский

Citations

3