Synergistically self-assembled in situ growth of MXene@MOF derived sodium alginate hydrogel 3D frameworks as next-generation electrocatalysts for oxygen and hydrogen evolution

Journal of Materials Chemistry A, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The need to minimize carbon emissions and improve sustainable energy systems has stimulated significant research into multifunctional materials.

Language: Английский

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Automated synthesis and processing of functional nanomaterials: Advances and perspectives

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 523, P. 216249 - 216249

Published: Oct. 11, 2024

Language: Английский

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Design Strategies, Characterization Mechanisms, and Applications of MOFs in Polymer Composite Electrolytes for Solid‐State Lithium Metal Batteries

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 16, 2025

Abstract Solid composite electrolytes (SCEs) composed of functional fillers and solid polymer (SPEs) can overcome some shortcomings single‐phase combine advantages each component, are considered as high‐performance solid‐state (SSEs) candidates for assembling lithium metal batteries (SSLMBs) with high safety energy density. In recent years, due to designability metal–organic frameworks (MOFs), MOFs/polymer (MPCEs) have become a highly promising novel type SCEs. Based on the above content, this article first describes composition mechanism action MPCEs, followed by discussion typical fabrication methods MPCEs. addition, mechanisms unmodified neat MOFs in improving performance SSEs enhancing interface stability presented detail, focus design strategies their applications including dimensional design, ligand IL@MOFs hybrid design. Finally, thorough analysis is conducted current challenges faced corresponding future development directions proposed. This review presents comprehensive, systematic, easily understandable application different designs providing new perspective researchers study SSEs.

Language: Английский

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Enhancing ionic conductivity and expanding the electrochemical window in polymer electrolytes via ferroelectric-metal-organic-frameworks to manipulate charge spatial distribution

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 685, P. 437 - 448

Published: Jan. 20, 2025

Language: Английский

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Dendrite‐Free Li Metal Anode Achieved by Bi‐Functional Host of NH₂‐Modified UiO‐66 on Zn‐Embedded Porous Carbon Nanofibers

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 11, 2025

Abstract 3D carbonaceous host is considered as an ideal candidate for stabilizing Li metal anode (LMA) owing to its lightweight and high electronic conductivity. Nonetheless, the surface chemistries of carbon materials at different locations should be regulated modify lithiophilicity ion diffusion. In this study, a metal–organic frameworks‐engaged strategy design core–shell porous with mixed ionic/electronic conducting feature developed. To specific, Zn‐embedded nanofibers (Zn/CF) are designed cores using ZIF‐8 particles precursors pore‐forming agents. Meanwhile, NH 2 ‐functionalized UiO‐66 (NH ‐UiO‐66) nanoparticles in‐situ grown on above fibers promoted ions migration. As result, composite LMA bi‐functional Zn/CF@NH ‐UiO‐66 demonstrates enhanced stability rate performance. Particularly, obtained asymmetric cell delivers stable operation up 500 cycles 1 mA cm −2 . Moreover, corresponding Li‐Zn/CF@NH ‐UiO‐66//LiFePO 4 full shows high‐capacity retention 93.4% over 1700 C (1 ≈169 g −1 ).

Language: Английский

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Outstanding lithium storage performance of a copper coordination complex [Cu(DMSO)2]Cl2 as anode material for lithium-ion batteries

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 116, P. 116045 - 116045

Published: March 3, 2025

Language: Английский

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Mitigating Oxidation of Li₇P₂S₈I-Based Electrolytes in All-Solid-State Batteries: Cathode Coating versus Electrolyte Interface Engineering

Industrial & Engineering Chemistry Research, Journal Year: 2025, Volume and Issue: unknown

Published: March 11, 2025

Language: Английский

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Review and Future Perspectives on Lithium Battery Fire Safety: Focusing on Design of Organic Components

Energy & environment materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 28, 2025

The widespread use of lithium batteries has led to frequent fire hazards, which significantly threaten both human lives and property safety. One the primary challenges in enhancing safety lies flammability their organic components. As electronic devices continue proliferate, integration liquid electrolytes separators become common. However, these components are prone high volatility leakage, limits Fortunately, recent advancements solid‐state gel have demonstrated promising performance laboratory settings, providing solutions issues. Typically, improving flame retardancy involves careful design formulations or molecular structures materials. Moreover, internal interfacial interactions also play a vital role ensuring This review examines innovative strategies developed over past 5 years address concerns associated with batteries. Future next generation high‐safety should not only focus on optimizing component but emphasize rigorous operational testing. dual approach will drive further progress battery research development, overall reliability systems.

Language: Английский

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Ultra-thin, Scalable, and MOF Network-Reinforced Composite Solid Electrolyte for All-Solid-State Lithium Metal Batteries

Journal of Membrane Science, Journal Year: 2025, Volume and Issue: unknown, P. 124009 - 124009

Published: March 1, 2025

Language: Английский

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2D/3D hierarchical Zinc@Ti3C2Tx-MXene composite-coated copper foil as dendrite-free lithium host for stable lithium metal batteries

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 693, P. 137643 - 137643

Published: April 18, 2025

Language: Английский

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