Efficient and Ultrastable Seawater Electrolysis at Industrial Current Density with Strong Metal‐Support Interaction and Dual Cl⁻‐Repelling Layers

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(49)

Published: Oct. 25, 2024

Abstract Direct seawater electrolysis is emerging as a promising renewable energy technology for large‐scale hydrogen generation. The development of Os‐Ni 4 Mo/MoO 2 micropillar arrays with strong metal‐support interaction (MSI) bifunctional electrocatalyst reported. structure enhances electron and mass transfer, extending catalytic reaction steps improving efficiency. Theoretical experimental studies demonstrate that the MSI between Os Ni optimizes surface electronic catalyst, reducing barrier thereby activity. Importantly, first time, dual Cl − repelling layer constructed by electrostatic force to safeguard active sites against attack during oxidation. This includes Os─Cl adsorption an in situ‐formed MoO 2− layer. As result, catalyst exhibits ultralow overpotential 113 336 mV reach 500 mA cm −2 HER OER natural from South China Sea (without purification, 1 m KOH added). Notably, it demonstrates superior stability, degrading only 0.37 µV h −1 after 2500 oxidation, significantly surpassing technical target 1.0 set United States Department Energy.

Language: Английский

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Integrating Marine Renewable Energy with Green Hydrogen Production from Seawater: Feasibility and Future Prospects for Sustainable Energy Development in Indonesia

Journal of Marine Science and Application, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 7, 2025

Language: Английский

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Construction of chlorine-free electrical double layer for efficient seawater oxidation

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 529, P. 216463 - 216463

Published: Jan. 21, 2025

Language: Английский

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Understanding the interatomic electron transfer effect on boosting electrocatalytic water splitting over Nd-Co3O4 nanosheets self-supporting electrode

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 1, 2025

Language: Английский

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Boosting hydrogen adsorption via manipulating interfacial electronic structure of NiPx for enhanced alkaline seawater electrolysis

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 155925 - 155925

Published: Sept. 1, 2024

Language: Английский

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Anchoring Pt single atoms on 3D flower-like NiMoP via Pt Ni bonding with enhanced hydrogen evolution reaction

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 688, P. 233 - 240

Published: Feb. 24, 2025

Language: Английский

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Recent Progress in the Design and Application of Strong Metal–Support Interactions in Electrocatalysis

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 4, 2025

The strong metal-support interaction (SMSI) in supported metal catalysts represents a crucial factor the design of highly efficient heterogeneous catalysts. This can modify surface adsorption state, electronic structure, and coordination environment metal, altering interface structure catalyst. These changes serve to enhance catalyst's activity, stability, reaction selectivity. In recent years, multitude researchers have uncovered range novel SMSI types induction methods including oxidized (O-SMSI), adsorbent-mediated (A-SMSI), wet chemically induced (Wc-SMSI). Consequently, systematic critical review is desirable illuminate latest advancements deliberate its application within article provides characteristics various most methods. It concluded that significantly contributes enhancing catalyst selectivity, increasing catalytic activity. Furthermore, this paper offers comprehensive extensive electrocatalysis hydrogen evolution (HER), oxygen (OER), reduction (ORR), carbon dioxide (CO2RR). Finally, opportunities challenges faces future are discussed.

Language: Английский

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Ultrafast Microwave Quasi‐Solid‐State Construction of Os‐OsP₂ with Enhanced Interfacial Spillover for Seawater‐Based Anion Exchange Membrane Electrolyzers

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 26, 2025

Abstract Developing cost‐effective hydrogen evolution reactions (HER) catalysts to replace Pt/C in alkaline seawater media remains a critical challenge. Therefore, the osmium‐osmium phosphide (Os‐OsP 2 ) catalyst is reported with heterogeneous junction through ultrafast (20 s) microwave quasi‐solid approach for seawater‐splitting under industrial‐grade current density. Experimental and theoretical analysis reveal that Os‐OsP₂ interface optimizes electronic structure: osmium (Os) sites accelerate water dissociation by lowering d‐band center, while OsP₂ promotes desorption via interfacial spillover, collectively reducing HER energy barrier. In addition, requires only 1.74 V reach 1 A cm −2 owns high price activity anion exchange membrane electrolyzer, surpassing commercial 23% efficiency identical conditions. Furthermore, it exhibits robust across wide pH range exceptional durability over 100 h seawater. Economic evaluation highlights its superior cost (85.6 dollar⁻¹), 90‐fold higher than Pt/C, production costs ($0.86 GGE⁻¹) undercutting U.S. DOE target. This study provides feasible guidance development of high‐performance, scalable from

Language: Английский

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Modulation of electronic structure caused by the coupling between Al, P modified NiO and Ru for boosting alkaline hydrogen evolution

Fuel, Journal Year: 2025, Volume and Issue: 398, P. 135609 - 135609

Published: May 8, 2025

Language: Английский

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Research progress of chlorine corrosion resistance in seawater electrolysis: Materials and technologies

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 503, P. 158458 - 158458

Published: Dec. 9, 2024

Language: Английский

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