Dual Additive Strategy with Quasi-Planar Heterojunction Architecture Assisted in Morphology Optimization for High-Efficiency Organic Solar Cells DOI

Waqar Ali Memon,

Yiwu Zhu, Shilong Xiong

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 5, 2024

Achieving high-performance and stable organic solar cells (OSCs) remains a critical challenge, primarily due to the precise optimization required for active layer morphology. Herein, this work reports dual additive strategy using 3,5-dichlorobromobenzene (DCBB) 1,8-diiodooctane (DIO) optimize morphology of both bulk-heterojunction (BHJ) quasi-planar heterojunction (Q-PHJ) based on donor D18 acceptor BTP-eC9. The systematic results reveal that significantly promotes phase separation while inhibiting excessive aggregation, which, in turn, improves molecular order crystallization. As result, BHJ Q-PHJ OSCs processed with DIO + DCBB achieve impressive power conversion efficiencies 17.77% 18.60%, respectively, highest reported values additive-processed OSCs. superior performance is attributed improved charge transport reduced recombination losses, as evidenced by higher short-circuit current densities (JSC) fill factors (FF). Importantly, either or DCBB, comparison OSCs, exhibit exceptional shelf-stability, maintaining 80% their initial efficiency after 2660 2193 h, respectively. These findings underscore potential strategies advance development stable, high-efficiency suitable large-area fabrication, marking significant step forward renewable energy technology.

Language: Английский

Understanding and research progress on the initial coulombic efficiency of silicon-based anodes in lithium-ion batteries DOI
Long Cheng, Zhoulu Wang, Tiantian Wang

et al.

Journal of Electroanalytical Chemistry, Journal Year: 2024, Volume and Issue: unknown, P. 118670 - 118670

Published: Sept. 1, 2024

Language: Английский

Citations

4
Recent Advances in Thermo- and Photostabilities of Organic Solar Cells: Material Design and Morphology Control DOI Creative Commons

Jinyang Yu,

Shuixing Li, Minmin Shi

et al.

Polymer science & technology., Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 27, 2025

Language: Английский

Citations

0
Deuteration solid additive strategy for high-performance and thermally robust organic solar cells DOI
Bowen Li, Xia Hao, Ruijie Ma

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162655 - 162655

Published: April 1, 2025

Language: Английский

Citations

0
Dual Additive Strategy with Quasi-Planar Heterojunction Architecture Assisted in Morphology Optimization for High-Efficiency Organic Solar Cells DOI

Waqar Ali Memon,

Yiwu Zhu, Shilong Xiong

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 5, 2024

Achieving high-performance and stable organic solar cells (OSCs) remains a critical challenge, primarily due to the precise optimization required for active layer morphology. Herein, this work reports dual additive strategy using 3,5-dichlorobromobenzene (DCBB) 1,8-diiodooctane (DIO) optimize morphology of both bulk-heterojunction (BHJ) quasi-planar heterojunction (Q-PHJ) based on donor D18 acceptor BTP-eC9. The systematic results reveal that significantly promotes phase separation while inhibiting excessive aggregation, which, in turn, improves molecular order crystallization. As result, BHJ Q-PHJ OSCs processed with DIO + DCBB achieve impressive power conversion efficiencies 17.77% 18.60%, respectively, highest reported values additive-processed OSCs. superior performance is attributed improved charge transport reduced recombination losses, as evidenced by higher short-circuit current densities (JSC) fill factors (FF). Importantly, either or DCBB, comparison OSCs, exhibit exceptional shelf-stability, maintaining 80% their initial efficiency after 2660 2193 h, respectively. These findings underscore potential strategies advance development stable, high-efficiency suitable large-area fabrication, marking significant step forward renewable energy technology.

Language: Английский

Citations

0