Polymer, Journal Year: 2025, Volume and Issue: unknown, P. 128457 - 128457
Published: April 1, 2025
Language: Английский
Polymer, Journal Year: 2025, Volume and Issue: unknown, P. 128457 - 128457
Published: April 1, 2025
Language: Английский
Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 31, 2025
Abstract Metal‐organic frameworks (MOFs) are highly versatile materials with tunable chemical and structural properties, making them promising for triboelectric nanogenerators (TENGs) electrocatalysis. However, achieving precise control over MOF coordination structures to optimize facet‐dependent properties remains challenging. Here, a facile scalable dual‐solvent synthesis strategy is presented fabricate dendrite Co‐2‐methylimidazole (ZIF‐67‐D), enabling tailored preferred facet environments. Using density functional theory (DFT) calculations synchrotron‐based X‐ray absorption spectroscopy, it demonstrated that ZIF‐67‐D, enriched (112) facets, features reduced Co number enhanced electron‐donating ability compared the conventionally (011) facet‐dominated rhombic dodecahedron ZIF‐67 (ZIF‐67‐R). This engineering boosts TENG charge by 2.4‐fold, OER current 9.9‐fold (@1.65 V), HER 1.9‐fold (@‐0.3 V). The (112)/(011) ratio can be also tuned precisely alter output. Moreover, optimized ZIF‐67‐D shows excellent stability, maintaining electrolyzer performance 72 h devices even in high humidity. Consequently, ZIF‐67‐D‐based (D‐TENG) exhibit robust energy generation power ZIF‐67‐D||ZIF‐67‐D electrolyzers continuous hydrogen (H 2 ) production. These findings introduce new paradigm converting mechanical into sustainable energy, offering insights high‐performance harvesting systems.
Language: Английский
Citations
1Polymer, Journal Year: 2025, Volume and Issue: unknown, P. 128166 - 128166
Published: Feb. 1, 2025
Language: Английский
Citations
0Polymer, Journal Year: 2025, Volume and Issue: unknown, P. 128242 - 128242
Published: March 1, 2025
Language: Английский
Citations
0Sustainable materials and technologies, Journal Year: 2025, Volume and Issue: unknown, P. e01361 - e01361
Published: March 1, 2025
Language: Английский
Citations
0International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: unknown, P. 142365 - 142365
Published: March 1, 2025
Language: Английский
Citations
0The Journal of Supercritical Fluids, Journal Year: 2025, Volume and Issue: unknown, P. 106617 - 106617
Published: April 1, 2025
Language: Английский
Citations
0Composites Communications, Journal Year: 2025, Volume and Issue: unknown, P. 102402 - 102402
Published: April 1, 2025
Language: Английский
Citations
0Advanced Science, Journal Year: 2025, Volume and Issue: unknown
Published: April 11, 2025
Abstract The growing scarcity of freshwater, driven by climate change and pollution, necessitates the development efficient sustainable desalination technologies. Solar‐powered interfacial water evaporation has emerged as a promising solution; however, its practical implementation is hindered limited availability stable photothermal materials. Herein, bandgap engineering strategy via linker modification to enhance conversion capability metal‐organic frameworks (MOFs) reported toward solar‐driven desalination. By systematically introducing functional groups with varying electron‐donating electron‐withdrawing abilities, energy UiO–66–X (X = ─F, ─H, ─OH, ─NH 2 , ─(NH ) finely tuned. Density theory (DFT) calculations femtosecond transient absorption (fs–TA) spectroscopy reveal that stronger narrow MOFs, thereby improving their efficiency. optimized UiO–66–(NH material reaches peak surface temperature 58.7 °C when exposed simulated sunlight at ≈1 kW·m −2 efficiency 86.50% an rate 2.34 kg·m ·h −1 97.40%. This study presents novel approach for fine‐tuning in materials, offering pathway advanced solar technologies address global crisis.
Language: Английский
Citations
0Next Materials, Journal Year: 2025, Volume and Issue: 8, P. 100647 - 100647
Published: April 16, 2025
Language: Английский
Citations
0Polymer, Journal Year: 2025, Volume and Issue: unknown, P. 128433 - 128433
Published: April 1, 2025
Language: Английский
Citations
0