Carbon composites in the mitigation of micro and nanoplastics DOI
Sumathi C. Samiappan, Mahesh Narayanan, Rajesh Pandiyan

et al.

Physical Sciences Reviews, Journal Year: 2024, Volume and Issue: 9(11), P. 3451 - 3466

Published: April 29, 2024

Abstract The pervasive issue of micro and nanoplastics (MNPs) in the environment has escalated into a global concern, necessitating exploration innovative efficient removal strategies. This review paper provides comprehensive analysis application carbon composites mitigating MNPs, drawing upon wide array studies technological advancements field. Carbon composites, known for their high surface area, porosity, functional ability, offer promising avenue adsorption, degradation, MNPs from various environmental matrices. We delve mechanisms underlying interaction between including physical chemical binding, photocatalytic highlighting factors that influence these interactions, such as composite structure, chemistry, conditions. further categorizes activated carbon, nanotubes, graphene, biochar-based examining efficacy, limitations, potential impacts. A critical recent field laboratory insights composites’ practical applications performance real-world scenarios. Additionally, we discuss challenges future directions developing scalability, regeneration, sustainable production materials. hold significant mitigation offering viable solution to one our time’s most pressing challenges. However, research is needed optimize materials widespread application, enhancing selectivity, capacity, durability while minimizing unintended consequences. aims catalyze investigation innovation field, paving way more effective technologies nanoplastics.

Language: Английский

CaTiO3 Nanocuboids Decorated with Bi2WO6 Nanoflakes for Stimulating Exciton Dissociation in Photocatalytic Dye Degradation DOI

Kaushalya Bhakar,

Soumya Roy,

Naresh A. Rajpurohit

et al.

ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 16, 2024

Herein, we tailored a Bi2WO6–CaTiO3 (BWO–CTO) nanostructure for the effective degradation of various textile dyes such as rhodamine B (RhB), methylene blue (MB), methyl orange (MO), and Congo red (CR), under visible light. The nanostructures were developed using simple hydrothermal method characterized XRD, FTIR, FE-SEM, HR-TEM, XPS, PL, EIS, Mott–Schottky analysis. Different with varying BWO to CTO mass ratios (5, 10, 15, 20%), denoted 5BWO-CTO, 10BWO-CTO, 15BWO-CTO, 20BWO-CTO, respectively. 15BWO-CTO heterostructure exhibits excellent photocatalytic activity efficiency 98.5, 97, 84, 74% RhB, MB, MO, CR, respectively, within 60 min irradiation. appropriate band alignment BWO-CTO heterojunction efficiently suppresses dissociation excitons extends their lifespans. built-in electric field allows movement charge carriers from CTO, following Z-scheme transfer mechanism high redox capacity. kinetic study indicates pseudo-first-order model higher reaction rate (0.0691 min–1), good cyclic stability up four cycles, energy (927 kW h/m3). findings affirm prowess BWO–CTO potent photocatalyst targeted dye degradation. TOC LCMS analyses performed evaluate mineralization possible pathways RhB dye.

Language: Английский

Citations

0

Carbon composites in the mitigation of micro and nanoplastics DOI
Sumathi C. Samiappan, Mahesh Narayanan, Rajesh Pandiyan

et al.

Physical Sciences Reviews, Journal Year: 2024, Volume and Issue: 9(11), P. 3451 - 3466

Published: April 29, 2024

Abstract The pervasive issue of micro and nanoplastics (MNPs) in the environment has escalated into a global concern, necessitating exploration innovative efficient removal strategies. This review paper provides comprehensive analysis application carbon composites mitigating MNPs, drawing upon wide array studies technological advancements field. Carbon composites, known for their high surface area, porosity, functional ability, offer promising avenue adsorption, degradation, MNPs from various environmental matrices. We delve mechanisms underlying interaction between including physical chemical binding, photocatalytic highlighting factors that influence these interactions, such as composite structure, chemistry, conditions. further categorizes activated carbon, nanotubes, graphene, biochar-based examining efficacy, limitations, potential impacts. A critical recent field laboratory insights composites’ practical applications performance real-world scenarios. Additionally, we discuss challenges future directions developing scalability, regeneration, sustainable production materials. hold significant mitigation offering viable solution to one our time’s most pressing challenges. However, research is needed optimize materials widespread application, enhancing selectivity, capacity, durability while minimizing unintended consequences. aims catalyze investigation innovation field, paving way more effective technologies nanoplastics.

Language: Английский

Citations

0