
ECS Journal of Solid State Science and Technology, Journal Year: 2024, Volume and Issue: 13(11), P. 113011 - 113011
Published: Nov. 1, 2024
Polymethyl methacrylate (PMMA)/polyvinyl acetate (PVAc)/tetra-n-butylammonium iodide (TBAI)/ x wt % polyaniline (PANI) blended polymers are fabricated using the casting method to operate in energy storage purposes. The structure and morphology of created blends were studied X-ray diffraction (XRD) scanning electron microscope (SEM) techniques. XRD analysis displayed that semicrystalline behavior polymer blend is unaffected by doping. At 293 K 100 Hz, dielectric constant decreased from 22.7 (undoped) 14.04–21.7 depended on amount PANI doped blend. greatest density ( U ) values reported with = 0.33; 0.00469 J m −3 at Hz. Increasing temperature also improves for all blends. 0.11, 0.22, 0.33 showed an impressive rise relative undoped In low intermediate frequency ranges, ac c onductivity increased 0.44. correlated barrier hopping (CBH) model was used describe electric mechanism influence quantity doping electrical impedance spectroscopy, modulus, relaxation time investigated. A 0.44 exhibited dc conductivity; 343 K. conductivity 2.477 × 10 −8 S −1 1.086 −5 (x 0.44). activation energies E a varied between 1.36 eV 1.01 based range. added host controlled samples.
Language: Английский