International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 71, P. 227 - 238
Published: May 21, 2024
Language: Английский
International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 71, P. 227 - 238
Published: May 21, 2024
Language: Английский
EcoEnergy, Journal Year: 2023, Volume and Issue: 1(1), P. 108 - 153
Published: Sept. 1, 2023
Abstract Photoelectrochemical (PEC) water splitting with zero carbon emissions is a promising technology to solve the global issues of energy shortage and environmental pollution. However, current development PEC systems facing bottleneck low solar‐to‐hydrogen (STH) efficiency (<10%), which cannot meet demand large‐scale H 2 production. The low‐cost, highly active, stable photoanode materials crucial for high STH splitting. recent BiVO 4 as has been great success, ABO ‐type ternary metal oxides similar structure have potential efficient photoanodes high‐performance design are critically reviewed special emphasis on modification strategies performance improvement mechanisms each semiconductor. comprehensive analysis in this review provides guidelines insights exploration new high‐efficiency solar fuel
Language: Английский
Citations
54ACS Applied Materials & Interfaces, Journal Year: 2023, Volume and Issue: 15(17), P. 21123 - 21133
Published: April 21, 2023
The coupling of oxygen evolution reaction (OER) catalysts with photoanodes is a promising strategy for enhancing the photoelectrochemical (PEC) performance by passivating photoanode's surface defect states and facilitating charge transfer at photoanode/electrolyte interface. However, serious interface recombination issue caused poor OER coating quality often limits further improvement photoanodes. Herein, rapid Fenton-like method demonstrated to produce ultrathin amorphous Ni:FeOOH in situ-induced vacancies (Vo) improve water oxidation activity stability BiVO4 combined physical characterizations, PEC studies, density functional theory calculations revealed that reductive environment situ produces abundant Vo catalysts, which significantly improves separation efficiency while also offering active sites reduced energy barrier OER. As result, Ni:FeOOH-Vo yielded more than 2-fold increased photocurrent photoanode (from 1.54 4.15 mA cm-2 1.23 VRHE), accompanied high 5 h. This work not only highlights significance but provides new insights into rational design fabrication efficient stable solar water-splitting systems.
Language: Английский
Citations
26Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(20), P. 7459 - 7511
Published: Jan. 1, 2024
This review provides a comprehensive overview on the mechanism of photoelectrochemical biomass conversion and highlights extension dual-function cells for valorization paired with more valuable half-reactions.
Language: Английский
Citations
10Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 358, P. 124369 - 124369
Published: July 6, 2024
Language: Английский
Citations
9Frontiers in Energy, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 15, 2025
Language: Английский
Citations
1Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 474, P. 145509 - 145509
Published: Aug. 18, 2023
Language: Английский
Citations
22Journal of Photochemistry and Photobiology C Photochemistry Reviews, Journal Year: 2023, Volume and Issue: 58, P. 100649 - 100649
Published: Dec. 28, 2023
Language: Английский
Citations
19International Journal of Hydrogen Energy, Journal Year: 2023, Volume and Issue: 51, P. 1497 - 1507
Published: Nov. 19, 2023
Language: Английский
Citations
18Small, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 2, 2024
Rational construction of high-efficiency photoelectrodes with optimized carrier migration to the ideal active sites, is crucial for enhancing solar water oxidation. However, complexity in precisely modulating interface configuration and directional charge transfer pathways retards design robust stable artificial photosystems. Herein, a straightforward yet effective strategy developed compact encapsulation metal oxides (MOs) an ultrathin non-conjugated polymer layer modulate interfacial separation. By periodically coating highly ordered TiO
Language: Английский
Citations
8Applied Surface Science, Journal Year: 2023, Volume and Issue: 641, P. 158505 - 158505
Published: Sept. 18, 2023
The utilization of fossil fuels to meet ever-increasing energy demands is causing a significant threat the Earth's climate and its inhabitants. To address this issue, photoelectrochemical (PEC) water splitting has emerged as promising solution produce oxygen (O2) hydrogen (H2) in cost-effective, environmentally friendly, clean, renewable manner. In study, we present development cost-effective Cu3Se2 S-doped thin films on Fluorine-doped Tin Oxide (FTO) substrates using chemical bath deposition (CBD) process enhance efficiency PEC oxidation oxygen. X-Ray Diffraction (XRD) pattern confirms presence single-phase tetragonal crystal structure with noticeable shift characteristic (2 1 1) reflection towards higher 2θ value, from 38.1° 38.4°, indicating successful doping S films. further validate lattice, X-ray photoelectron spectroscopy (XPS), dispersive (EDX), Fourier transform infrared (FTIR), Raman Spectroscopy were employed. TEM reveals granular an average particle size 7–8 nm, which consistent crystallite determined by XRD. Furthermore, valence band conduction edge positions are found be 1.56 −0.57 eV, respectively. increased gap Cu3Se2, 1.97 2.15 thus confirming bending upon doping. specific surface areas (SSA) pristine 5.03 111.48 m2g−1, respectively, showing twenty-two-fold increase performance materials was evaluated through chopped chronoamperometry (CA), linear sweep voltammetry (LSV), electrochemical impedance (EIS), Mott-Schottky (M-S) analysis. prepared under optimum conditions, exhibited photocurrent density difference 880 µA cm−2, 6 times greater than for film. results indicate negative slope, implying p-type conductivity, lower flat potential value 0.33 V vs. RHE. Our approach provides green fabricate producing CBD.
Language: Английский
Citations
14