Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 131077 - 131077
Published: Dec. 1, 2024
Language: Английский
Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 131077 - 131077
Published: Dec. 1, 2024
Language: Английский
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(45)
Published: July 8, 2024
Abstract Membranes offer a potentially energy‐efficient and space‐saving solution to reduce CO 2 emissions combat global warming. However, engineering membranes with advanced materials for high permeance reasonable selectivity is pressing need. In this context, series of carbazole‐based conjugated microporous polymer (CMP) are fabricated thicknesses few hundred nanometers through in situ electropolymerization post‐combustion carbon capture. The findings reveal that various experimental conditions, including the monomer concentration, electric potential, cyclic voltammetry (CV) cycling number, largely impact polymerization degree CMP, thus influencing mode chain packing. An optimal leads larger micropore size higher fractional free volume (FFV), allowing fast transport. study first demonstrates feasibility using CMPs fabricate thin film composite (TFC) capture confirms controllability their micropores. These insights provide instructive guidance future advancement CMP applications membrane fabrication gas separation other fields require precise generation design.
Language: Английский
Citations
10Science Advances, Journal Year: 2025, Volume and Issue: 11(4)
Published: Jan. 22, 2025
Mixed matrix membranes, with well-designed pore structure inside the polymeric via incorporation of inorganic components, offer a promising solution for addressing CO 2 emissions. Here, we synthesized series novel metal organic cages (MOCs) aperture size precisely positioned between and N or CH 4 . These MOCs were uniformly dispersed in polymers intrinsic microporosity (PIM-1). Among them, MOC-Ph cage effectively modulated chain packing optimized microporous membrane. Remarkably, PIM-Ph-5% membrane shows superior performance, achieving an excellent permeability 8803.4 barrer /N selectivity 59.9, far exceeding 2019 upper bound. This approach opens opportunities improving porous membranes capture other separation applications.
Language: Английский
Citations
1Journal of Membrane Science, Journal Year: 2025, Volume and Issue: unknown, P. 123775 - 123775
Published: Jan. 1, 2025
Language: Английский
Citations
1Energy Conversion and Management, Journal Year: 2024, Volume and Issue: 323, P. 119244 - 119244
Published: Nov. 16, 2024
Language: Английский
Citations
7Journal of Membrane Science, Journal Year: 2024, Volume and Issue: unknown, P. 123528 - 123528
Published: Nov. 1, 2024
Language: Английский
Citations
4Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 131206 - 131206
Published: Jan. 1, 2025
Language: Английский
Citations
0Chemical Science, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
This perspective critiques advancements in integrated CO 2 capture and electrochemical conversion, contrasting emerging methods like eRCC via amine or (bi)carbonate pathways direct ACC with traditional sequential conversion strategies.
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132312 - 132312
Published: Feb. 1, 2025
Language: Английский
Citations
0Published: Jan. 1, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132535 - 132535
Published: March 1, 2025
Language: Английский
Citations
0