Published: Jan. 1, 2024
Language: Английский
Published: Jan. 1, 2024
Language: Английский
Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1302, P. 137420 - 137420
Published: Jan. 1, 2024
Language: Английский
Citations
3Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 141535 - 141535
Published: Jan. 1, 2025
Language: Английский
Citations
0Inorganica Chimica Acta, Journal Year: 2023, Volume and Issue: 560, P. 121815 - 121815
Published: Oct. 18, 2023
Language: Английский
Citations
3Applied Organometallic Chemistry, Journal Year: 2024, Volume and Issue: 38(12)
Published: Aug. 29, 2024
ABSTRACT Two novel tetra‐ and hepta‐nuclear Ni(II) salamo‐type clusters, [Ni 4 (L) 2 ( μ ‐Cl) 3 ‐OH) (EtOH) ]⋅4CH Cl 1 ) 7 ‐OEt) 6 ] ), were constructed by modulating different anions (Cl − NO ). X‐ray crystallographic researches revealed that cluster is a tetranuclear consisting of symmetric binuclear structure in which chloride ions are involved coordination. Although consists seven ions, three deprotonated 2− parts, two ‐ethoxy groups, six ‐OH anions, coordinated ethanol molecules, it quite rare for large number water molecules to be participate the bridging due alkaline environment. TEM electron scanning displayed distinct shapes. Comparison DFT calculations less chemically reactive more kinetically stable, accordance with analytical results weak interactions, where stronger interaction forces presented, stable molecule is. Finally, comparative analysis UV–Vis, IR, fluorescence spectra carried out.
Language: Английский
Citations
0Published: Jan. 1, 2024
Language: Английский
Citations
0