Formation and saturation of β-phase of PVDF in DMF solvent: a comprehensive study
Soft Materials,
Journal Year:
2025,
Volume and Issue:
unknown, P. 1 - 11
Published: Jan. 6, 2025
In
the
present
work,
we
report
effect
of
solvent
content
on
β-phase
fraction
in
PVDF
(poly(vinylidene
fluoride))
films
synthesized
by
facile
wet
chemical
route
using
DMF
(N,N-Dimethylformamide)
as
solvent.
The
amount
powder
was
kept
fixed
while
varied.
X-ray
diffraction
(XRD)
revealed
transformation
α-phase
to
films,
which
further
confirmed
Fourier
Transform
Infrared
Spectroscopy
(FTIR).
Deconvolution
XRD
profiles
showed
increase
(viz.
βα
ratio)
with
initial
volume.
However,
a
surprising
and
previously
unreported
result
emerged,
i.e.
saturation
beyond
certain
volume
plausible
mechanism
for
formation
is
discussed.
Language: Английский
Recent Progress in Energy Harvesting Technologies for Self‐Powered Wearable Devices: The Significance of Polymers
Hana Afshar,
No information about this author
Farimah Kamran,
No information about this author
Farangis Shahi
No information about this author
et al.
Polymers for Advanced Technologies,
Journal Year:
2025,
Volume and Issue:
36(4)
Published: April 1, 2025
ABSTRACT
The
growing
demand
for
self‐powered
wearable
electronic
devices
in
healthcare,
fitness,
and
entertainment
has
driven
significant
advancements
energy
harvesting
technologies.
This
review
explores
the
latest
progress
mechanisms
that
enable
sustainable
autonomous
devices,
with
a
particular
emphasis
on
role
of
polymers
their
development.
Polymers
offer
unique
combination
mechanical
flexibility,
biocompatibility,
lightweight
properties,
making
them
ideal
applications.
systematically
categorizes
major
technologies
into
three
primary
mechanisms:
thermoelectric
generators
(TEGs),
piezoelectric
harvesters
(PEHs),
triboelectric
nanogenerators
(TENGs).
Each
section
provides
an
in‐depth
discussion
working
principles,
material
innovations,
fabrication
techniques,
applications
these
systems.
Beyond
fundamental
mechanisms,
discusses
hybrid
systems
integrate
multiple
sources
to
maximize
power
generation
ensure
continuous
device
operation.
storage
technologies,
such
as
flexible
supercapacitors
micro‐batteries,
is
also
highlighted
address
intermittency
challenges
ambient
sources.
Despite
progress,
remain
improving
conversion
efficiency,
enhancing
durability,
optimizing
system
integration
real‐world
identifies
key
research
directions
overcoming
challenges,
including
advanced
materials
engineering,
miniaturization
artificial
intelligence‐driven
management
strategies.
findings
presented
this
provide
valuable
insights
development
next‐generation
paving
way
efficient
electronics
seamlessly
daily
life.
Language: Английский
Crystallization behavior and electrical conductivity of fluorosilane-modified multi-walled carbon nanotubes/polymethyl methacrylate/polyvinylidene fluoride ternary composite
Bo Lin,
No information about this author
Jian‐Wu Xiao,
No information about this author
Jingmin Li
No information about this author
et al.
Journal of Thermal Analysis and Calorimetry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 2, 2025
Abstract
In
order
to
increase
the
compatibility
with
polyvinylidene
fluoride
(PVDF),
multi-walled
carbon
nanotubes
(MWCNTs)
were
modified
by
trimethoxy
(1H,
1H,
2H,
2H
heptadecafluorodecyl)
silane
obtain
fluorosilane-modified
MWCNTs
(F-MWCNTs).
The
as-prepared
F-MWCNTs
characterized
scanning
electron
microscopy
(SEM),
wide-angle
X-ray
diffraction
(WAXD),
thermogravimetric
analysis
(TGA),
and
Fourier
transform
infrared
(FTIR)
confirm
successful
surface
modification
of
fluorosilane.
further
blended
polymethyl
methacrylate
(PMMA)
PVDF
prepare
MWCNTs/PMMA/PVDF
ternary
composites
containing
1%,
3%,
5%,
7%,
10%
solution
mixing,
SEM,
WAXD,
FTIR,
alternating
current
(AC)
electrical
conductivity
testing.
It
was
confirmed
that
homogeneously
distributed
in
PMMA/PVDF
matrix.
Moreover,
existence
contributed
improvement
crystallization
degree
(
X
c
)
β
crystalline
content
[
F
)]
as
well
AC
σ
for
composites.
values
,
),
at
100
Hz
MWCNTs(10%)/PMMA/PVDF
composite
47.4%,
56.5%,
2.40
×
10
–1
Sm
−1
respectively,
while
corresponding
pure
only
42.2%,
27.8%,
1.85
–9
respectively.
enhanced
performances
comparison
those
can
be
attributed
interface
interactions
among
F-MWCNTs,
PVDF,
PMMA
phase
separation
PVDF.
Language: Английский
Research on the rigid preparation method of flexible micro coils for flexible self powered electrical devices using laser cutting technology
Wencheng Li,
No information about this author
Huifang Liu,
No information about this author
Yufei Lu
No information about this author
et al.
Optics & Laser Technology,
Journal Year:
2025,
Volume and Issue:
188, P. 112991 - 112991
Published: April 18, 2025
Language: Английский
High-Efficiency Nanostructured Materials for Flexible and Wearable Energy Harvesting Technologies
EPJ Web of Conferences,
Journal Year:
2025,
Volume and Issue:
325, P. 01002 - 01002
Published: Jan. 1, 2025
The
growing
demand
for
portable,
sustainable
power
sources
has
driven
significant
advancements
in
flexible
and
wearable
energy
harvesting
technologies.
These
technologies
leverage
ambient
mechanical,
thermal,
vibrational
to
small
electronic
devices,
offering
a
promising
solution
self-sustaining,
on-the-go
systems.
integration
of
nanostructured
materials
into
devices
emerged
as
key
strategy
enhance
efficiency,
flexibility,
performance.
This
paper
explores
the
role
high-efficiency
development
It
examines
various
mechanisms,
including
piezoelectric,
triboelectric,
thermoelectric,
their
compatibility
with
nanomaterials.
unique
properties
materials—such
increased
surface
area,
enhanced
electrical
performance—are
discussed
context
optimizing
conversion
efficiency.
also
reviews
design
principles
integrating
these
highlighting
recent
innovations
case
studies
field.
Applications
harvesters
electronics,
self-powered
medical
environmental
monitoring
are
presented,
along
challenges
scaling,
durability,
sustainability.
Finally,
future
perspectives
on
commercialization
provided,
emphasizing
need
improved
material
fabrication,
cost-effectiveness,
long-term
reliability.
offers
comprehensive
overview
how
revolutionizing
harvesting,
paving
way
more
efficient,
sustainable,
portable
solutions.
Language: Английский
Performance Assessment of a Piezoelectric Vibration Energy Harvester for Hybrid Excitation with Varying Cross Sections
Sensors,
Journal Year:
2024,
Volume and Issue:
24(23), P. 7629 - 7629
Published: Nov. 28, 2024
This
paper
experimentally
examines
the
influence
of
hybrid
excitation
on
performance
vibrational
piezoelectric
energy
harvesting
systems
a
bluff
body
with
variable
cross
section
along
its
generatrix.
A
combination
from
shaker
and
airflow
is
considered
source
which
harvested.
Varied
frequencies
velocities
across
five
different
masses
were
considered,
each
defining
natural
frequency
system.
The
system's
in
excitation,
enhancements
harvesting,
challenges
these
was
observed,
helping
to
determine
optimal
operating
conditions
function
effectively
ambient
environments.
tests
identified
ranges
within
maximized
responses
observed.
Next,
computational
fluid
dynamic
(CFD)
simulations
carried
out
understand
impact
circular
square
sections
controlling
nature
representative
wide
range
that
may
be
utilized
for
such
purposes.
analyses
helped
contextualize
opportunities
limitations
use
understanding
if
transition
one
another
can
lead
an
assimilation
advantages
observed
using
independently.
Language: Английский