Design of Precise Nanoparticles via Polymer Crystallization DOI

Jingyuan Gu,

Zhenyan Chu,

Bowen Zheng

et al.

ACS Macro Letters, Journal Year: 2025, Volume and Issue: unknown, P. 645 - 657

Published: May 5, 2025

The utilization of polymer crystallization to manipulate the self-assembly polymeric amphiphiles in solution is gaining increasing attention for design anisotropic core-shell nanoparticles and even more complex hierarchical architectures. Notably, living-crystallization-driven (CDSA) method, which involves seeded growth, has emerged as an ambient temperature approach creating low-dispersity nanomaterials such one-dimensional (1D) cylinders two-dimensional (2D) platelets. This technique offers predictable size control facilitates creation segmented structures with spatially defined compositions functionalities, this process epitaxial regarded intrinsic mechanism living CDSA. For context, Viewpoint, we delineate key aspects CDSA growth a particular emphasis on heteroepitaxial employing crystalline cores distinct chemistries from perspective. Revealing in-depth enables expansion where core functionalities are defined. Utilizing chemically strategies, synthetic processes 2D hollow platelets unique architecture also summarized, special interest soft matter.

Language: Английский

Design of Precise Nanoparticles via Polymer Crystallization DOI

Jingyuan Gu,

Zhenyan Chu,

Bowen Zheng

et al.

ACS Macro Letters, Journal Year: 2025, Volume and Issue: unknown, P. 645 - 657

Published: May 5, 2025

The utilization of polymer crystallization to manipulate the self-assembly polymeric amphiphiles in solution is gaining increasing attention for design anisotropic core-shell nanoparticles and even more complex hierarchical architectures. Notably, living-crystallization-driven (CDSA) method, which involves seeded growth, has emerged as an ambient temperature approach creating low-dispersity nanomaterials such one-dimensional (1D) cylinders two-dimensional (2D) platelets. This technique offers predictable size control facilitates creation segmented structures with spatially defined compositions functionalities, this process epitaxial regarded intrinsic mechanism living CDSA. For context, Viewpoint, we delineate key aspects CDSA growth a particular emphasis on heteroepitaxial employing crystalline cores distinct chemistries from perspective. Revealing in-depth enables expansion where core functionalities are defined. Utilizing chemically strategies, synthetic processes 2D hollow platelets unique architecture also summarized, special interest soft matter.

Language: Английский

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