Journal of Vinyl and Additive Technology,
Journal Year:
2024,
Volume and Issue:
30(5), P. 1317 - 1326
Published: June 27, 2024
Abstract
DL‐Isoborneol
is
a
forestry
chemical
product
that
can
serve
as
an
intermediate
in
the
synthesis
of
value‐added
plasticizer
products.
In
this
study,
three
kinds
esters
(octanoic
acid‐DL‐Isoborneol,
decanoic
acid‐DL‐Isoborneol
ester,
and
lauric
ester
[LDE])
with
different
fatty
hydrocarbon
chains
were
synthesized
via
esterification
reaction.
Fourier
transform
infrared
spectrometer
(FT‐IR)
Nuclear
magnetic
hydrogen
spectrum
(
1
H
NMR)
indicated
successfully
synthesized.
The
oral
toxicity
experiment
plasticizers
mice
have
toxic
doses
5000
mg/kg
was
environmentally
friendly
nontoxic.
used
main
to
plasticize
polyvinyl
chloride
(PVC)
compared
commercial
dioctyl
phthalate
(DOP).
results
showed
could
improve
thermoplastic
processing
performance
thermal
stability
plasticized
PVC
than
DOP.
more
excellent
compatibility
T
g
reached
22°C,
tensile
strength
elongation
at
break
40
wt%
LDE
12.90
±
0.83
MPa
342
13%,
respectively.
improved
migration
resistance
plasticization
efficiency
completely
replace
DOP
for
PVC.
Highlights
are
be
Plasticized
processability.
replaced
by
esters.
Applied Sciences,
Journal Year:
2024,
Volume and Issue:
14(23), P. 10953 - 10953
Published: Nov. 26, 2024
Esters
of
aliphatic
dicarboxylic
acids
are
promising
plasticizers
polyvinyl
chloride
due
to
their
low
toxicity
and
high
biodegradability.
Plasticized
PVC
materials
containing
them
characterized
by
frost
resistance
heat
resistance.
In
this
regard,
esters
adipic
acid
alkoxylated
alcohols
with
various
structures
have
been
obtained.
The
influence
alcohol
structure
on
the
plasticizing
ability
ether
has
determined.
A
theoretical
assessment
effect
diesters
in
relation
was
performed
based
calculation
Hansen
solubility
parameters.
For
purpose,
thermodynamic
compatibility
adipates
investigated.
processability
composition
compositions
studied
according
values
critical
temperature
dissolution
PVC.
intervals
transition
plastics
from
a
glassy
highly
elastic
state,
as
well
depression
glass
compounds
adipates,
were
Rheological
characteristics
obtained
It
is
shown
that
chemical
group
determines
important
technological
operational
polymer
materials.
Green Chemistry,
Journal Year:
2023,
Volume and Issue:
25(18), P. 7292 - 7308
Published: Jan. 1, 2023
Isosorbide
and
isomannide
have
been
esterified
with
short-chain
acids
via
two
different
esterification
routes.
The
obtained
reaction
data
were
applied
for
a
comparative
life
cycle
assessment
to
identify
starting
points
further
ecological
improvement.
Journal of Vinyl and Additive Technology,
Journal Year:
2024,
Volume and Issue:
30(5), P. 1317 - 1326
Published: June 27, 2024
Abstract
DL‐Isoborneol
is
a
forestry
chemical
product
that
can
serve
as
an
intermediate
in
the
synthesis
of
value‐added
plasticizer
products.
In
this
study,
three
kinds
esters
(octanoic
acid‐DL‐Isoborneol,
decanoic
acid‐DL‐Isoborneol
ester,
and
lauric
ester
[LDE])
with
different
fatty
hydrocarbon
chains
were
synthesized
via
esterification
reaction.
Fourier
transform
infrared
spectrometer
(FT‐IR)
Nuclear
magnetic
hydrogen
spectrum
(
1
H
NMR)
indicated
successfully
synthesized.
The
oral
toxicity
experiment
plasticizers
mice
have
toxic
doses
5000
mg/kg
was
environmentally
friendly
nontoxic.
used
main
to
plasticize
polyvinyl
chloride
(PVC)
compared
commercial
dioctyl
phthalate
(DOP).
results
showed
could
improve
thermoplastic
processing
performance
thermal
stability
plasticized
PVC
than
DOP.
more
excellent
compatibility
T
g
reached
22°C,
tensile
strength
elongation
at
break
40
wt%
LDE
12.90
±
0.83
MPa
342
13%,
respectively.
improved
migration
resistance
plasticization
efficiency
completely
replace
DOP
for
PVC.
Highlights
are
be
Plasticized
processability.
replaced
by
esters.
