Effect of Phosphorus‐Containing Silane Coupling Agents Modified Ammonium Polyphosphate on the Flame Retardancy and Mechanical Properties of Epoxy Resin
Song Wang,
No information about this author
Rui Ma
No information about this author
Journal of Applied Polymer Science,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 30, 2025
ABSTRACT
Two
phosphorus‐containing
silane
coupling
agents
(PSCAs),
KH550‐P
and
KH560‐P,
are
successfully
prepared
by
reacting
10‐hydroxy‐9,10‐dihydro‐9‐oxa‐10‐phosphorus‐10‐oxide
(DOPOOH)
with
(3‐aminopropyl)
triethoxysilane
(KH550)
3‐glycidyloxypropyltrimethoxysilane
(KH560),
respectively.
These
two
PSCAs
used
as
the
surface
modification
of
ammonium
polyphosphate
(APP).
The
flame
retardancy
mechanical
properties
epoxy
resin
(EP)
PSCA‐modified
APP
investigated.
When
weight
ratio
to
is
18:2
addition
amount
APPs,
APP‐KH550‐P
APP‐KH560‐P
,
in
EP
reaches
8%,
resulting
flame‐retardant
composite
materials,
EP/APP‐KH550‐P
EP/APP‐KH560‐P
exhibit
good
a
V‐0
rating
vertical
combustion
test
(UL‐94).
limiting
oxygen
index
values
both
higher
than
30%.
peak
heat
release
rates
decrease
13.8%
28.5%,
respectively,
compared
containing
8%
(EP/APP).
Both
KH560‐P
demonstrate
similar
performance
enhancing
APP.
added
EP,
found
be
those
EP/APP.
Conversely,
tensile
strength
impact
increase
23.8%
74.3%,
shows
significantly
better
EP.
Language: Английский
Organosilicone-based clustered phosphinic acid endows outstanding synergistic flame retardancy of epoxy resins
European Polymer Journal,
Journal Year:
2025,
Volume and Issue:
unknown, P. 113771 - 113771
Published: Jan. 1, 2025
Language: Английский
A novel boron and silicon hybrid zeolite flame retardants for reducing the fire hazard of epoxy resin
Colloids and Surfaces A Physicochemical and Engineering Aspects,
Journal Year:
2025,
Volume and Issue:
unknown, P. 136746 - 136746
Published: March 1, 2025
Language: Английский
A facile surface modification of ammonium polyphosphate with boron-based compound to reduce its particle size and improve the flame retardancy and anti-dripping of polylactic acid resin
Sheng‐Chao Huang,
No information about this author
Xiaosui Chen,
No information about this author
Yuhang Huang
No information about this author
et al.
Colloids and Surfaces A Physicochemical and Engineering Aspects,
Journal Year:
2025,
Volume and Issue:
unknown, P. 136781 - 136781
Published: March 1, 2025
Language: Английский
Interface reaction constructs iron and phosphorus functionalized zeolite endowing EP with excellent fire safety and mechanical properties
Chemical Engineering Journal,
Journal Year:
2025,
Volume and Issue:
unknown, P. 162904 - 162904
Published: April 1, 2025
Language: Английский
Flame‐Retardant Self‐Healing Polymers: A Review
M. Kianfar,
No information about this author
Hossein Ipakchi,
No information about this author
Shiva Mohajer
No information about this author
et al.
Journal of Polymer Science,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 25, 2024
ABSTRACT
Developing
multifunctional
flame
retardants
(FRs)
has
become
a
strategy
to
reply
on
needs
for
advanced
polymers.
Self‐healing
polymers
are
an
emerging
class
of
polymeric
materials,
which
have
been
upgraded
progressively,
and
recently
taken
the
advantage
fire
safety.
Correspondingly,
diverse
industries
like
aerospace,
automotive,
construction
consumer
electronics
benefited
from
flame‐retardant
self‐healing
underlines
their
increasing
contribution
modern
technologies.
The
characteristics
stem
intricate
chemical
physical
interactions,
adopting
self‐directed
repair
mechanisms
leading
eliminating
need
frequent
replacements,
subsequently
lowering
maintenance
costs
environmental
impact.
This
review
summarizes
advantages
with
emphasis
exploring
highly
innovative
advancements
among
bio‐based
hydrogels,
aerogels,
coatings,
thin
films,
lithium‐ion
batteries
ionotronic
skin
(‐i‐skin)
structures
embedding
sensing
features
smoke
detection
exposure
warnings,
further
broadening
application
in
smart
technologies
safety‐critical
infrastructure.
outcomes
reports
outline
challenges
remaining
developing
such
multifaceted
materials
view
lack
information
due
limited
or
exclusive
investigations.
However,
research
may
facilitate
dehydration,
thermal
shielding,
free
radical
quenching
contributing
retardancy
performance
Sustainability
circular
economy
requirements
briefly
discussed,
addition
outlining
remarks
future
developments.
Language: Английский