Polymer Chemistry, Journal Year: 2023, Volume and Issue: 14(7), P. 862 - 871
Published: Jan. 1, 2023
The design of a green and renewable bio-based self-healing vitrimer has attracted extensive attention due to the increasing emphasis on an environment friendly society.
Language: Английский
Chemical Society Reviews, Journal Year: 2022, Volume and Issue: 52(1), P. 277 - 317
Published: Dec. 15, 2022
The review presents the synthesis, properties and applications of sustainable cycloaliphatic polyurethanes from various renewable building blocks such as biobased terpenes, carbohydrates, fatty acids cholesterol or plastic wastes derivatives.
Language: Английский
Citations
75
Macromolecular Rapid Communications, Journal Year: 2023, Volume and Issue: 44(7)
Published: Jan. 20, 2023
Abstract The rapid increase in the use of plastics and related sustainability issues, including depletion global petroleum reserves, have rightly sparked interest biobased polymer feedstocks. Thermosets cannot be remolded, processed, or recycled, hence reused because their permanent molecular architecture. Vitrimers emerged as a novel family capable bridging difference between thermoplastic thermosets. enable unique recycling strategies, however, it is still important to understand where raw material feedstocks originate from. Transesterification vitrimers derived from renewable resources are massive opportunity, limited research has been conducted this specific vitrimers. This review article provides comprehensive overview transesterification produced monomers. focus on biomass structural suitability with dynamic covalent chemistry, well viability synthetic methods.
Language: Английский
Citations
59
Advanced Materials, Journal Year: 2023, Volume and Issue: 35(39)
Published: March 12, 2023
Abstract Polyimides (PIs) are widely used in circuit components, electrical insulators, and power systems modern electronic devices large appliances. Electrical/mechanical damage of materials important factors that threaten reliability service lifetime. Dynamic (self‐healable, recyclable degradable) PIs, a promising class successfully improve electrical/mechanical properties after damage, anticipated to solve this issue. The viewpoints perspectives on the status future trends dynamic PI based few existing documents shared. main forms dielectric application process first introduced, initial strategies schemes these problems proposed. Fundamentally, bottleneck issues faced by development PIs indicated, relationship between various universality method is evaluated. potential mechanism deal with highlighted several feasible prospective address discussed. This study concluded presenting short outlook improvements systems, challenges, solutions insulation. summary theory practice should encourage policy favoring energy conservation environmental protection promoting sustainability.
Language: Английский
Citations
59
Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(36)
Published: May 18, 2023
Abstract Linear chains in thermoplastics make them relatively weak performance but inherently weldable and recyclable. By contrast, thermosets with permanently crosslinked networks possess outstanding mechanical performance, thermal, chemical stability, are unweldable unrecyclable. In the last decade, a kind of thermoplastics‐like termed as vitrimer has been developed extensive applications, which welding vitrimers plays central fundamental role. Herein, we present current state art discuss from broad picture chemistry, physics, mechanics: i) chemistry mechanics vitrimers; ii) applicability assessment methods for iii) design principles implement strategies to iv) effects conditions on strength toughness; v) applications adhesion chemically inert materials. Finally, advantages, challenges, open questions highlighted, future opportunities mechanics, tough welding, artificial intelligence aided programming technology, standard, so discussed. The development would fuse disciplines transformative impact polymer industry.
Language: Английский
Citations
55
ACS Sustainable Chemistry & Engineering, Journal Year: 2023, Volume and Issue: 11(39), P. 14591 - 14600
Published: Sept. 12, 2023
Epoxy (EP) vitrimers are currently regarded as ideal substitutes for traditional thermosetting resins, this class of materials combines the advantages thermoplastic and thermoset polymers. However, maintaining high performance EP with excellent healing properties remains a challenge. In work, novel hardener combining disulfide imine bonds through reaction Schiff base (4-AFD-VAN) was designed then used to prepare vitrimer dual-dynamic covalent bonds. Compared single-disulfide-containing (EVP-4-AFD), prepared (EPV-4-AFD-VAN) exhibited lower activation energy faster stress relaxation. Moreover, EPV-4-AFD-VAN showed tensile strength up 71.5 MPa maintained recovery ratio approximately 90.0% during three cycles. Similar EP, retained its good solvent resistance, breakdown strength, dielectric properties, which can be chemically degraded in suitable solvents, demonstrating environmental sustainability.
Language: Английский
Citations
44
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 500, P. 157418 - 157418
Published: Nov. 1, 2024
Language: Английский
Citations
29
Nature Sustainability, Journal Year: 2024, Volume and Issue: 7(5), P. 616 - 627
Published: April 26, 2024
Language: Английский
Citations
24
Polymers, Journal Year: 2024, Volume and Issue: 16(16), P. 2262 - 2262
Published: Aug. 9, 2024
Biodegradable biobased polymers derived from biomass (such as plant, animal, marine, or forestry material) show promise in replacing conventional petrochemical polymers. Research and development have been conducted for decades on potential biodegradable such polylactic acid (PLA), polyhydroxyalkanoates (PHAs), succinate These materials evaluated practicality, cost, production capabilities limiting factors commercialization; however, challenges, the environmental limitations biodegradation rates polymer, need to be addressed. This review provides a history overview of current synthesis process properties polymers, along with techno-commercial analysis discussion impacts Specifically, focuses commercial potential, financial assessment, life-cycle assessment these materials, well government initiatives facilitate transition towards Lastly, challenges methods improving recycling reusability
Language: Английский
Citations
20
Macromolecules, Journal Year: 2024, Volume and Issue: 57(11), P. 5450 - 5460
Published: May 29, 2024
The development of sustainable composites necessitates biobased epoxy resins that are highly recyclable and degradable; however, the integration mechanical, reprocessing, rapid degradation properties into a single resin remains significant challenge. present study proposes straightforward approach to overcoming problem by combining two labile covalent bonds an resin. combination acetal disulfide demonstrates synergistic effect on performance resin, leading ultrafast polymer. carbon fiber-reinforced composite with matrix shows tensile strength exceeding 630 MPa, but degrades completely within just 8 min, while recovered fibers display nondestructive characteristics similar those original material. Moreover, we designed good self-healing reprocessing ability. Scratches surface can be self-healed heating, powdered reshaped under hot press. These findings offer new preparation composites, highlighting importance thermosetting polymers.
Language: Английский
Citations
16
Progress in Polymer Science, Journal Year: 2025, Volume and Issue: unknown, P. 101935 - 101935
Published: March 1, 2025
Language: Английский
Citations
3